Abstract
Correlation between the rheology and morphology of PVDF/LLDPE blends as well as the effect of LLDPE-g-MA compatibilizer on the microstructure and viscoelastic properties of these blends were studied in detail. Morphology development from matrix-dispersed to co-continuous and again to dispersed-matrix was well predicted using various linear viscoelastic analyses and confirmed via direct SEM experiments and continuity index analysis. Compatibilization induced alteration in the microstructure of the blends, particularly PVDF/PE 50/50 blend from co-continuous morphology to dispersed-matrix one, was also concluded from viscoelastic analysis and confirmed. It was shown that the feeding order had a distinct effect on morphology of the blends near the phase inversion composition. “Phase within a phase within a phase” morphology was observed near the phase inversion region, provided that the components are fed simultaneously. Different melting and crystallization temperature range of PVDF and PE phases was understood to be the main reason of this observation. It was also shown that compatibilization had higher impact on LLDPE-rich blends than PVDF-rich blends, while narrowed the co-continuity composition range.
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References
Willemse RC, Ramaker EJJ, Dam JV, Posthuma de Boer A (1999) Morphology development in immiscible polymer blends: initial blend morphology and phase dimensions. Polymer 40:6651–6659
Utracki LA (1990) Polymer alloys and blends: thermodynamics and rheology. Hanser, Munuch
Sperling LH (1997) Polymeric multicomponent materials. Wiley, New York
Han CD (1981) Multiphase flow in polymer processing. Academic Press, New York
Razavi Aghjeh MK, Khodabandelou M, Khezrefaridi M (2009) Rheology and morphology of high impact polystyrene/polyethylene blends and the effect of compatibilization on their properties. J Appl Polym Sci 114:2235–2245
Joseph S, Thomas S (2003) Morphology development and mechanical properties of polystyrene/polybutadiene blends. Eur Polym J 39:115–125
Fina A, Han Z, Saracco G, Gross U, Mainil M (2012) Morphology and conduction properties of graphite-filled immiscible PVDF/PP-g-MA blends. Polym Adv Technol 23:1572–1579
Cao JP, Zhao J, Zhao X, You F, Yu H, Hu GH, Dang ZM (2013) High thermal conductivity and high electrical resistivity of poly(vinylidene fluoride)/polystyrene blends by controlling the localization of hybrid fillers. Compos Sci Technol 89:142–148
Huang J, Mao C, Zhu Y, Jiang W, Yang X (2014) Control of carbon nanotubes at the interface of a co-continuous immiscible polymer blend to fabricate conductive composites with ultralow percolation thresholds. Carbon 73:267–274
Li Y, Shimizu H (2008) Conductive PVDF/PA6/CNTs nanocomposites fabricated by dual formation of co-continuous and nanodispersion structures. Macromolecules 41:5339–5344
Zhao X, Zhao J, Cao JP, Wang X, Chen M, Dang ZM (2013) Tuning the dielectric properties of polystyrene/poly(vinylidene fluoride) blends by selectively localizing carbon black nanoparticles. J Phys Chem 117:2505–2515
Yang J, Feng C, Dai J, Zhang N, Huang T, Wang Y (2012) Compatibilization of immiscible nylon 6/poly(vinylidene fluoride) blends using graphene oxides. Polym Int 62:1085–1093
Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H (1991) Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black. Polym Bull 25:265–271
Su C, Xu L, Zhang C, Zhu J (2011) Selective location and conductive network formation of multiwalled carbon nanotubes in polycarbonate/poly(vinylidene fluoride) blends. Compos Sci Technol 71:1016–1021
Zhang C, Yi XS, Yui H, Asai S, Sumita M (1998) Selective location and double percolation of short carbon fiber filled polymer blends: high-density polyethylene/isotactic polypropylene. Mater Lett 36:186–190
Wang D, Bao Y, Zha JW, Zhao J, Dang ZM, Hu GH (2012) Improved dielectric properties of nanocomposites based on poly(vinylidene fluoride) and poly(vinyl alcohol)-functionalized graphene. ACS Appl Mater Interfaces 4:6273–6279
Mohamadi S, Sharifi Sanjani N, Foyouhi A (2013) Evaluation of graphene nanosheets influence on the physical properties of PVDF/PMMA blend. J Polym Res 20:46–56
He F, Lau S, Chan HL, Fan J (2009) High dielectric permittivity and low percolation threshold in nanocomposites based on poly(vinylidene fluoride) and exfoliated graphite nanoplates. Adv Mater 21:710–715
Lin X, Fan LL, Zhao J, Dang ZM, Ren DY (2015) Effect of the compatibility on dielectric performance and breakdown strength of poly(vinylidene fluoride)/low-density polyethylene blends. J Appl Polym Sci 132:42507
Kaseem M, Hamad K, Yang HW, Lee YH, Deri F, Ko YG (2015) Melt rheology of poly(vinylidene fluoride) (PVDF)/low density polyethylene (LDPE) blends. Polym Sci Ser A 57:233–238
Omonov TS, Harrats C, Moldenaers P, Groeninckx G (2007) Phase continuity detection and phase inversion phenomena in immiscible polypropylene/polystyrene blends with different viscosity ratios. Polymer 48:5917
Faker M, Razavi Aghjeh MK, Ghaffari M, Seyyedi SA (2008) Rheology, morphology and mechanical properties of polyethylene/ethylene vinyl acetate copolymer (PE/EVA) blends. Eur Polym J 44:1834–1842
Sarazin P, Favis BD (2003) Morphology control in co-continuous poly(L-lactide)/ polystyrene blends: a route towards highly structured and interconnected porosity in poly(L-lactide) materials. Biomacromolecules 4:1669–1679
Mehrabi Mazidi M, Razavi Aghjeh MK (2015) Effects of blend composition and compatibilization on the melt rheology and phase morphology of binary and ternary PP/PA6/EPDM blends. Polym Bull 72:1975–2000
Basseri G, Mehrabi Mazidi M, Hosseini F, Razavi Aghjeh MK (2014) Relationship among microstructure, linear viscoelastic behavior and mechanical properties of SBS triblockcopolymer compatibilized PP/SAN blend. Polym Bull 71:465–486
Krache R, Benachour D, Potschke P (2004) Binary and ternary blends of polyethylene, polypropylene and polyamide 6,6: the effect of compatibilization on the morphology and rheology. J Appl Polym Sci 94:1976–1985
Hemmati M, Nazokdast H, Shariatpanahi H (2001) Study on morphology of ternary polymer blends. II Effect of composition. J Appl Polym Sci 82:1138–1146
Wu D, Zhang Y, Zhang M, Zhou W (2008) Phase behavior and its viscoelastic response of polylactide/poly (e-caprolactone) blend. Eur Polym J 44:2171–2183
Li R, Yu W, Zhou C (2006) Rheological characterization of droplet-matrix versus co-continuous morphology. J Macromol Sci Phys 45:889–898
Achaby MEL, Arrakhiz FZ, Vaudreuil S, Essassi EM, Qaiss A, Bousmina M (2013) Preparation and characterization of melt-blended graphene nanosheets–poly(vinylidene fluoride) nanocomposites with enhanced properties. J Appl Polym Sci 127:4697–4707
Ke K, Wang Y, Yang W, Xie BH, Yang MB (2012) Crystallization and reinforcement of poly(vinylidene fluoride) nanocomposites: role of high molecular weight resin and carbon nanotubes. Polym Test 31:117–126
Li J, Wu X, Liu Z (2013) Non-isothermal crystallization of poly(vinylidene fluoride)/multiwalled carbon nanotube composites. Int J Polym Anal Charact 18:83–92
Furukawa T, Sato H, Kita Y, Matsukawa K, Yamaguhi H, Ochiai S, Siesler HW, Ozaki Y (2006) Molecular structure, crystallinity and morphology of polyethylene/polypropylene blends studied by Raman mapping, scanning electron microscopy, wide angle x-ray diffraction and differential scanning calorimetry. Polym J 38:1127–1136
Krupa I, Luyt AS (2000) Thermal properties of uncross-linked and cross-linked LLDPE/wax blends. Polym Degrad Stab 70:111–117
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Jameie Oskooie, A., Razavi Aghjeh, M.K., Rafeie, O. et al. Composition and compatibilization induced morphology alteration in PVDF/LLDPE blends: correlation between rheology and morphology. J Polym Res 24, 21 (2017). https://doi.org/10.1007/s10965-017-1183-x
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DOI: https://doi.org/10.1007/s10965-017-1183-x