Abstract
The effect of additives of copper azomethine complexes of different structure on the character of polycondensation and physicomechanical properties of the obtained metal-containing epoxy polymers was studied. It was shown by the DSC method that the thermal stability of the starting CuII azomethine complexes depended on their structure and nature of polar functional groups. The physicomechanical properties of the unmodified and modified epoxyamine polymers at different ratios of functional groups were compared. The additives of CuII azomethine complexes of 0.42–0.43 wt.% were shown to increase the impact strength of the polymers at the ratio [NH]/EG = 1.07–1.13 (EG is epoxy group).
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For Part 73, see Ref. 1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0936–0942, April, 2015.
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Komarov, B.A., Kapasharov, A.T., Dzhavadyan, E.A. et al. Synthesis and reactivity of metal-containing monomers. Russ Chem Bull 64, 936–942 (2015). https://doi.org/10.1007/s11172-015-0958-7
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DOI: https://doi.org/10.1007/s11172-015-0958-7