Skip to main content

Advertisement

SpringerLink
Log in

Experimental Study of the Density and Derived Partial Molar Volumes of Ternary Water + 1-Propanol + Potassium Nitrate Mixtures at Temperatures from (303 to 448) K and Pressures up to 35 MPa

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Densities of ternary water + 1-propanol + KNO3 mixtures have been measured over the temperature range from 303 to 448 K and at pressures up to 35 MPa using a constant-volume piezometer immersed in a precision liquid thermostat. The effect of salt and alcohol concentrations on the ternary mixture densities and partial molar volumes were studied. The derived volumetric property such as partial molar volumes of the salt (KNO3, \( \bar{V}_{2}^{{}} \)) and the alcohol (1-propanol, \( \bar{V}_{1}^{{}} \)) were calculated using the measured values of the densities. The volumetric behavior of the ternary mixtures was interpreted in terms of changes in the water structure caused by the added alcohol and salt. It was shown that changes in the volumetric behavior of the complex solutions are the results of the structural changes in water structure caused by solutes (alcohol and salt).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Desai, K.G.H., Kulkarni, A.R., Aminabhavi, T.M.: Solubility of rofecoxib in the presence of methanol, ethanol, and sodium lauryl sulfate at (298.15, 303.15, and 308.15) K. J. Chem. Eng. Data 48, 942–945 (2003)

    Article  CAS  Google Scholar 

  2. Brown, D.T., Finney, J.L., Soper, A.K.: Structural investigation of solute–solvent interactions in aqueous solutions of tertiary butanol. J. Phys. Chem. B 102, 3551–3563 (1998)

    Article  Google Scholar 

  3. Arscon, P.G., Ma, C., Wenner, J.R.: DNA condensation by cobalt hexaammine(III) in alcohol–water mixtures: dielectric constant and other solvent effect. Bloonfield Biopolym. 36, 345–364 (1995)

    Article  Google Scholar 

  4. Widdel, F.: Growth of methanogenic bacteria in pure culture with 2-propanol and other alcohols as hydrogen donors. Appl. Environ. Microbiol. 51, 1056–1062 (1986)

    CAS  Google Scholar 

  5. Abdulagatov, I.M., Azizov, N.D.: Experimental study of the density and derived volumetric (excess, apparent, and partial molar volumes) properties of aqueous 1-propanol mixtures at temperatures from 298 to 582 K and pressures up to 40 MPa. J. Chem. Thermodyn. 71, 155–170 (2014)

    Article  CAS  Google Scholar 

  6. Abdulagatov, I.M., Akhmedova-Azizova, L.A., Azizov, N.D.: Experimental study of the density and derived (excess, apparent, and partial molar volumes) properties of binary water + ethanol and ternary water + ethanol + lithium nitrate mixtures at temperatures from 298 to 448 K and pressures up to 40 MPa. Fluid Phase Equilib. 376, 1–21 (2014)

  7. Krumgalz, B.S., Pogorelsky, R., Pitzer, K.S.: Volumetric properties of single aqueous electrolytes from zero to saturation concentration at 298.15 K represented by Pitzer’s ion-interaction equations. J. Phys. Chem. Ref. Data 25, 663–689 (1996)

    Article  CAS  Google Scholar 

  8. Millero, F.J.: In: Horne, R.A. (ed.) Water and Aqueous Solutions, Structure, Thermodynamics, and Transport Properties., Chapter 13. Wiley-Interscience, New York (1972)

  9. Domanin, D.V., Azizov, N.D., Zarembo, V.I.: Volumetric properties of aqueous potassium nitrate solutions at high temperatures and pressures. Russ. J. App. Chem. (Leningr.) 71, 212–215 (1998)

    CAS  Google Scholar 

  10. Traktuev, O.M., Ptistina, V.P.: Experimental study of the density of aqueous NaNO3, KNO3, and their mixtures. Dep. VINITI, Russ. N 3572-B29, 30.03 (1989)

  11. Gorbachev, S.V., Kondrat’ev, V.P., Androsov, V.I.: Specific volumes of potassium bromide, iodide and nitrate in water. Zh. Fiz. Khim. 48, 2675–2677 (1974)

    CAS  Google Scholar 

  12. Ellis, A.J., McFadden, J.M.: The partial molal volume of hydrochloric acid in high-temperature water. Chem. Commun. 9, 516–517 (1968)

    Google Scholar 

  13. Puchkov, L.V., Matashkin, V.G., Matveeva, R.P.: Density of aqueous solutions of sodium and potassioum nitrates in a wide concentration and temperature ranges (to 350 °C). Russ. J. App. Chem. (Leningr.) 52, 1015–1018 (1979)

    CAS  Google Scholar 

  14. Martínez-Andreu, A., Vercher, E., Peña, M.P.: Apparent molar volumes of strontium nitrate and copper(II) chloride in ethanol + water at 298.15 K. J. Chem. Eng. Data 44, 86–92 (1999)

    Article  Google Scholar 

  15. Peña, M.P., Vercher, E., Martínez-Andreu, A.: Apparent molar volumes of potassium nitrate and sodium nitrate in ethanol + water at 298.15 K. J. Chem. Eng. Data 43, 626–631 (1998)

    Article  Google Scholar 

  16. Peña, M.P., Vercher, E., Martínez-Andreu, A.: Apparent molar volumes of strontium chloride in ethanol + water at 298.15 K. J. Chem. Eng. Data 42, 187–189 (1997)

    Article  Google Scholar 

  17. Peña, M.P., Vercher, E., Martínez-Andreu, A.: Apparent molar volumes of strontium bromide in ethanol + water mixtures at 298.15 K. J. Chem. Eng. Data 40, 662–664 (1995)

    Article  Google Scholar 

  18. Vercher, E., Rojo, F., Martínez-Andreu, A.: Apparent molar volumes of calcium nitrate in 1-propanol + water at 298.15 K. J. Chem. Eng. Data 44, 1212–1215 (1999)

    Article  CAS  Google Scholar 

  19. Vercher, E., Dias, M., Vázquez, I., Martínez-Andreu, A.: Apparent molar volumes of lithium nitrate in 1-propanol + water in the temperature range from 298.15 to 318.15 K. Fluid Phase Equilib. 198, 131–145 (2002)

    Article  CAS  Google Scholar 

  20. Vercher, E., Solsona, S., Vázquez, I., Martínez-Andreu, A.: Apparent molar volumes of lithium chloride in 1-propanol + water in the temperature range from 288.15 to 318.15 K. Fluid Phase Equilib. 209, 95–111 (2003)

    Article  CAS  Google Scholar 

  21. Galleguillos, H.R., Taboada, M.E., Graber, T.A.: Compositions, densities, and refractive indices of potassium chloride + ethanol + water and sodium chloride + ethanol + water solutions at (298.15 and 313.15 K). J. Chem. Eng. Data 48, 405–410 (2003)

    Article  CAS  Google Scholar 

  22. Rehman, H., Ansari, M.S.: Density, viscosity, and electrical conductivity measurements on the ternary system H2O + C2H5OH + LiCl over the entire ranges of solvent composition and LiCl solubility from (−5 to 50) °C. J. Chem. Eng. Data 53, 2072–2088 (2008)

    Article  Google Scholar 

  23. Abdulagatov, I.M., Azizov, N.D.: Densities and apparent molar volumes of aqueous NaNO3 solutions at temperatures from 292 to 573 K and at pressures up to 30 MPa. J. Solution Chem. 32, 573–599 (2003)

    Article  CAS  Google Scholar 

  24. Abdulagatov, I.M., Azizov, N.D.: PVTx measurements and partial molar volumes for aqueous Li2SO4 solutions at temperatures from 297 to 573 K and pressures up to 40 MPa. Int. J. Thermophys. 24, 1581–1610 (2003)

    Article  CAS  Google Scholar 

  25. Abdulagatov, I.M., Azizov, N.D.: Densities and apparent molar volumes of aqueous H3BO3 solutions at temperatures from 296 to 573 K and at pressures up to 48 MPa. J. Solution Chem. 33, 1305–1331 (2004)

    Article  CAS  Google Scholar 

  26. Abdulagatov, I.M., Azizov, N.D.: Densities and apparent molar volumes of aqueous LiI solutions at temperatures from (296 to 600) K and at pressures up to 30 MPa. J. Chem. Thermodyn. 36, 829–843 (2004)

    Article  CAS  Google Scholar 

  27. Abdulagatov, I.M., Azizov, N.D.: Experimental vapor pressures and derived thermodynamic properties of aqueous solutions of lithium sulfate from 423 to 523 K. Fluid Phase Equlib. 216, 189–199 (2004)

    Article  CAS  Google Scholar 

  28. Corti, H.R., Abdulagatov, I.M.: PVTx properties of hydrothermal systems. In: Valyashko, V.M. (ed.) Hydrothermal Properties of Materials. Experimental Data on Aqueous Phase Equilibria and Solution Properties at Elevated Temperatures and Pressures, Chapter 2, pp. 135–193. John Wiley & Sons, London (2009)

  29. Wagner, W., Pruß, A.: New international formulation for the thermodynamic properties of ordinary water substance for general and scientific use. J. Phys. Chem. Ref. Data 31, 387–535 (2002)

    Article  CAS  Google Scholar 

  30. Benson, G.C., Kiyohara, O.: Thermodynamics of aqueous mixtures of nonelectrolytes. I. Excess volumes of water–n-alcohol mixtures at several temperatures. J. Solution Chem. 9, 04–791 (1980)

    Google Scholar 

  31. Kubota, H., Tanaka, Y., Makita, T.: Volumetric behavior of pure alcohols and their water mixtures under high pressure. Int. J. Thermophys. 8, 47–70 (1987)

    Article  Google Scholar 

  32. Pečar, D., Doleček, V.: Volumetric properties of ethanol–water mixtures under high temperatures and pressures. Fluid Phase Equilib. 230, 36–44 (2005)

    Article  Google Scholar 

  33. Neal, J.I., Goring, D.A.: Volume–temperature relationships of hydrophobic and hydrophilic nonelectrolytes in water. J. Phys. Chem. 74, 658–664 (1970)

    Article  CAS  Google Scholar 

  34. Nakajima, T., Komatsu, T., Nakagawa, T.: Apparent molal volumes and adiabatic compressibilities of n-alkanols and α, ω-alkane diols in dilute aqueous solutions at 5, 25, and 45 °C. I. Apparent molal volumes. Bull. Chem. Soc. Jpn. 48, 783–787 (1975)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

I.M. Abdulagatov thanks the Applied Chemicals and Materials Division at the National Institute of Standards and Technology for the opportunity to work as a Guest Researcher at NIST during the course of this research.

Author information

Author notes

  1. Ilmutdin M. Abdulagatov

    Present address: Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO, 80305, USA

Authors and Affiliations

  1. Geothermal Research Institute of the Dagestan Scientific Center of the Russian Academy of Sciences, Makhachkala, Dagestan, Russia

    Ilmutdin M. Abdulagatov

  2. Department of Industrial Ecology and Industrial Safety Properties of Aqueous Systems, Azerbaijan Technical University, Baku, Azerbaijan

    Lala A. Akhmedova-Azizova

  3. Azerbaijan State Oil Academy, Baku, 370601, Azerbaijan

    Nazim D. Azizov

Authors
  1. Ilmutdin M. Abdulagatov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lala A. Akhmedova-Azizova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nazim D. Azizov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ilmutdin M. Abdulagatov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abdulagatov, I.M., Akhmedova-Azizova, L.A. & Azizov, N.D. Experimental Study of the Density and Derived Partial Molar Volumes of Ternary Water + 1-Propanol + Potassium Nitrate Mixtures at Temperatures from (303 to 448) K and Pressures up to 35 MPa. J Solution Chem 43, 2045–2066 (2014). https://doi.org/10.1007/s10953-014-0252-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-014-0252-6

Keywords

Search

Navigation