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Effect of CuPc@MWCNTs on rheological, thermal, mechanical and dielectric properties of polyarylene ether nitriles (PEN) terminated with phthalonitriles

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Abstract

In this work, multi-walled carbon nanotubes (MWCNTs) were successfully enwrapped by a thin layer of phthalocyanine copper (CuPc) via solvent-thermal method to obtain the core-shell CuPc@MWCNTs hybrid materials, which were confirmed by SEM and TGA characterization. The optical spectroscopy including FTIR and UV–vis were used for probing the surface chemical modification of MWCNTs. Thereafter, CuPc@MWCNTs/polyarylene nitrile ethers (PEN) composite films were prepared via solution-casting method. Based on the SEM and rheological characterization of polymer composites, CuPc@MWCNTs hybrid materials show good dispersion and compatibility in the PEN polymer matrix, leading to the excellent thermal, mechanical and dielectric properties.

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Acknowledgments

The authors wish to thank for financial support of this work from the National Natural Science Foundation (No.51173021, No.51373028) and "863" National Major Program of High Technology (2012AA03A212)

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Authors and Affiliations

  1. Research Branch of Advanced Functional Materials, Institute of Microelectronics & Solid State Electronics, High-Temperature Resistant Polymers and Composites Key Laboratory of Sichuan Province, University of Electronic Science & Technology of China, Chengdu, 610054, People’s Republic of China

    Ya Long, Zejun Pu, Xu Huang, Kun Jia & Xiaobo Liu

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  1. Ya Long
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  2. Zejun Pu
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  3. Xu Huang
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  4. Kun Jia
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  5. Xiaobo Liu
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Correspondence to Kun Jia or Xiaobo Liu.

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Long, Y., Pu, Z., Huang, X. et al. Effect of CuPc@MWCNTs on rheological, thermal, mechanical and dielectric properties of polyarylene ether nitriles (PEN) terminated with phthalonitriles. J Polym Res 21, 525 (2014). https://doi.org/10.1007/s10965-014-0525-1

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  • DOI: https://doi.org/10.1007/s10965-014-0525-1

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