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Volumetric Properties of Dilute Solutions of Water in Acetone between 288.15 and 318.15 K

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Abstract

Densities of dilute solutions of water in acetone, with solute mole fractions ranging up to 0.03, have been measured with an error of 8 ×10−6 g⋅cm−3, at 288.15, 298.15, 308.15 and 318.15 K, using a precision vibrating-tube densimeter. The partial molar volumes of the solute water (down to infinite dilution) and solvent acetone, as well as the excess molar volumes of the specified mixtures, have been calculated. The effects of the solute concentration and temperature on the volume packing changes, caused by solvation of water in acetone, have been considered.

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Authors and Affiliations

  1. Laboratory of Thermodynamics of Solutions of Non-electrolytes and Biologically Active Substances, Institute of Solution Chemistry, Russian Academy of Sciences, 1 Akademicheskaya Street, 153045, Ivanovo, Russia

    Evgeniy V. Ivanov, Vladimir K. Abrosimov & Elena Y. Lebedeva

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  1. Evgeniy V. Ivanov
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  2. Vladimir K. Abrosimov
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  3. Elena Y. Lebedeva
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Correspondence to Evgeniy V. Ivanov.

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Ivanov, E.V., Abrosimov, V.K. & Lebedeva, E.Y. Volumetric Properties of Dilute Solutions of Water in Acetone between 288.15 and 318.15 K. J Solution Chem 37, 1261–1270 (2008). https://doi.org/10.1007/s10953-008-9301-3

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  • DOI: https://doi.org/10.1007/s10953-008-9301-3

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