Abstract
We consider the mean-field classical Heisenberg model and obtain detailed information about the total spin of the system by studying the model on a complete graph and sending the number of vertices to infinity. In particular, we obtain Cramér- and Sanov-type large deviations principles for the total spin and the empirical spin distribution and demonstrate a second-order phase transition in the Gibbs measures. We also study the asymptotics of the total spin throughout the phase transition using Stein’s method, proving central limit theorems in the sub- and supercritical phases and a nonnormal limit theorem at the critical temperature.
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Acknowledgements
The authors thank Enzo Marinari and Giovanni Gallavotti for illuminating discussions.
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K. Kirkpatrick is partially supported by NSF grants OISE-0730136 and DMS-1106770. E. Meckes is partially supported by the American Institute of Mathematics and NSF grant DMS-0852898.
Appendix
Appendix
1.1 A.1 Calculus of Φ β
Recall that the free energy is obtained by minimizing the function
In the following lemmas, we explicitly identify the minima for all β>0, and obtain an estimate used in the proof of Theorem 10.
Lemma 21
If β≤3, then
achieved only at x=0.
Proof
We show first that the expression to be minimized is increasing. Differentiating the expression in question yields
Expanding sinh(x) in a Taylor series,
The problem is therefore reduced to showing that
or alternatively,
Clearly showing this for β=3 suffices to prove the lemma. Rearranging yet again, this is equivalent to showing that
Expanding coth(x) in terms of e 2x and rearranging terms, this is furthermore equivalent to showing that
Expanding e 2x in a Taylor series, the left-hand side of the inequality above is given by
It is easy to see that the n=3 and n=4 terms in the power series above are zero and that the rest are all positive, thus completing the proof that the expression to be minimized is increasing. Moreover, recall that \(\lim_{x\to0} \coth(x)-\frac{1}{x}=0\) and \(\lim_{x\to0}\frac{x}{\sinh(x)}=1\), so
□
Lemma 22
For β>3, there is a unique value of x∈(0,∞) which minimizes
over [0,∞).
Proof
From the previous proof, we have that the derivative of the expression to be minimized is
for x near zero. For β>3, it follows that x=0 is a local maximum of the expression on [0,∞). As x tends to infinity, the expression to be minimized is asymptotic to log(x), and there is therefore at least one interior minimum. Since \(\frac{1}{x^{2}}-\frac{1}{\sinh^{2}(x)}>0\), it must be the case that at this interior minimum,
that is,
In fact, the function \(g(x)=\frac{x}{\coth(x)-\frac{1}{x}}\) is strictly increasing on (0,∞), and this equation thus uniquely determines x in terms of β. First observe that
and it thus suffices to show that
for x>0; multiplying through by xsinh2(x), one could equivalently show that
Using the identities \(\sinh(x)\cosh(x)=\frac{\sinh(2x)}{2}\) and \(\sinh^{2}(x)=\frac{\cosh(2x)-1}{2}\), this is equivalent to showing that
Expanding the left-hand side in Taylor series yields
all of whose terms are indeed positive. □
Lemma 23
Let k 2 denote the unique value of x∈(0,∞) with
Then
In particular, if
then \(\varPhi_{\beta}'(k_{2})=0\) and \(\varPhi_{\beta}''(k_{2})> 0\).
Proof
Let
so that f(k 2)=0; as was shown in the previous proof, this uniquely defines k 2 in terms of β. Moreover, it was also shown that lim x→0 f(x)=0, lim x→∞ f(x)=∞, and lim x→0 f′(x)<0. That is, f is initially decreasing from 0, and then becomes increasing eventually, crossing the x-axis exactly once in (0,∞). It must therefore be that there is an x<k 2 such that f′(x)=0. Now,
In fact, \(g(x):=\frac{1}{x^{2}}-\frac{1}{\sinh^{2}(x)}\) is decreasing on (0,∞): observe first that
and so the claim is true if \(\coth(x)\operatorname {csch}^{2}(x)<x^{-3}\). By the definitions of the hyperbolic trigonometric functions, this is equivalent to
Expanding in power series, this is equivalent to
Letting α:=i−1, β:=j−1, and γ=k−1, the coefficient of x n on the right-hand side is
It is now easy to see that the coefficient of x n on the right-hand side is smaller than the one on the left for each n≥3, and so it is in fact true that \(g(x):=\frac{1}{x^{2}}-\frac{1}{\sinh^{2}(x)}\) is decreasing on (0,∞). It follows that f′(x) is increasing on (0,∞), and so the previously identified x<k 2 such that f′(x)=0 is in fact the only zero of f′, and f′(k 2)>0.
Now, recall from the proof of the previous lemma that
The value k 2 was in fact determined by the fact that \(\varPhi_{\beta}'(k_{2})=0\). Moreover,
and so
□
1.2 A.2 Proof of Theorem 19
This section is devoted to the proof of the abstract approximation theorem used in Sect. 6. For convenience, we recall the statement.
Theorem 19
Let (W,W′) be an exchangeable pair of positive random variables. Suppose there exists a σ-field \(\mathcal{F}\supseteq\sigma(W)\) and k>0 deterministic such that
and
Let X have density
Then there are constants C 1, C 2, C 3 depending only on c such that for all \(h\in C^{2}(\mathbb{R})\),
In any version of Stein’s method, a crucial component is the characterization of the distribution of interest by a linear operator. The following lemma identifies the characterizing operator for the random variable X defined above.
Lemma 24
Let Y be a positive random variable. Then Y has density
if and only if
for all f∈C 1((0,∞)) such that \(\int_{0}^{\infty}f(t)t^{5}e^{-3ct^{2}}\,dt<\infty\). That is, the characterizing operator T p for the distribution with density p is defined by
Not only is the random variable X characterized by the operator above, but this operator is invertible on \(\{h:\mathbb{E}h(X)=0\}\), and the inverse has the following important boundedness properties.
Lemma 25
Let \(h:\mathbb{R}\to\mathbb{R}\) be given. Suppose that
with p as above. Then \([T_{p}f_{h}](x)=h(x)-\mathbb{E}h(X)\) and
-
(a)
∥f h ∥∞≤5∥h∥∞.
-
(b)
\(\|f_{h}'\|_{\infty}\le42\sqrt{c}\|h\|_{\infty}+3\|h'\|_{\infty}\).
-
(c)
\(\|f_{h}''\|_{\infty}\le C_{1}\|h\|_{\infty}+C_{2}\|h'\|_{\infty}+ C_{3}\|h''\|_{\infty}\), where C 1, C 2, C 3 are constants depending only on c.
With these two lemmas, the proof of Theorem 19 is relatively straightforward.
Proof of Theorem 19
Given h, let f be the solution to the Stein equation described above. Then by exchangeability and the conditions on (W,W′),
Then
and
The result is thus immediate from Lemma 25. □
We conclude by giving the proofs of the key lemmas.
Proof of Lemma 24
If Y has the density above, then the fact that Y satisfies (23) is just integration by parts.
For the reverse implication, one must solve the so-called Stein equation; i.e., given \(h:(0,\infty)\to\mathbb{R}\), find f=f h such that
where X has the density above. The solution f is given by
where \(p(s):=\frac{s^{5}}{z}e^{-3cs^{2}}\). Observe that
so that
Here we have made use of the fact, frequently used below, that
It is shown in the next lemma that f and f′ are both bounded, and so if Y satisfies (23), then if h is given and f solves the Stein equation,
and so \(Y\stackrel{d}{=}X\). □
Proof of Lemma 25
(a) By the first expression for f h , if \(t\le t_{o}:=\sqrt{\frac {5}{6c}}\), then
By the second expression for f h ,
It is easy to show directly that \(\mathbb{P}[X\ge t]\le\frac{p(t)}{6ct} (1+\frac{2}{3ct^{2}}+\frac {2}{9c^{2}t^{4}} )\), and so
for t≥t o . This completes the proof.
(b) Recall that, because f solves the Stein equation,
For t≤t o , observe that
Now,
making use of the fact that p(s)≤p(t) in this range. Also,
so that for t≤t o ,
and thus
If t≥t o , then
By the second expression for f,
making use again of the estimate \(\mathbb{P}[X\ge t]\le\frac{p(t)}{6ct} (1+\frac{2}{3ct^{2}}+\frac{2}{9c^{2}t^{4}} )\). Taking \(t_{o}=\sqrt{\frac{5}{6c}}\) as before and making some trivial simplifying estimates completes the proof of this part.
(c) Differentiating both sides of the Stein equation gives that
If t≤t o , then |12cf(t)|≤5c∥h∥∞ and by the Stein equation, |6ctf′(t)|≤36c∥f∥∞+12c∥h∥∞≤192c∥h∥∞. Also by the Stein equation,
The first term can be absorbed into the existing bound, so that
(From now on we will not bother to keep track of specific constants and their dependence on c.) Now,
Let \(H(t):=[h(t)-\mathbb{E}h(X)]e^{-3ct^{2}}\). Then
and so the equation above becomes
It follows that
Now,
so
All together, this gives that for t≤t o ,
where C 1, C 2, C 3 are constants depending only on c.
For t>t o , it follows from (24) and estimates already carried out that
By the Stein equation,
and
and so finally
□
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Kirkpatrick, K., Meckes, E. Asymptotics of the Mean-Field Heisenberg Model. J Stat Phys 152, 54–92 (2013). https://doi.org/10.1007/s10955-013-0753-5
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DOI: https://doi.org/10.1007/s10955-013-0753-5