Abstract
In this paper a certain type of reaction–diffusion equation—similar to the Allen-Cahn equation—is the starting point for setting up a genuine thermodynamic reduction i.e. involving a finite number of parameters or collective variables of the initial system. We firstly operate a finite Lyapunov–Schmidt reduction of the cited reaction–diffusion equation when reformulated as a variational problem. In this way we gain a finite-dimensional ODE description of the initial system which preserves the gradient structure of the original one and that is exact for the static case and only approximate for the dynamic case. Our main concern is how to deal with this approximate reduced description of the initial PDE. To start with, we note that our approximate reduced ODE is similar to the approximate inertial manifold introduced by Temam and coworkers for Navier–Stokes equations. As a second approach, we take into account the uncertainty (loss of information) introduced with the above mentioned approximate reduction by considering the stochastic version of the ODE. We study this reduced stochastic system using classical tools from large deviations, viscosity solutions and weak KAM Hamilton–Jacobi theory. In the last part we suggest a possible use of a result of our approach in the comprehensive treatment non equilibrium thermodynamics given by Macroscopic Fluctuation Theory.
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Notes
E.g. \(\mathcal {H}\) is the Sobolev space \(W^{2,2}_0(\Omega ;\mathbb {R})\).
By applying twice (2.34), we write \(\left| \Delta ^1 \chi \right| ^2 \ge \Lambda \left| \Delta ^\frac{1}{2} \chi \right| ^2 \ge \Lambda ^2 \left| \Delta ^0 \chi \right| ^2\), from which it follows \( \left| \Delta \chi \right| \ge \Lambda \left| \chi \right| \).
We recall that for the reduced equation the set of critical points is in a one-to-one correspondence with the equilibria of the original reaction–diffusion equation.
Precisely, we consider the Fokker–Planck equation (3.2) with a factor \(\nu /2\) in front of the Laplacian.
When considering lattice gas model, the above introduced continuity equation is the hydrodynamic limit equation for density \(\rho (x,t) \) which in turn is the limit of the empirical density \(\rho _N (z,t)\) of particles in a given point z on the lattice \(\Lambda \subset \mathbb {Z}^d\) with N particles. In the thermodynamic limit \(N \rightarrow \infty \) the empirical density \(\rho _N\) satisfies a large deviations principle, [21].
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Cardin, F., Favretti, M. & Lovison, A. Inertial Manifold and Large Deviations Approach to Reduced PDE Dynamics. J Stat Phys 168, 1000–1015 (2017). https://doi.org/10.1007/s10955-017-1845-4
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DOI: https://doi.org/10.1007/s10955-017-1845-4
Keywords
- Non-equilibrium thermodynamics
- Lyapunov–Schmidt reduction
- Inertial manifolds
- Collective variables
- Fokker–Planck equation
- Hamilton–Jacobi equation
- Large deviations