Skip to main content
SpringerLink
Log in

Polymer-metal complexes of phenolic resin with Ln (III): thermal, catalytic and antimicrobial aspects

  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

The polycondensation of 2-hydroxy-4-ethoxybenzophenone with 1, 3 butane diol was carried out in presence of polyphosphoric acid as a catalyst at 155 °C for 10 h to synthesize desired resin. The resin was used to synthesize polymer-metal complexes with 4f-block elements. The resin and its polymer-metal complexes were characterized on the basis of elemental analyses, electronic spectra, magnetic susceptibilities, FTIR, NMR and Thermogravimetric analyses. Morphology of resin and its polymer-metal complexes was studied by SEM. Catalytic activity of selected polymer-metal complexes in organic synthesis was examined. Antimicrobial activity of polymer-metal complexes against Escherichia coli, Bacillus subtilis, Staphylococcus aureus (bacteria) and Saccharomyces cerevisiae (yeast) were measured. It is observed that polymer-metal complexes are efficient and effective catalysts and antimicrobial agents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Scheme 3
Fig. 2
Scheme 4

Similar content being viewed by others

References

  1. Carlucci L, Ciani G, Proserpio DM (2003) Coord Chem Rev 246(1–2):247. doi:10.1016/S0010-8545(03)00126-7

    Article  CAS  Google Scholar 

  2. Manners I (1999) Pure Appl Chem 71(8):1471. doi:10.1351/pac199971081471

    Article  CAS  Google Scholar 

  3. Manners I (2002) J Polym Sci Part Polym Chem 40(2):179. doi:10.1002/pola.10069

    Article  CAS  Google Scholar 

  4. Cyr PW, Tzolov M, Manners I, Sargent EH (2003) Macromol Chem Phys 204(7):915. doi:10.1002/macp.200390061

    Article  CAS  Google Scholar 

  5. Kaya I, Cihangiroglu N (2004) J Polym Res 11:37. doi:10.1023/B:JPOL.0000021746.50347.34

    Article  CAS  Google Scholar 

  6. Nair VA, Mustafa SM, Krishnapillai S (2003) J Polym Res 10:267. doi:10.1023/B:JPOL.0000004629.53837.b3

    Article  CAS  Google Scholar 

  7. Eddaoudi M, Li H, Yaghi OM (2000) J Am Chem Soc 122(7):1391. doi:10.1021/ja9933386

    Article  CAS  Google Scholar 

  8. Guo X, Chen M, Tianhong Lu T, Huang X (2008) J Polym Res 15:141. doi:10.1007/s10965-007-9153-3

    Article  CAS  Google Scholar 

  9. Parac-Vogt TN, Binnemans K (2004) Tetrahedron Lett 45(15):3137. doi:10.1016/j.tetlet.2004.02.084

    Article  CAS  Google Scholar 

  10. Gaona-Tiburcio C, Almeraya-Caldero’n F, Chacon-Nava JG, Matutes-Aquino JA, Martinez-Villafan’e A (2004) J Alloy Comp 369(1–2):78. doi:10.1016/j.jallcom.2003.09.050

    Article  CAS  Google Scholar 

  11. Cao RD, Sun F, Liang YC Y, Hong MC, Tatsumi K, Shi Q (2002) Inorg Chem 41:2087. doi:10.1021/ic0110124

    Article  CAS  Google Scholar 

  12. Lin HM, Qing CX, Qian M, Ping XH (2005) Russ J Coord Chem 31(5):368. doi:10.1007/s11173-005-0106-2

    Article  CAS  Google Scholar 

  13. Evans CH (1992) Biochemistry of the Lanthanides, vol 8. Plenum press, New York and London

    Google Scholar 

  14. Shah TB, Patel HS, Dixit RB (2001) Int J Polymeric Mater 49(3):271. doi:10.1080/00914030108039779

    Article  CAS  Google Scholar 

  15. Patel MM, Kapadia MA, Patel GP, Joshi JD (2007) J Appl Polym Sci 106(2):1307. doi:10.1002/app.26711

    Article  CAS  Google Scholar 

  16. Stanier RY (1986) Introduction to the Microbial World, 5th edn. Prentice Hall Inc, NJ, p 16

    Google Scholar 

  17. Vogel AI (1978) A Text Book of Quantitative Inorganic Analysis, 4th edn. Longmans Green and Co. Ltd., London

    Google Scholar 

  18. Dwivedi DK, Shukla RK, Shukla BK (1991) Acta Cienc Indica Chem 17c (14): 383, Chem Abstr 117:14241n, (1992)

  19. Ursu M, Frey H, Neuner I, Thomann R, Rusu M (2004) Rep Romanian Phys 56(3):445

    Google Scholar 

  20. Ahamad T, Kumar V, Nishat N (2006) Polym Int 55(12):1398. doi:10.1002/pi.1999

    Article  CAS  Google Scholar 

  21. Nikolaev AV, Logvinenko VA, Myachina LT (1969) Thermal Analysis. Academic Press, New York, p 79

    Google Scholar 

  22. Pittman CW Jr, Voes RL, Elder J (1971) Macromolecules 5:302. doi:10.1021/ma60021a008

    Article  Google Scholar 

  23. Upadhyaya HD, Patel PP, Patel MM (1990) Synth React Inorg Met-Org Chem 20:1153. doi:10.1080/00945719008048625

    Article  Google Scholar 

  24. Patel MM, Kapadia MA, Patel GP, Joshi JD (2007) J Appl Polym Sci 106(2):1307. doi:10.1002/app.26711

    Article  CAS  Google Scholar 

  25. Shah BA, Shah AV, Shah PM (2006) Iran. Polym J 15(10):809

    CAS  Google Scholar 

  26. Samal S, Das RR, Dey RK, Acharya S (2000) J Appl Polym Sci 77(5):967. doi:10.1002/1097-4628(20000801)77:5<967::AID-APP3>3.0.CO;2-5

    Article  CAS  Google Scholar 

  27. Gudasi KB, Havanur VC, Patil SA, Patil BR (2007) Metal-Based Drugs . doi:10.1155/2007/37348

    Google Scholar 

  28. Kappe CO (2000) Eur J Med Chem 35:1043. doi:10.1016/S0223-5234(00)01189-2

    Article  CAS  Google Scholar 

  29. Overman LE, Rabiniwitz MH, Renhowe PA (1995) J Am Chem Soc 117(9):2657. doi:10.1021/ja00114a034

    Article  CAS  Google Scholar 

  30. Partha P, Baruah PP, Gadhwal S, Prajapati D, Sandhu JS (2002) Chem Lett 31(10):1038

    Google Scholar 

  31. Sabita G, Reddy KK, Reddy KB, Yadav JS (2003) Tetrahedron Lett 44(34):6497. doi:10.1016/S0040-4039(03)01564-8

    Article  Google Scholar 

  32. Paraskar AS, Dewkar GK, Sudalai A (2003) Tetrahedron Lett 44(16):3305. doi:10.1016/S0040-4039(03)00619-1

    Article  CAS  Google Scholar 

  33. Nishat N, Ahmad S, Ahamad RT (2006) J Appl Polym Sci 100(2):928. doi:10.1002/app.23064

    Article  CAS  Google Scholar 

  34. Nishat N, Ahmad S, Ahamad RT (2006) J Appl Polym Sci 101(3):1347. doi:10.1002/app.23036

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The authors thank the Heads of the, Department of Chemistry and Bioscience, Sardar Patel University, Vallabh Vidyanagar, for providing laboratory facilities. One of the authors (MMP) is thankful to UGC, New Delhi, for the award of a research fellowship for meritorious students (RFSMS).

Author information

Authors and Affiliations

  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388 120, Gujarat, India

    Mihir Patel, Malav Kapadia & Jayantilal Joshi

Authors
  1. Mihir Patel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Malav Kapadia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jayantilal Joshi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jayantilal Joshi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Patel, M., Kapadia, M. & Joshi, J. Polymer-metal complexes of phenolic resin with Ln (III): thermal, catalytic and antimicrobial aspects. J Polym Res 16, 755–765 (2009). https://doi.org/10.1007/s10965-009-9282-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10965-009-9282-y

Keywords

Search

Navigation