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Densities and Excess Molar Volumes of Alkane (Heptane, Octane, Nonane, or Decane) + Thiophene from T=293.15 to 313.15 K

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Abstract

Densities of four binary systems composed of an alkane (heptane, octane, nonane, or decane) and thiophene were measured at temperatures from 293.15 to 313.15 K at atmospheric pressure (0.7 atm). Measurements were made covering the full range of compositions for all systems studied and for the pure compounds by using a vibrating-tube densimeter (VTD). Excess molar volumes have been obtained from these experimental results and were fitted to a Redlich–Kister type expansion. The excess molar volumes exhibit positive deviations from ideal behavior for all of the binary systems studied here.

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References

  1. Zúñiga-Moreno, A., Galicia-Luna, L.A., Betancourt-Cárdenas, F.F.: Compressed liquid densities and excess volumes of CO2 + thiophene binary mixtures from 313 to 363 K and pressures up to 25 MPa. Fluid Phase Equilib. 236, 193–204 (2005)

    Article  Google Scholar 

  2. Camacho-Camacho, L.E., Galicia-Luna, L.A.: Experimental densities of hexane + benzothiophene mixtures from (313 to 363) K and up to 20 MPa. J. Chem. Eng. Data 52, 2455–2461 (2007)

    Article  CAS  Google Scholar 

  3. Juárez-Guerra, F.M., Rivera, J.L., Zúñiga-Moreno, A., Galicia-Luna, L.A., Rico, J.L., Lara, J.: Molecular modeling of thiophene in the vapor–liquid equilibrium. Sep. Sci. Technol. 41, 261–281 (2006)

    Article  Google Scholar 

  4. Yu, Z.-W., Liu, Y., Sun, X.-D.: Excess molar volumes of n-alkanes–thiophene mixtures at 25 °C. J. Solution Chem. 21, 497–506 (1992)

    Article  CAS  Google Scholar 

  5. Elizalde-Solis, O., Galicia-Luna, L.A.: Solubility of thiophene in carbon dioxide and carbon dioxide + 1-propanol mixtures at temperatures from 313 to 363 K. Fluid Phase Equilib. 230, 51–57 (2005)

    Article  CAS  Google Scholar 

  6. Gao, H., Xing, J., Li, Y., Li, W., Liu, Q., Liu, H.: Desulfurization of diesel fuel by extraction with Lewis-acidic ionic liquid. Sep. Sci. Technol. 44, 971–982 (2009)

    Article  CAS  Google Scholar 

  7. Huang, C., Chen, B., Zhang, J., Liu, Z., Li, Y.: Desulfurization of gasoline by extraction with new ionic liquids. Energy Fuels 18, 1862–1864 (2004)

    Article  CAS  Google Scholar 

  8. Bösmann, A., Datsevich, L., Jess, A., Lauter, A., Schmitz, C., Wasserscheid, P.: Deep desulfurization of diesel fuel by extraction with ionic liquids. Chem. Commun. 23, 2494–2495 (2001)

    Article  Google Scholar 

  9. Zhang, S., Zhang, Q., Zhang, Z.C.: Extractive desulfurization and denitrogenation of fuels using ionic liquids. Ind. Eng. Chem. Res. 43, 614–622 (2004)

    Article  CAS  Google Scholar 

  10. Redlich, O., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  11. Zúñiga-Moreno, A., Reza-San Germán, C.M., Rojas-Valencia, O.G., Juárez-Camacho, E.P.: Volumetric properties for the binary mixture nonane + decane at temperature from T=283.15 to 353.15 K and atmospheric pressure. J. Solution Chem. 40, 621–631 (2011)

    Article  Google Scholar 

  12. TRC Thermodynamic Tables—Hydrocarbons. Thermodynamics Research Center, The Texas A&M University System, College Station (1993)

  13. Aralaguppi, M.I., Jadar, C.V., Aminabhavi, T.M.: Density, refractive index, viscosity, and speed of sound in binary mixtures of cyclohexanone with hexane, heptane, octane, nonane, decane, dodecane, and 2,2,4-trimethylpentane. J. Chem. Eng. Data 44, 435–440 (1999)

    Article  CAS  Google Scholar 

  14. Aminabhavi, T.M., Patil, V.B.: Density, refractive index, viscosity, and speed of sound in binary mixtures of ethenylbenzene with hexane, heptane, octane, nonane, decane, and dodecane. J. Chem. Eng. Data 42, 641–646 (1997)

    Article  CAS  Google Scholar 

  15. Vijande, J., Piñeiro, M.M., García, J., Valencia, J.L., Legido, J.L.: Density and surface tension variation with temperature for heptane +1-alkanol. J. Chem. Eng. Data 51, 1778–1782 (2006)

    Article  CAS  Google Scholar 

  16. Fandiño, O., Pensado, A.S., Lugo, L., Comuñas, M.J.P., Fernández, J.: Compressed liquid densities of squalane and pentaerythritol tetra(2-ethylhexanoate). J. Chem. Eng. Data 50, 939–946 (2005)

    Article  Google Scholar 

  17. Landaverde-Cortes, D.C., Estrada-Baltazar, A., Iglesias-Silva, G.A.: Densities and viscosities of MTBE + heptane or octane at p=0.1 MPa from (273.15 to 363.15) K. J. Chem. Eng. Data 52, 1226–1232 (2007)

    Article  CAS  Google Scholar 

  18. González, B., Dominguez, A., Tojo, J.: Viscosities, densities and speeds of sound of the binary systems: 2-propanol with octane, or decane, or dodecane at T=(293.15,298.15, and 303.15) K. J. Chem. Thermodyn. 35, 939–953 (2003)

    Article  Google Scholar 

  19. Morávková, L., Wagner, Z., Aim, K., Linek, J.: (P,V m,T) Measurements of (octane + 1-chlorohexane) at temperatures from 298.15 K to 328.15 K and at pressures up to 40 MPa. J. Chem. Thermodyn. 38, 861–870 (2006)

    Article  Google Scholar 

  20. Pineiro, M.M., Garcia, J., De Cominges, B.E., Vijande, J., Valencia, J.L., Legido, J.L.: Density and surface tension variation with temperature for n-nonane + 1-hexanol. Fluid Phase Equilib. 245, 32–36 (2006)

    Article  CAS  Google Scholar 

  21. Pereira, S.M., Rivas, M.A., Real, J.N., Legido, J.L., Iglesias, T.P.: Densities, speeds of sound, and refractive indices of the mixture nonane + triethylene glycol dimethyl ether at 288.15 K, 293.15 K, 298.15 K, and 308.15 K. J. Chem. Eng. Data 47, 919–922 (2002)

    Article  CAS  Google Scholar 

  22. Queimada, A.J., Marrucho, I.M., Coutinho, J.A.P., Stenby, E.H.: Viscosity and liquid density of asymmetric n-alkane mixtures: Measurement and modeling. Int. J. Thermophys. 26, 47–61 (2005)

    Article  CAS  Google Scholar 

  23. Fawcett, F.S., Rasmussen, H.E.: Physical properties of thiophene. J. Am. Chem. Soc. 67, 1705–1717 (1945)

    Article  CAS  Google Scholar 

  24. Ulagendran, V., Kumar, R., Jayakumar, S., Kannappan, V.: Ultrasonic and spectroscopic investigations of charge–transfer complexes in ternary liquid mixtures. J. Mol. Liq. 148, 67–72 (2009)

    Article  CAS  Google Scholar 

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Acknowledgements

We are grateful to Instituto Politécnico Nacional (IPN), and Consejo Nacional de Ciencia y Tecnología (CONACYT) of México for their financial support under grant projects: SIP20111066 and 80543, respectively. We also want to thank Dr. José Gonzalo Hernández Cortez for his help on GC analyses, and M.C. Sergio Alvarez Badillo for his assistance on literature data review of pure compounds.

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Authors and Affiliations

  1. Laboratorio de Investigación en Fisicoquímica y Materiales, Departamento de Ingeniería Química Industrial, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Edif. Z5, 2° piso, UPALM, Col. Zacatenco, Mexico D.F., Mexico

    Edgar Cisneros-Pérez, Carmen M. Reza-San Germán, María E. Manríquez-Ramírez & Abel Zúñiga-Moreno

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  1. Edgar Cisneros-Pérez
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  2. Carmen M. Reza-San Germán
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  3. María E. Manríquez-Ramírez
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  4. Abel Zúñiga-Moreno
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Correspondence to Abel Zúñiga-Moreno.

Glossary of Symbols Used in the Tables

Glossary of Symbols Used in the Tables

ρ (g⋅cm−3):

densities

V E (cm3⋅mol−1):

excess molar volumes

A i :

parameters of Redlich–Kister expansion (Eq. 4)

σ :

standard deviation

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Cisneros-Pérez, E., Reza-San Germán, C.M., Manríquez-Ramírez, M.E. et al. Densities and Excess Molar Volumes of Alkane (Heptane, Octane, Nonane, or Decane) + Thiophene from T=293.15 to 313.15 K. J Solution Chem 41, 1054–1066 (2012). https://doi.org/10.1007/s10953-012-9851-2

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  • DOI: https://doi.org/10.1007/s10953-012-9851-2

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