Abstract
The brittle-to-ductile transition is investigated in polycarbonate (PC) after different types of thermomechanical treatment. In addition to the stress versus strain curves in uniaxial stretching to fracture of the original, preheated, shape recovered and high temperature pre-stretched samples, photoelasticity is applied to reveal the internal stress field in the fracture samples and high temperature pre-stretched samples. The change in microstructure after pre-deformation is concluded to be the reason behind the brittle-to-ductile transition. However, the type of subsequent loading to fracture is also important to determine if there is any transition. The magnitude of pre-deformation, the temperature of pre-deformation and the maximum deformation capability of the original material are three major parameters that affect the significance of brittle-to-ductile transition.
Similar content being viewed by others
References
Yan Q, Xu T, Zhang W, Lv C, Guo H, Tian F et al (2021) Abnormal brittle-ductile transition for glassy polymers after free and constrained melt stretching: The role of molecular alignment. Polymer 233:124199
Xu S, Tahon J-F, De-Waele I, Stoclet G, Gaucher V (2020) Brittle-to-ductile transition of PLA induced by macromolecular orientation. eXPRESS Polym Lett 14:1037–1047
Zartman GD, Cheng S, Li X, Lin F, Becker ML, Wang S-Q (2012) How melt-stretching affects mechanical behavior of polymer glasses. Macromolecules 45:6719–6732
Wang C, Pek JX, Chen HM, Huang WM (2022) On-Demand Tailoring between Brittle and Ductile of Poly (methyl methacrylate)(PMMA) via High Temperature Stretching. Polymers 14:985
Bradley W, Kobayashi A (1970) An investigation of propagating cracks by dynamic photoelasticity. Exp Mech 10:106–113
Wu X, Wang T, Huang W, Zhao Y (2017) Thermo-responsive shape-memory effect and surface features in polycarbonate (PC). Appl Sci 7:848
Huang WM, Ding Z, Wang CC, Wei J, Zhao Y, Purnawali H (2010) Shape memory materials. Mater Today 13:54–61
Otsuka K, Wayman CM (1998) Shape memory materials. Cambridge University Press, Cambridge
Yang WG, Lu HB, Huang WM, Qi HJ, Wu XL, Sun KY (2014) Advanced shape memory technology to reshape product design, manufacturing and recycling. Polymers 6:2287–2308
Hertzberg RW, Vinci RP, Hertzberg JL (2020) Deformation and fracture mechanics of engineering materials. John Wiley & Sons
Ashby MF (1990) Materials selection in engineering design. Indian J Technol 28:217–225
Khine M, Macuare KA (2018) The NAI fellow profile: An interview with Dr. Michelle Khine. Technol Innov 19:765–771
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wu, X., Wang, C., Pek, J.X. et al. Brittle-to-ductile transition in high temperature pre-stretched polycarbonate. J Polym Res 29, 435 (2022). https://doi.org/10.1007/s10965-022-03282-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10965-022-03282-1