Abstract
Two new copolymers based on methylmethacrylate (MMA) with methacrylamide (MAA) and methacrylic acid (MA) containing distributed phenanthrenequinone (PQ) molecules are fabricated for the purpose of optical recording by generating holographic diffractive structures under argon laser illumination. Chemical conditions for the formation of holograms are discussed and confirmed by the spectral characteristics of the material. Thermal and adhesive properties were improved with the aim of expanding the range of polymer application and generating of diffractive elements with long term stability and high optical quality.
Similar content being viewed by others
References
Lin S, Chen P, Hsiao Y, Whang W (2008) Fabrication and characterization of poly(methyl methacrylate) photopolymer doped with 9,10-phenanthrenequinone (PQ) based derivatives for volume holographic data storage. Opt Commun 281:559–566
Mahilny UV, Marmysh DN, Tolstik AL, Matusevich V, Kowarschik R (2008) Phase hologram formation in highly concentrated phenanthrenequinone–PMMA media. J Opt A: Pure Appl Opt 085302
Steckman GJ, Solomatine I, Zhou G, Psaltis D (1998) Characterization of phenanthrenequinone-doped poly(methyl methacrylate) for holographic memory. Opt Lett 23:1310–1312
Russo JM, Kostuk RK (2007) Temperature dependence properties of holographic gratings in phenanthrenquinone doped poly(methyl methacrylate) photopolymers. Appl Opt 46:7494–7499
Veniaminov A, Bartsch E, Popov A (2005) Postexposure evolution of a photoinduced grating in a polymer material with phenanthrenequinone. Opt Spectr 99:744–750
Liu H, Yu D, Li X, Luo S, Jiang Y, Sun X (2010) Diffusional enhancement of volume gratings as an optimized strategy for holographic memory in PQ-PMMA photopolymer. Opt Expr 18:6447–6454
Tolstik E, Kashin O, Matusevich A, Matusevich V, Kowarschik R (2008) Nonlocal response in the glass-like polymer storage materials based on poly (methylmethacrylate) with distributed phenantrenequinone. Opt Expr 16:11253–11258
Luo Y, Gelsinger PJ, Barton JK, Barbastathis G, Kostuk RK (2008) Optimization of multiplexed holographic gratings in PQ-PMMA for spectral-spatial imaging filters. Opt Lett 33:566–568
Kashin O, Tolstik E, Matusevich V, Kowarschik R (2009) Numerical investigation of the (1 + 1)D self-trapping of laser beams in polymeric films based on polymethylmethacrylate and phenanthrenequinone. J Opt Soc Am B 26:2152–2156
Tolstik E, Kashin O, Matusevich V, Kowarschik R (2011) Broadening of the light self-trapping due to thermal defocusing in PQ-PMMA polymeric layers. Opt Expr 19:2739–2747
Tolstik E, Winkler A, Matusevich V et al (2009) PMMA-PQ photopolymers for head-up-displays. IEEE Ph Techn Lett 21:784–786
Matusevich V, Tolstik E, Winkler A, Kowarschik R (2010) Head-up-displays from plexiglas. J Photonik 2:44–45
Krul LP, Matusevich V, Hoff D et al (2007) Modified polymethylmethacrylate as a base for thermostable optical recording media. Opt Expr 15:8543–8549
Kuo S-W, Kao H-C, Chang F-C (2003) Thermal behavior and specifical interaction in high-glass transition temperature PMMA copolymers. Polymer 44:6873–6882
Yakimtsova L, Egorova E, Murashko E, Matusevich Y, Polikarpov A, Krul L (2008) Thermomechanical properties and heat resistance of copolymers of methyl methacrylate with acrylic acid. Rus J Appl Chem 81:668–671
Matusevich V, Matusevich A, Kowarschik R, Matusevich YI, Krul LP (2008) Holographic volume absorption grating in glass-like polymer recording material. Opt Expr 16:1552–1558
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tolstik, E., Egorova, E., Hoff, D. et al. New thermostable copolymers for holographic storage based on methylmethacrylate with methacrylamide or methacrylic acid. J Polym Res 19, 9742 (2012). https://doi.org/10.1007/s10965-011-9742-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10965-011-9742-z