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Study of the Ternary Complex Formation between Vanadium(III)-Cysteine and Small Blood Serum Bioligands

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Abstract

The complex species formed between vanadium(III) cysteine and small blood serum bioligands: lactic, oxalic, citric and phosphoric acids were studied in aqueous solution by means of electromotive force measurements, Emf(H), at 25 °C and 3.0 mol⋅dm−3 KCl as the ionic medium. The ternary complexes were studied by potentiometric measurements and the data analyzed using the least-squares computational program LETAGROP to obtain the respective stability constants and stoichiometric coefficients. The UV-Vis spectrophotometric measurements were done in order to make a qualitative characterization of the complexes formed in aqueous solution.

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Authors and Affiliations

  1. Departamento de Química, Universidad Simón Bolívar (USB), Apartado 89000, Caracas, 1080 A, Venezuela

    Héctor Rosas, Leidy Erika Sarmiento & Vito Lubes

  2. Centro de Equilibrios en Solución, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas, Venezuela

    María Goncalves, Mary Lorena Araujo & Felipe Brito

Authors
  1. Héctor Rosas
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  2. Leidy Erika Sarmiento
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  3. Vito Lubes
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  4. María Goncalves
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  5. Mary Lorena Araujo
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  6. Felipe Brito
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Corresponding author

Correspondence to Vito Lubes.

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Rosas, H., Sarmiento, L.E., Lubes, V. et al. Study of the Ternary Complex Formation between Vanadium(III)-Cysteine and Small Blood Serum Bioligands. J Solution Chem 37, 701–711 (2008). https://doi.org/10.1007/s10953-008-9264-4

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  • DOI: https://doi.org/10.1007/s10953-008-9264-4

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