Abstract
An isocyanate-terminated polyoxytetramethylene (IPOTM; \(\stackrel{-}{MW}\) = 1350 g/mol) was used to modify silica nanoparticles (SNPs). The nanoparticles were spherically coated by an organic shell consisting of the polyether material with 55% by weight, according to thermogravimetric analysis (TGA). IPOTM diisocyanate, as a telechelic prepolymer, was also used for the preparation of polyurethane elastomers (PUEs) through polyaddition reactions with 1,4-butane diol in the presence/absence of IPOTM-modified SNPs. The elastomers were characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and field emission-scanning electron microscopy (FE-SEM). Despite the use of the low amounts of the organically modified filler (5.0 and 7.0 wt.% of OSNPs), a significant enhancement in the storage and loss moduli (E' and E'' values) of the elastomeric films could be occurred. Also, according to the tan δ vs temperature graphs obtained from dynamic mechanical analysis (DMA), the IPOTM-modified SNPs led to a little decrease, up to 5°C, in the glass transition temperatures (Tg values) of the elastomers. In addition, TGA thermograms showed that no reduction occurred in the thermal stability of the elastomeric polyurethanes after the addition of IPOTM-modified nanoparticles.
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References
Xie F, Zhang T, Bryant P, Kurusingal V, Colwell JM, Laycock B (2019) Degradation and stabilization of polyurethane elastomers. Prog Polym Sci 90:211–268
Harle T, Nguyen GT, Ledesert B, Melinge Y, Hebert RL (2020) Cross-linked polyurethane as solid-solid phase change material for low temperature thermal energy storage. Thermochim Acta 685:178–191
Guney A, Gardiner C, McCormack A, Malda J, Grijpma DW (2018) Thermoplastic PCL-b-PEG-b-PCL and HDI Polyurethanes for Extrusion-Based 3D-Printing of Tough Hydrogels. Bioengineering 5(99)
Akindoyo JO, Beg M, Ghazali S, Islam M, Jeyaratnam N, Yuvaraj A (2016) Polyurethane types, synthesis and applications:a review RSC Adv 6(115):114453–114482
Jian X, Hu Y, Zhou W, Xiao L (2018) Self-healing polyurethane based on disulfide bond and hydrogen bond. Polym Adv Technol 29(1):463–469
Kasprzyk P, Sadowska E, Datta J (2019) Investigation of Thermoplastic Polyurethanes Synthesized via Two Different Prepolymers. J Polym Environ 27:2588–2599
Tsou CH, Lee HT, Tsai HA, Cheng HJ, Suen MC (2013) Synthesis and properties of biodegradable polycaprolactone/polyurethanes by using 2, 6-pyridinedimethanol as a chain extender. Polym Degrad Stab 98:643–650
Wang F, Chen S, Wu Q, Zhang R, Sun P (2019) Strain-induced structural and dynamic changes in segmented polyurethane elastomers. Polymer 163:154–161
Zaredar Z, Askari F, Shokrolahi P (2018) Polyurethane synthesis for vascular application. Prog Biomater 7(4):269–278
Zhou X, Li Y, Fang C, Li S, Cheng Y, Lei W, Meng X (2015) Recent advances in synthesis of waterborne polyurethane and their application in water-based ink: a review. J Mater Sci Technol 31:708–722
Mirabedini A, Mohseni M, Ramezanzadeh B (2013) A comparative study between experimentally measured mechanical attributes and users’ perception of soft feel coatings: Correlating human sense with surface characteristics of polyurethane based coatings. Prog Org Coat 76:1369–1375
Saavedra J, Lopez-Beceiro J, Naya S, Artiaga R (2008) Effect of silica content on thermal stability of fumed silica/epoxy composites. Polym Degrad Stab 93(12):2133–2137
Dittanet P, Pearson RA, Kongkachuichay P (2017) Thermo-mechanical behaviors and moisture absorption of silica nanoparticle reinforcement in epoxy resins. Int J Adhes Adhes 78:74–82
Jong L (2019) Improved mechanical properties of silica reinforced rubber with natural polymer. Poly Test 79:106–109
Lee DW, Yoo BR (2016) Advanced silica/polymer composites: Materials and applications. J Ind Eng Chem 38:1–12
Hajibeygi M, Shabanian M, Omidi-Ghallemohamadi M (2017) Development of new acid-imide modified Mg-Al/LDH reinforced semi-crystalline poly (amide-imide) containing naphthalene ring; study on thermal stability and optical properties. Appl Clay Sci 139:9–19
Hajibeygi M, Shabanian M, Omidi-Ghallemohamadi M, Khonakdar HA (2017) Optical, thermal and combustion properties of self-colored polyamide nanocomposites reinforced with azo dye surface modified ZnO nanoparticles. Appl Surf Sci 416:628–638
Omidi-Ghallemohamadi M, Ahmadi-Khaneghah A, Behniafar H (2019) Epoxy networks possessing polyoxyethylene unites and loaded by Jeffamine-modified graphene oxide nanoplatelets. Prog Org Coat 134:264–271
Sari MG, Saeb MR, Shabanian M, Khaleghi M, Vahabi H, Vagner C, Zarrintaj P (2018) Epoxy/starch-modified nano-zinc oxide transparent nanocomposite coatings: A showcase of superior curing behavior. Prog Org Coat 115:143–150
Ahmadi-Khaneghah A, Omidi-Ghallemohamadi M, Behniafar H (2019) PEG-based epoxy and epoxy/silica networks: Thermal, mechanical, and thermo-mechanical investigations. Int J Adhes Adhes 95:102430
Kim SK, Nguyen NA, Wie JJ, Park HS (2015) Manipulating the glass transition behavior of sulfonated polystyrene by functionalized nanoparticle inclusion. Nanoscale 7(19):8864–8872
Mallakpour S, Naghdi M (2018) Polymer/SiO2 nanocomposites: Production and applications. Prog Mater Sci 97:409–447
Farrukh A, Ashraf F, Kaltbeitzel A, Ling X, Wagner M, Duran H, Ghaffar A, Rehman PSH, Domke KF (2015) Polymer brush functionalized SiO2 nanoparticle based Nafion nanocomposites: a novel avenue to low-humidity proton conducting membranes. Polym Chem 6(31):5782–5789
Dinari M, Haghighi A (2017) Surface modification of TiO2 nanoparticle by three dimensional silane coupling agent and preparation of polyamide/modified-TiO2 nanocomposites for removal of Cr (VI) from aqueous solutions. Prog Org Coat 110:24–34
Arun M, Kantheti S, Gaddam RR, Narayan R, Raju K (2014) Surface modification of TiO2 nanoparticles with 1, 3, 5-triazine based silane coupling agent and its cumulative effect on the properties of polyurethane composite coating. J Polym Res 21(12):600
Ghomi ER, Khorasani SN, Kichi MK, Dinari M, Ataei S, Enayati MH, Koochaki MS, Neisiany RE (2020) Synthesis and characterization of TiO2/acrylic acid-co-2-acrylamido-2-methyl propane sulfonic acid nanogel composite and investigation its self-healing performance in the epoxy coatings. Colloid Polym Sci 1–11
Mallakpour S, Nikkhoo E (2013) Morphological and thermal properties of nanocomposites contain poly (amide-imide) reinforced with bioactive N-trimellitylimido-L-valine modified TiO2 nanoparticles. J Polym Res 20(2):78
Jouyandeh M, Paran SMR, M, Ghiyasi S, Vahabi H, Badawi M, Formela K, Puglia D, Saeb MR, (2018) Curing behavior of epoxy/Fe3O4 nanocomposites: a comparison between the effects of bare Fe3O4, Fe3O4/SiO2/chitosan and Fe3O4/SiO2/chitosan/imide/phenylalanine-modified nanofillers. Prog Org Coat 123:10–19
Naeemikhah E, Ahmadi-khaneghah A, Heydari A, Behniafar H (2019) Magnetic crosslinked polystyrene with hydrophilic nature prepared through surface-initiated ATRP technique. Colloids Surf A 582:123–131
Shabanian M, Mirzakhanian Z, Moghanian H, Hajibeygi M, Salimi H, Khonakdar HA (2017) Thermal, combustion and optical properties of new polyimide/ODA-functionalized Fe3O4 nanocomposites containing xanthene and amide groups. J Therm Anal Calorim 129:147–159
Shabanian M, Moghanian H, Khaleghi M, Hajibeygi M, Khonakdar HA, Vahabi H (2016) Chitosan and imide-functional Fe3O4 nanoparticles to prepare new xanthene based poly (ether-imide) nanocomposites. RSC adv 6:112568–112575
Rao TN, Hussain I, Koo BH (2019) Enhanced thermal properties of silica nanoparticles and chitosan bio-based intumescent flame retardant Polyurethane coatings. Mater Today Proc
Lin B, Zhou S (2017) Poly (ethylene glycol)-grafted silica nanoparticles for highly hydrophilic acrylic-based polyurethane coatings. Prog Org Coat 106:145–154
Bonab SA, Moghaddas J, Rezaei M (2019) In-situ synthesis of silica aerogel/polyurethane inorganic-organic hybrid nanocomposite foams: Characterization, cell microstructure and mechanical properties. Polymer 172:27–40
Cho JW, Lee SH (2019) Influence of silica on shape memory effect and mechanical properties of polyurethane–silica hybrids. Eur polym j 40(7):1343–1348
Sadeghi M, Semsarzadeh MA, Barikani M, Chenar MP (2011) Gas separation properties of polyether-based polyurethane–silica nanocomposite membranes. J Membr Sci 376:188–195
Puszka A (2018) Thermal and mechanical behavior of new transparent thermoplastic polyurethane elastomers derived from cycloaliphatic diisocyanate. Polymers 10:537
Datta J, Kopczynska P (2015) Effect of kenaf fibre modification on morphology and mechanical properties of thermoplastic polyurethane materials. Ind Crops Prod 74:566–576
Jiang G, Tuo X, Wang D, Li Q (2012) Synthesis and properties novel polyurethane-hexafluorobutyl methacrylate copolymers. J Mater Sci Mater Med 23(8):1867–1877
Behniafar H, Yazdi M (2016) PTMG-Modified MWCNT/PTMG-based polyurethane nanocomposites: Strong interaction and homogeneous dispersion. Polym Sci Ser B 58(6):736–744
Behniafar H, Yazdi M (2018) Poly (tetramethylene oxide)(PTMO)-grafted carbon nanotubes for preparing PTMO-based polyurethane films with enhanced storage moduli. Adv Polym Technol 37:1374–1381
Behniafar H, Ahmadi-khaneghah A, Yazdi M (2016) Enhanced heat stability and storage modulus in novel PTMO-intercalated clay platelets/PTMO-based polyurethane nanocomposites. J Polym Res 23:202
Behniafar H, Alimohammadi M, Malekshahinezhad K (2015) Transparent and flexible films of new segmented polyurethane nanocomposites incorporated by NH2-functionalized TiO2 nanoparticles. Prog Org Coat 88:150–154
Behniafar H, Azadeh S (2015) Transparent and flexible films of thermoplastic polyurethanes incorporated by Nano-SiO2 modified with 4, 4′-methylene diphenyl diisocyanate. Int J Polym Mater Polym Biomater 64:1–6
Jafari F, Behniafar H (2019) Epoxy Networks Cured with α, ω-Diamino Polyoxytetramethylene in the Presence of Polyoxytetramethylene-coated Silica Nanoparticles. Polymer Korea 43(1):52–59
Jafari F, Pajoohi E, Behniafar H (2019) Bisphenol A Diglycidyl Ether-Based Epoxy Networks with Enhanced Storage Moduli Using Silica Nanoparticles Coated by NH2-Functionalized Poly (tetramethylene oxide). Polym Sci Ser B 61(3):357–365
Karimzadeh M, Eslampanah E, Behniafar H (2018) Poly (tetramethylene oxide)-coated silica nanoparticles incorporated into poly (4, 4′-oxydiphenylene-pyromellitimide) matrix. Mater Manuf Processes 33:1093–1099
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Financial support from the Research Council of Islamic Azad University-Damghan branch is greatly acknowledged. The authors wish to express their gratitude to the School of Chemistry and Research Council of Damghan University.
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Omidi-Ghallemohamadi, M., Jafari, P. & Behniafar, H. Polyurethane elastomer–silica hybrid films based on oxytetramethylene soft segments: thermal and thermo-mechanical investigations. J Polym Res 28, 96 (2021). https://doi.org/10.1007/s10965-021-02466-5
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DOI: https://doi.org/10.1007/s10965-021-02466-5