Abstract
A novel nanometer-sized chelating resin (NSCR) was prepared via two steps, First step: copolymerization reaction of N-methacryloxyphtalimide (NMP) with methylenebisacrylamide (MBA) by suspension polymerization method to give ultrafine poly (NMP-co-MBA). Second step: reaction of triethylenetetramine (TETA) with poly (NMP-co-MBA) to give NSCR. The prepared NSCR was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Brunauer-Emmett-Taller (BET) and thermogravimetric analysis (TGA). This study illustrated the capability of NSCR for extraction of Cu(II), Co(II) and Ni(II) from aquatic solutions. The pH effect, metal ions concentration, temperature and contact time were elaborated in batch experiments. The results showed that high capacities were 1.3, 1.0 and 0.95 mmol/g resin for Cu(II), Ni(II) and Co(II) ions, respectively. The experimental data of adsorption isotherms were convenient for Langmuir isotherm, and the kinetic data illustrated that the removal process was described by pseudo-second order kinetic model. The parameters of Thermo dynamic illustrated that the process of adsorption was endothermic and spontaneous reaction. The prepared NSCR was regenerated and used repetitively for five times with small decrease in adsorption capacity.
Similar content being viewed by others
References
Van Genderen EJ, Ryan AC, Tomasso JR, Klaine SJ (2005) Evaluation of acute copper toxicity to larval fathead minnows (Pimephales Promelas) in soft surface waters. Environ Toxicol Chem 24:408–414
Apostoli P, Catalani S, Zaghini A, Mariotti A, Poliani PL, Vielmi V, Semeraro F, Duse S, Porzionato A, Macchi V, Padovani A, Rizzetti MC, De Caro R (2012) High doses of cobalt induce optic and auditory neuropathy. Exp Toxicol Pathol 65:719–727
Das KK, Das SN, Dhundasi SA (2008) Nickel, its adverse health effects & oxidative stress. Indian J Med Res 128:412–425
Nebel BJ, Wright RT (1966) Environmental science 5th edn. Prenticehall, London,
Nagh WSW, Endud CS, Mayanar R (2002) Removal of Cu(II) ions from aqueous solution onto chitosan and crosslinked chitosan beads. React Funct Polym 50:181–190
Tofighy MA, Mohammadi T (2011) Adsorption of divalent heavy metal ions from water using carbon nano tube sheet. J Hazard Mater 185:140–147
Deligz H, Erdem E (2008) Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives. J Hazard Mater 154:29–32
Bessbousse H, Rhlalou T, Verchere JF, Lebrun L (2008) Removal of heavy metal ions from aqueous solutions by filteration with a novel complexing membrane containing poly(ethyleneimine) inapoly (vinylalcohol) matrix. J Membr Sci 307:249–259
Rivas BL, Quilodran B, Quiroz E (2004) Trace metal ion retention properties of crosslinked poly(4-Vinylpyridine) and poly(acrylic acid). J Appl Polym Sci 92:2908–2916
Henry WD, Zhao D, Sengupta AK, Lang C (2004) Preparation and characterization of a new class of polymeric ligand exchangers for selective removal of trace contaminants from water. React Funct Polym 60:109–120
Nastasovic A, Jovanovic S, Dordevic D, Onjia A, Jakovljevic D, Novakovic T (2004) Metal sorption on macroporous poly (GMA-co-EGDMA) modified with ethylene di amine. React Funct Polym 58:139–147
Baraka A, Hall PJ, Heslop MJ (2007) Preparation and characterization of melamine-formaldehyde-dtpa chelating resin and its use as an adsorbent for heavy metals removal from wastewater. React Funct Polym 67:585–600
Leinonen H, Lehto J (2000) Ion-exchange of nickel by iminodiacetic acid chelating resin Chelex 100. React Funct Polym 43:1–6
Neagu V, Bunia I, Luca C (2006) Organic ion exchangers synthesis and their behaviour in the retention of some metal ions. Macromol Symp 235:136–142
Denizli A, Sanli N, Garipcan B, Patir S, Alsancak G (2004) Methacryloylamidoglutamic acid incorporated porous poly(methyl methacrylate) beads for heavy-metal removal. Ind Eng Chem Res 43:6095–6101
Zohuriaan Mehr MJ, Pourjavadi A, Salehi Rad M (2004) Modified CMC. 2. Novel carboxymethylcellulose-based poly(amidoxime) chelating resin with high metal sorption capacity. React Funct Polym 61:23–31
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2014) Synthesis of a new chelating resin bearing amidoxime group for adsorption of cu(II), Ni(II) and Pb(II) by batch and fixed-bed column methods. J Environ Chem Eng 2:632–641
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2013) Removal of Pb(II), cd(II), Mn(II) and Zn(II) using iminodiacetate chelating resin by batch and fixed bed column methods. Desalin Water Treat 51:5526–5536
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2013) Synthesis and characterization of dithiocarbamate chelating resin and its adsorption performance towards Hg(II), Cd(II) and Pb(II) by batch and fixed-bed column methods. J Environ Chem Eng 1:208–217
Shaaban AF, Mohamed TY, Fadel DA, Bayomi NM (2017) Removal of Ba(II) and Sr(II) ions using modified chitosan beads with bendent amidoxime moieties by batch and fixed column methods. J Desalin Water Treat in press
Ge F, Li M, Ye H, Zhao B (2012) Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles. J Hazard Mater 211–212:366–372
Cumbal L, Sengupta AK (2005) Removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of donnan membrane effect. Environ Sci Technol 39:6508–6515
Zargoosh K, Abedini H, Abdolmaleki A, Molavian MR (2013) Effective removal of heavy metal ions from industrial wastes using thiosalicylhydrazide-modified magnetic nanoparticles. Ind Eng Chem Res 52:14944–14954
Wang X, Guo Y, Yang L, Han M, Zhao J, Cheng X (2012) Nanomaterials as sorbents to remove heavy metal ions in wastewater treatment. J Environ Anal Toxicol 2:154
Shaaban AF, Arief MMH, Khalil AA, Messina NN (1988) 2-Poly-N-acyloyloxy- and -N- methacryloyloxyphthalimi- de as activated drug-binding matrices. Acta Polym 39:145–148
Khalil AA (2006) Exchange reactions of poly-2-(N-phthalimido) ethyl acrylate with hydroxyl and amino compounds. J Appl Polym Sci 99:2258–2262
Long C, Li Y, Yu W, Li A (2012) Adsorption characteristics of water vapor on the hypercrosslinked polymeric adsorbent. Chem Eng J 180:106–112
Bratkowska D, Fontanals N, Borrull F, Cormack PAG, Sherrington DC, Marce RM (2010) Hydrophilic hypercrosslinked polymeric sorbents for the solid-phase extraction of polar contaminants from water. J Chromatogr A 1217:3238–3243
Gurses A, Yalcin M, Sozbilir M, Dogar C (2003) The investigation of adsorption thermodynamics and mechanism of a cationic surfactant, CTAB, onto powdered active carbon. Fuel Process Technol 81:57–66
Cumbal L, Greenleaf J, Leun D, SenGupta AK (2003) Polymer supported inorganic nanoparticles: characterization and environmental applications. React Funct Polym 54:167–180
Elbhiri Z, Chevalier Y, Chovelon J-M, Jeffrezic-Renault N (2000) Grafting of phosphonate groups on the silica surface for the elaboration of ion-sensitive field-effect transistors. Talanta 52:495–507
Lin Z, Zhang Y, Chen Y, Qian H (2012) Extraction and recycling utilization of metal ions (Cu2+, Co2+ and Ni2+) with magnetic polymer beads. J Chem Eng 200–202:104–110
Pekel N, Sahiner N, Guven O (2001) Use of amidoximated acrylonitrile/N-vinyl 2 pyrrolidone interpenetrating polymer networks for uranyl ion adsorption from aqueous systems. J Appl Polym Sci 81:2324–2329
Kawai O, Saito K, Sugita K (2000) Comparison of amidoxime adsorbents prepared by cografting methacrylic acid and 2-hydroxyethyl methacrylate with acrylonitrile onto polyethylene. Ind Eng Chem Res 39:2910–2915
Cegłowski M, Schroeder G (2015) Removal of heavy metal ions with the use of chelating polymers obtained by grafting pyridine–pyrazole ligands onto polymethylhydrosiloxane. J Chem Eng 259:885–893
Lia B, Liu F, Wang J, Ling C, Li L, Hou P, Li A, Bai Z (2012) Efficient separation and high selectivity for nickel from cobalt-solution by a novel chelating resin: batch, column and competition investigation. J Chem Eng 195–196:31–39
Coşkun R, Soykan C, Saçak M (2006) Adsorption of copper(II), nickel(II) and cobalt(II) ions from aqueous solution by methacrylic acid/acrylamide monomer mixture grafted poly(ethylene terephthalate) fiber. Sep Purif Technol 49:107–114
Bekheit MM, Nawar N, Addison AW, Abdel-Latif DA, Monier M (2011) Preparation and characterization of chitosan-grafted-poly(2-amino-4,5-pentamethylene-thiophene-3-carboxylic acid N -acryloyl-hydrazide) chelating resin for removal of Cu(II), Co(II) and Ni(II) metal ions from aqueous solutions. Int J Biol Macromol 48:558–565
Monier M, Ayad DM, Wei Y, Sarhan AA (2010) Preparation and characterization of magnetic chelating resin based on chitosan for adsorption of Cu(II), Co(II), and Ni(II) ions. React Funct Polym 70:257–266
Sales Jose AA, Faria Flavia P, Prado Alexandre GS, Claudio A (2004) Attachment of 2-aminomethylpyridine molecule onto grafted silica gel surface and its ability in chelating cations. Polyhedron 23:719–725
Monier M, Ayad DM, Wei Y, Sarhan AA (2010) Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin. J Hazard Mater 177:962–970
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403
Weber TW, Chakravot RK (1974) Pore and solid diffusion models for fixed bed adsorbents. AICHE J 20:228–238
Sari A, Tuzen M, Citak D, Soylak M (2007) Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay. J Hazard Mater 149:283–291
Wang XS, Huang J, Hua HQ, Wang J, Qin Y (2007) Determination of kinetic and equilibrium parameters of the batch adsorption of Ni(II) from aqueous solutions by Na-mordenite. J Hazard Mater 142:468–476
Freundlich H (1906) Adsorption in solution. Phys Chem Soc 40:1361–1368
Temkin MJ, Phyzev V (1940) Recent modifications to Langmuir isotherms. Acta Physiochim 12:217–222
Lagergren S, Svenska BK (1898) Zur theorie der sogenannten adsorption geloester stoffe. K Svenska Vetenskapsakad Handl 24:1–39
Ho YS (2006) Second order kinetic model for the sorption of cadmium on to tree fern: a comparison of linear and non linear methods. Water Res 40:119–125
Weber WJ, Morris JC (1964) Equilibria and capacities for adsorption on carbon. J Sanit Eng Div 90:79–91
Sarici-Ozdemir C, Onal Y (2010) Equilibrium, kinetic and thermodynamic adsorptions of the environmental pollutant tannic acid onto activated carbon. Desalination 251:146–152
Nilchi A, Saberi R, Moradi M, Azizpour H, Zarghami R (2011) Adsorption of cesium on copper hexacyanoferrate–PAN composite ion exchanger from aqueous solution. J Chem Eng 172:572–580
Unlu N, Ersoz M (2007) Removal of heavy metal ions by using dithiocarbamated- sporopollenin. Sep Purif Technol 52:461–469
Bandegharaei AH, Hosseini MS, Jalalabadi Y, Sarwghadi M, Nedaie M, Taherian A, Ghaznavi A, Eftekhari A (2011) Removal of Hg (II) from aqueous solutions using a novel impregnated resin containing 1-(2-thiazolylazo)-2-naphthol (TAN). J Chem Eng 168:1163–1173
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shaaban, A.F., Khalil, A.A., Radwan, M. et al. Synthesis, characterization and application of a novel nanometer-sized chelating resin for removal of Cu(II), Co(II) and Ni(II) ions from aqueous solutions. J Polym Res 24, 165 (2017). https://doi.org/10.1007/s10965-017-1323-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10965-017-1323-3