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Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols (C3–C6) at Different Temperatures from Experimental and Theoretical Points of View

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Abstract

The densities, \(\rho\) and speeds of sound, u were measured for pure and the binary mixtures of monoethanolamine (MEA) + 1-alcohols (1-propanol, 1-butanol, 1-pentanol and 1-hexanol) at (298.15–318.15) K and the whole composition range. From the experimental data excess molar volumes, \({V}_{\text{m}}^{\text{E}}\), excess partial molar volumes, \({\overline{V}}_{i}^{\text{E}},\) excess thermal expansion coefficients, \({\alpha }^{\text{E}}\), isothermal coefficients of excess molar enthalpies, \((\partial {H}_{\text{m}}^{\text{E}}/\partial P)_{T,x}\), isentropic compressibility, \({k}_{\text{s}}^{ }\) and excess isentropic compressibilities, \({k}_{\text{s}}^{\text{E}}\) have been calculated for the binary systems. The excess molar volume and excess isentropic compressibility were correlated with the Redlich–Kister polynomial equation. The excess molar volumes and excess isentropic compressibilities were negative for all binary systems, except, for the system of MEA + 1-hexanol in which excess molar volume showed a sigmoid shape. The effect of temperature and chain length of alcohol on the excess molar volumes, \({V}_{\text{m}}^{\text{E}}\), and excess isentropic compressibilities, \({k}_{\text{s}}^{\text{E}}\), are discussed in terms of molecular interactions between unlike molecules. The Extended Real Associated Solution model was applied to correlate the excess molar volumes.

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Acknowledgements

We are thankful to Bu-Ali Sina University for providing the necessary facilities to carry out the work.

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Authors and Affiliations

  1. Department of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

    Fahime Forghani & Hossein Iloukhani

  2. Department of Chemistry, RAC Analytical Chemistry Laboratory, Hamedan, Iran

    Khatereh Khanlarzadeh

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  1. Fahime Forghani
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Correspondence to Hossein Iloukhani.

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Forghani, F., Iloukhani, H. & Khanlarzadeh, K. Volumetric and Acoustic Investigation on the Binary Mixtures of Monoethanolamine + 1-Alcohols (C3–C6) at Different Temperatures from Experimental and Theoretical Points of View. J Solution Chem 52, 385–412 (2023). https://doi.org/10.1007/s10953-022-01236-1

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