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Preparation of diblock copolymer PBA-b-PSt by DPE method in emulsion

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Abstract

Diblock copolymer poly (butyl acrylate)-b-polystyrene (PBA-b-PSt) was prepared by two steps in a complete emulsion system, using DPE (1, 1-diphenylethylene) as free radical control agent. In the first step, butyl acrylate (BA), initiator potassium peroxodisulfate (KPS) and DPE were emulsion polymerized to form P(BA-DPE) precursor. Then the precursor was heated in the presence of a second monomer styrene (St), and block copolymer was synthesized successfully. The structures, molecular weight of precursor and block copolymer were characterized by FTIR, UV–VIS, 1H-NMR and SEC/MALLS. Influence of DPE on polymerization kinetics was also investigated. Meantime, thermal properties of block copolymer were analyzed by TGA and DSC.

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References

  1. Bassani A, Pessan LA, Hage E (2001) J Appl Polym Sci 82:2185–2193

    Article  CAS  Google Scholar 

  2. Kazunori K, Atsushi H, Yukio N (2001) Adv Drug Deliv Rev 47:113–131

    Article  Google Scholar 

  3. Geneviève G, Marie-Hélène D, Vinayak PS et al (2005) J Control Release 109:169–188

    Article  Google Scholar 

  4. Annette R, Guido WMV, Harm-Anton K (2001) Adv Drug Deliv Rev 53:95–108

    Article  Google Scholar 

  5. Jin-shan W, Krzysztof M (1995) J Am Chem Soc 117:5614–5615

    Article  Google Scholar 

  6. Jian L, Zhidan S, Yingpeng Z et al (2010) J Polym Res 17:551–556

    Article  Google Scholar 

  7. David GH, Graeme M, Ezio R et al (1999) Macromolecules 32:5457–5459

    Article  Google Scholar 

  8. Michael KG, Richard PNV, Peter MK et al (1993) Macromolecules 26:2987–2988

    Article  Google Scholar 

  9. Parisa S, Mojtaba A, Ali AE (2007) J Polym Res 14:45–52

    Article  Google Scholar 

  10. Michael FC (2002) Prog Polym Sci 27:1039–1067

    Article  Google Scholar 

  11. Michael FC (2008) Prog Polym Sci 33:365–398

    Article  Google Scholar 

  12. Philipp CW, Benedikt R, Oskar N (2001) Macromol Rapid Commun 22:700–703

    Article  Google Scholar 

  13. Zongtao W, Zhang ZC (2005) Radiat Phys Chem 74:331–337

    Article  Google Scholar 

  14. Zongtao W, Zhang ZC (2007) J Appl Polym Sci 105:3492–3499

    Article  Google Scholar 

  15. Dong C, Zhifeng F, Yan S (2008) Polym Bull 60:259–269

    Article  Google Scholar 

  16. Dong C, Yan S, Zhifeng F (2009) J Appl Polym Sci 111:1581–1587

    Article  Google Scholar 

  17. Feige G, Qiuyu Z, Baoliang Z et al (2009) Polymer 50:1887–1894

    Article  Google Scholar 

  18. Feige G, Qiuyu Z, Hepeng Z et al (2010) J Polym Res. doi:10.1007/s10965-010-9471-8

    Google Scholar 

  19. Sophie V, Klaus T, Markus A et al (2002) Polymer 43:7231–7241

    Article  Google Scholar 

  20. Sophie V, Markus A, Klaus T et al (2003) Polymer 44:1339–1351

    Article  Google Scholar 

  21. Sophie V, Klaus T, Markus A et al (2005) Polymer 46:7843–7854

    Article  Google Scholar 

  22. Wolfgang B, Benedikt R (2002) Prog Org Coat 45:95–99

    Article  Google Scholar 

  23. Ying-Da L, I-Chen C, Wen-Yen C et al (2009) J Polym Sci A Polym Chem 47:4435–4445

    Article  Google Scholar 

  24. Cochin D, Laschewsky A, Nallet F (1997) Macromolecules 30:2278–2287

    Article  CAS  Google Scholar 

  25. Chorng-Shyan C, Shi-Yow L, Li-Jen C et al (1997) Polymer 38:1977–1984

    Article  Google Scholar 

  26. Tomaz K, Christine S, Yusuf Y et al (2005) Eur Polym J 41:1265–1271

    Article  Google Scholar 

  27. Simons WW, Zanger M (1973) Sadtler Res Labs Inc

  28. Jessica G, Ian M (2009) Polymer 50:5384–5389

    Article  Google Scholar 

  29. Davis KA, Matyjaszewski K (2002) Adv Polym Sci 159:34

    Google Scholar 

  30. Gaynor SG, Matyjaszewski K (1997) Macromolecules 30:4241–4245

    Article  CAS  Google Scholar 

  31. Nicolas G, Alain G, Jerome C (2003) J Polym Sci A Polym Chem 41:684–698

    Article  Google Scholar 

  32. Mario E, Eduardo G, Margarita GP et al (2008) Polymer 49:5650–5658

    Article  Google Scholar 

  33. Chia-Fen L, Yu-Hsia C, Wen-Yen C (1998) J Appl Polym Sci 69:13–23

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Key Laboratory of Applied Physics and Chemistry in Space of Ministry of Education, School of Science, Northwestern Polytechnical University, Xi’an, 710072, China

    Wenwen Wang, Qiuyu Zhang, Feige Guo, Junwei Gu & Changjie Yin

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  1. Wenwen Wang
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  2. Qiuyu Zhang
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  3. Feige Guo
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  4. Junwei Gu
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  5. Changjie Yin
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Correspondence to Wenwen Wang or Qiuyu Zhang.

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Wang, W., Zhang, Q., Guo, F. et al. Preparation of diblock copolymer PBA-b-PSt by DPE method in emulsion. J Polym Res 18, 1229–1235 (2011). https://doi.org/10.1007/s10965-010-9541-y

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  • DOI: https://doi.org/10.1007/s10965-010-9541-y

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