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Preparation of a New Polymerized Ionic Liquid-Modified Magnetic Nano Adsorbent for the Extraction and Preconcentration of Nitrate and Nitrite Anions from Environmental Water Samples

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Abstract

In this research, a new type of poly ionic liquid-coated magnetic nanoparticle (MNPs@PIL) was designed and prepared via free radical polymerization. The as-synthesized MNPs were characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermo gravimetric analysis (TGA) and elemental analysis (EA). Then, they were successfully used as adsorbent in magnetic solid-phase extraction (MSPE) method for the extraction of nitrate and nitrite anions from water samples, and the analytes were finally determined by ion chromatography/conductivity detection. The effects of several experimental variables (including pH of sample solution, amount of the adsorbent, extraction and desorption time) were studied and the optimum values were determined. Under the optimum experimental conditions, detection limits (S/N = 3) of the proposed method for nitrate and nitrite were obtained as 0.2 and 0.133 µg L−1, respectively. The repeatability of the method, expressed as relative standard deviation (RSD), was lower than 5%. The proposed method was successfully applied for determination of nitrate and nitrite in real water samples.

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References

  1. Aguilar-Arteaga K, Rodriguez JA, Barrado E (2010) Anal Chim Acta 674:157–165

    Article  CAS  Google Scholar 

  2. Feizbakhsh A, Ehteshami S (2016) Chromatographia 79:1177–1185

    Article  CAS  Google Scholar 

  3. Vasconcelos I, Fernandes Ch (2017) TrAC Trends Anal Chem 89:41–52

    Article  CAS  Google Scholar 

  4. Wu L, Yu L, Ding X, Li P, Dai X, Chen X, Zhou H, Bai Y, Ding J (2017) Food Chem 217:320–325

    Article  CAS  Google Scholar 

  5. Qin X, Ahmed Bakheet AA, Zhu X (2017) J Iran Chem Soc 14:2017–2022

    Article  CAS  Google Scholar 

  6. Nasiri J, Naghavi MR, Alizadeh H, Fattahi-Moghadam MR, Motamedi E, Mashouf A (2015) Chromatographia 78:1143–1157

    Article  CAS  Google Scholar 

  7. Nazari Serenjeh F, Hashemi P, Naeimi H, Zakerzadeh E, Ghiasvand AR (2016) Microchim Acta 183(8):2449–2455

    Article  CAS  Google Scholar 

  8. Keskin S, Kayrak-Talay D, Akman U, Hortacsu O (2007) J Supercrit Fluids 43:150–180

    Article  CAS  Google Scholar 

  9. Yuan JY, Antonietti M (2011) Polymer 52(7): 1469–1482

    Article  CAS  Google Scholar 

  10. Yuan JY, Mecerreyes D, Antonietti M (2013) Prog Polym Sci 38:1009–1036

    Article  CAS  Google Scholar 

  11. Devasurendra AM, Zhang C, Young JA, Tillekeratne LMV, Anderson JL, Kirchhoff JR (2017) ACS Appl Mater Interfaces 9(29):24955–24963

    Article  CAS  Google Scholar 

  12. Young JA, Zhang C, Devasurendra AM, Tillekeratne LMV, Anderson JL, Kirchhoff JR (2016) Anal Chim Acta 910:45–52

    Article  CAS  Google Scholar 

  13. Huang XJ, Chen LL, Yuan DX, Bi SS (2012) J Chromatogr A 1248:67–73

    Article  CAS  Google Scholar 

  14. Galan-Cano F,. Alcudia-Leon MDC, Lucena R, Cardenas S, Valcarcel M (2013) J Chromatogr A 1300:134–140

    Article  CAS  Google Scholar 

  15. Bi W, Wang M, Yang X, Ho-Row K (2014) J Sep Sci 37:1632–1639

    Article  CAS  Google Scholar 

  16. Yang L, Su P, Chen X, Zhang R, Yang Y (2015) Anal Methods 7:3246–3252

    Article  CAS  Google Scholar 

  17. Huang X, Wang Y, Liu Y, Yuan D (2013) J Sep Sci 36:3210–3219

    CAS  PubMed  Google Scholar 

  18. Ahmed-Bakheet AA, Shi-Zhu X (2017) J Mol Liq 242:900–906

    Article  Google Scholar 

  19. Moorcroft MJ, Davis J, Compton RG (2001) Talanta 54:785–803

    Article  CAS  Google Scholar 

  20. Wang QH, Yu LJ, Liu Y, Lin L, Lu R, Zhu J, He L, Lu ZL (2017) Talanta 165:709–720

    Article  CAS  Google Scholar 

  21. Antczak-Chrobot A, Bak P, Wojtczak M (2018) Food Chem 240:648–654

    Article  CAS  Google Scholar 

  22. Kissner R, Koppenol WH (2005) Methods Enzymol 396:61–68

    Article  CAS  Google Scholar 

  23. Helaleh MIH, Korenaga T (2000) J Chromatogr B 744:433–437

    Article  CAS  Google Scholar 

  24. Muscara MN, De Nucci G (1996) J Chromatogr B 686:157–164

    Article  CAS  Google Scholar 

  25. Mashhadizadeh MH, Karami Z (2011) J Hazard Mater 190:1023–1029

    Article  CAS  Google Scholar 

  26. Wu JW, Su P, Huang J, Wang SM, Yang Y (2013) J Colloid Interface Sci 399:107–109

    Article  CAS  Google Scholar 

  27. Deng YH, Qi D, Deng CH, Zhang XM, Zhao DY (2008) J Am Chem Soc 130:28–31

    Article  CAS  Google Scholar 

  28. Kaykhaii M, Dicinoski GW, Smedley R, Pawliszyn J, Haddad PR (2010) J Chromatogr A 1217:3452–3456

    Article  CAS  Google Scholar 

  29. Hu ZZ, Chen HD, Yao CY, Zhu Y (2011) J Chromatogr Sci 49:612–617

    Article  Google Scholar 

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Acknowledgements

The authors wish to thank Imam Khomeini international university research council for supporting the project.

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Authors and Affiliations

  1. Department of Chemistry, Imam Khomeini International University (IKIU), Qazvin, 3414916818, Iran

    Fateme Aflatouni & Majid Soleimani

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  1. Fateme Aflatouni
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  2. Majid Soleimani
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Correspondence to Majid Soleimani.

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The authors acknowledge that there was no conflict of interest.

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There were no human or animals test participants involved in this study.

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Aflatouni, F., Soleimani, M. Preparation of a New Polymerized Ionic Liquid-Modified Magnetic Nano Adsorbent for the Extraction and Preconcentration of Nitrate and Nitrite Anions from Environmental Water Samples. Chromatographia 81, 1475–1486 (2018). https://doi.org/10.1007/s10337-018-3590-5

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  • DOI: https://doi.org/10.1007/s10337-018-3590-5

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