Abstract
This work reveals a sol–gel approach for synthesis of silver doped magnesium oxide (Ag:MgO) incorporated in PVC matrix to give Ag:MgO/PVC nanocomposite. On glass substrate three different percentages of Ag:MgO/PVC (3,7, and 10%) were deposited by spin coating method. This film of Ag:MgO/PVC nanocomposites were characterized using AFM, UV–Vis, XRD and FTIR analysis. The results of XRD revealed the formation of Ag doped MgO nanoparticles with two phases (MgO and metallic Ag) in the matrix of PVC with the average size of nanoparticles equal to 31.5,22.29, 23.77, 29.68 nm. The direct band gap energy for PVC and pure MgO/PVC was 4.1 eV and 3.85 eV respectively. The band gap energy value changes from 3.85 eV, 3.75 eV, 3.71 eV, 3.69 eV with increasing Ag:MgO concentration(3–10%). Atomic force microscopyalso shows a change in the roughness of the nanocomposites film with increasing Ag:MgO nanoparticles percentage. The photocatalytic activity of this nanocomposite film was evaluated for the methylene blue (MB) dye under UV light irradiation. The result demonstrated good potential of Ag:MgO/PVC nanocomposites films for MB degradation with a suitable photocatalytic reaction proposed mechanism. The kinetic studies revealed a rate constant of 6.25 × 10–3 min−1 for 10% Ag:MgO/PVC nanocomposite thin films.
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References
Jeon IY, Baek JB (2010) Nanocomposites Derived from Polymers and Inorganic Nanoparticles. J Mater. 3(6):3654–3674. https://doi.org/10.3390/ma3063654
Roy S, Srivastava SK, Mittal V (2016) Facile noncovalent assembly of MWCNT-LDH and CNF-LDHas reinforcing hybrid fillers in thermoplastic polyurethane/nitrilebutadiene rubber blends. J Polym Res 23:36. https://doi.org/10.1007/s10965-016-0926-4
Meti S, Bhat UK, Rahman MR (2020) Colossal dielectric permittivity of Nylon-6 matrix-based composites with nano-TiO2 fillers. Applied Physics A 126:264. https://doi.org/10.1007/s00339-020-3445-4
Agarwal S, Saraswat VK (2015) Structural and optical characterization of ZnO doped PC/PS blendnanocomposites. J Opt Mater. https://doi.org/10.1016/j.optmat.2015.01.024
Balakrishnan G, Velavan R, Batoo KM, Raslan EH (2020) Microstructure, optical and photocatalytic properties of MgO nanoparticles. https://doi.org/10.1016/j.rinp.2020.103013
Tang ZX, Lu BF (2014) MgO Nanoparticles as antibacterial agent: Preparation and Activity Brazilian. J Chem Eng 31:591–601. https://doi.org/10.1590/0104-6632.20140313s00002813
Cai Y, Wu Dan, Zhu X, Wang Wei, Tan Fatang, Chen J, Xueliang Q, Qiu X (2016) Sol-gel preparation of Ag-doped MgOnanoparticles with high efficiency for bacterialinactivation. J Ceramics Int. https://doi.org/10.1016/j.ceramint.2016.10.041
Gulati U, Rajesh UC, Rawat DS, Zaleski JM (2012) Development of magnesium oxide-silver hybrid nanocatalysts for synergistic carbon dioxide activation to afford esters and Heterocycles at Ambient Pressure. J. N ame.00:1–3 .https://doi.org/10.1039/C9GC04040D
Yıldırım OA, Unalan HE, Durucan C (2013) Highly Efficient Room Temperature Synthesis of Silver-Doped Zinc Oxide(ZnO:Ag) Nanoparticles: Structural, Optical, and Photocatalytic Properties. J Am Ceram Soc 96(3) 766–773. https://doi.org/10.1111/jace.12218
Hosseini SM, Abdolhosseini I. Kameli SP, Salamati H (2015 )Effect of Ag doping on structural, optical and photocatalytic properties of ZnO nanoparticles. J Alloys Compd 640:408–415 https://doi.org/10.1016/j.jallcom.2015.03.136
Feldman D (2014) Poly(vinyl chloride) Nanocomposites. J Macromol Sci, Part A: Pure Appl Chem 51:659–667. https://doi.org/10.1080/10601325.2014.925265
Chem TJ (2004) Turk J Chem 28:725–729
Deng Z, Zhu H, Deng Z, Zhu H, Peng B, Chen H, Sun Y, Gang X, Jin P, Wang J (2012) Synthesis of PS/Ag nanocomposite spheres with catalytic and antibacterial activities. J ACS Appl Mater Interfaces (4):5625−5632. https://doi.org/10.1021/am3015313
Zhou X (2015) Ag-doping improving the detection sensitivity of bolometer based on ZnO thin films. J Vacuum 117:47e49
Kang HS, Ahn BD, Kim JH, Kim GH, Lim SH, Chang HW, Lee SY (2006) Structural, electrical, and optical properties of p-type ZnO thin films with Ag dopant. Appl Phys Lett 88:202108
Li W, Kong C, Ruan H, Qin G, Huang G, Yang T, Liang W, Zhao Y, Meng X, Yu P (2012) Electrical properties and Raman scattering investigation of Ag doped ZnO thin films. Solid state communications 152:147–150
Cai Y, Wu D, Zhu X, Wang W, Tan F, Chen J, Qiao X, Qiu X (2017) Sol-gel preparation of Ag-doped MgO nanoparticles with high efficiency for bacterial inactivation. Ceram Int 43:1066–1072
Ahmad KS, Jaffri SB (2018) Phytosynthetic Ag doped ZnO nanoparticles: Semiconducting green remediators. J Open Chem 16:556–570. https://doi.org/10.1515/chem-2018-0060
Kassaee MZ, Mohammadkhani M, Akhavan A, Mohammadi R (2011) In situ formation of silver nanoparticles in PMMA via reduction of silver ions by butylated hydroxytoluene. Struc Chem 22:11–15
Vodnik VV, Vuković JV, Nedeljković JM (2009) Synthesis and characterization of silver—poly(methylmethacrylate) nanocomposites. Colloid Polym Sci 287:847–851
Kandulna R, Choudhary RB, Maji P (2017) Ag-doped ZnO reinforced polymeric Ag:Zno/PMMA nanocomposites as electron transporting layer for OLED application. J Inorg Organomet Polym. https://doi.org/10.1007/s10904-017-0639-0
Almontasser A, Parveen, Azam A (2019) Synthesis, Characterization and antibacterial activity of Magnesium Oxide (MgO) nanoparticles. J IOP Conf Ser: Mater Sci Eng (577):012051. https://doi.org/10.1088/1757-899X/577/1/012051
Krehula LK, Papic A,Krehula S, Gilja V, Foglar L, Hrnjak-Murgic Z (2016) Properties of UV protective films of poly(vinyl-chloride)/TiO2nanocomposites for food packaging. J Polym Bull. https://doi.org/10.1007/s00289-016-1782-4
Natarajan S, Kumari J, Lakshmi DS, Mathur A, Bhuvaneshwari M, Parashar A, Pulimi M, Chandrasekaran M, Mukherjee A (2015) Differences in antibacterial activity of PMMA/TiO2/Ag nanocomposite on individual dominant bacterial isolates from packaged drinking water, and their consortium under UVC and dark conditions. J Applied Surface Science. https://doi.org/10.1016/j.apsusc.2015.11.223
Bhavitha KB, Nair AK, Mariya H, Jose J, Mayeen A ,Kala MS, Saha A, Thomas S, Oluwafemi OS, Kalarikka N (2018) In-situ Dose dependent Gamma ray Irradiated Synthesis of PMMA-Ag nanocomposites films for multifunctional applications. New J of Chem (2018). https://doi.org/10.1039/C8NJ02684J
Cho S (2001) Wonyong Choi; Solid-phase photocatalytic degradation of PVC–TiO2 polymer composites. J Photochem Photobiol A 143:221–228
Yang C, Deng K, Peng T (2011) Ling Zan;Enhanced Solid-Phase Photocatalytic Degradation Activity of a Poly(vinyl chloride)-TiO2 Nanocomposite Film with Bismuth Oxyiodide. J Chem Eng Technol 34(6):886–892
Yang C, Gong C, Peng T, Deng K (2010) Ling Zan; High photocatalytic degradation activity of the polyvinyl chloride (PVC)–vitamin C (VC)–TiO2 nano-composite film. J Hazard Mater 178:15
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Authors are thankful to the Researchers Supporting Project number (RSP-2021/132), King Saud University, Riyadh, Saudi Arabia
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Rouabah, N., Boudine, B., Nazir, R. et al. Nanocomposite synthesis of silver doped magnesium oxide incorporated in PVC matrix for photocatalytic applications. J Polym Res 28, 154 (2021). https://doi.org/10.1007/s10965-021-02516-y
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DOI: https://doi.org/10.1007/s10965-021-02516-y