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Synthesis and reactivity of metal-containing monomers

74. Azomethine copper complexes as modifying agents of epoxy matrices

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Abstract

The effect of additives of copper azomethine complexes of different structure on the character of polycondensation and physicomechanical properties of the obtained metal-containing epoxy polymers was studied. It was shown by the DSC method that the thermal stability of the starting CuII azomethine complexes depended on their structure and nature of polar functional groups. The physicomechanical properties of the unmodified and modified epoxyamine polymers at different ratios of functional groups were compared. The additives of CuII azomethine complexes of 0.42–0.43 wt.% were shown to increase the impact strength of the polymers at the ratio [NH]/EG = 1.07–1.13 (EG is epoxy group).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    B. A. Komarov, A. T. Kapasharov, E. A. Dzhavadyan, V. A. Lesnichaya, G. I. Dzhardimalieva & A. D. Pomogailo

  2. Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    A. S. Burlov, A. I. Uraev & S. A. Mashchenko

  3. Southern Scientific Center, 41 ul. Chekhova, 344006, Rostov-on-Don, Russian Federation

    D. A. Garnovskii

Authors
  1. B. A. Komarov
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  2. A. T. Kapasharov
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  3. E. A. Dzhavadyan
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  4. V. A. Lesnichaya
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  5. G. I. Dzhardimalieva
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  6. A. S. Burlov
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  7. A. I. Uraev
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  8. S. A. Mashchenko
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  9. D. A. Garnovskii
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  10. A. D. Pomogailo
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Corresponding author

Correspondence to B. A. Komarov.

Additional information

For Part 73, see Ref. 1.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0936–0942, April, 2015.

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Komarov, B.A., Kapasharov, A.T., Dzhavadyan, E.A. et al. Synthesis and reactivity of metal-containing monomers. Russ Chem Bull 64, 936–942 (2015). https://doi.org/10.1007/s11172-015-0958-7

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  • DOI: https://doi.org/10.1007/s11172-015-0958-7

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