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Solution properties of amphoteric macromolecular dyes derived from poly(acrylamide-co-vinylamine)

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Abstract

Amphoteric macromolecular (AM) dyes with different degrees of substitution were synthesized by grafting a poly(acrylamide-co-vinylamine) oligomer with reactive dye. Solution properties of these AM dyes were measured as functions of pH, salt content, the degree of substitution, and concentration of AM dye solutions. The results of the potentiometric and conductometric titrations showed that the first transition at pH ∼10.5 corresponds to the onset of protonation of primary amino groups of AM dyes. and the second transition at pH ∼2.5 corresponds to the end of protonation of the primary amino groups. The results of the solubility behavior and zeta potential experiment exhibited that the AM dyes are precipitated near the isoelectric point, and the soluble pH region of the AM dyes can be controlled by changing the ratio of amino to sulfonate groups in these dyes. The viscosity behaviors exhibited that these AM dyes possessed low viscosity, only several mPa⋅s.

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Acknowledgments

This work was supported by the National Key Technology R&D Program (2011BAE07B01) and the Youth Foundation of Nanjing Xiaozhuang University (2013NXY92).

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Authors and Affiliations

  1. School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing, 211171, China

    Jingjing Yang & Jian Li

  2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China

    Bingtao Tang & Shufen Zhang

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  1. Jingjing Yang
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  2. Jian Li
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  3. Bingtao Tang
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  4. Shufen Zhang
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Correspondence to Jingjing Yang or Shufen Zhang.

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Yang, J., Li, J., Tang, B. et al. Solution properties of amphoteric macromolecular dyes derived from poly(acrylamide-co-vinylamine). J Polym Res 22, 13 (2015). https://doi.org/10.1007/s10965-015-0659-9

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  • DOI: https://doi.org/10.1007/s10965-015-0659-9

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