Abstract
The excess molar volume (V E), viscosity deviations (Δη) and Gibbs excess energy of activation for viscous flow (G∗E) have been investigated from density (ρ) and viscosity (η) measurements of eight binary mixtures of 1,3-dioxolane with methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, t-butanol, and i-amyl alcohol over the entire range of mole fractions at 303.15 K. The viscosity data have been correlated with the Grunberg and Nissan equation. Furthermore, excess isentropic compressibilities (KSE) have been calculated from ultrasonic speed measurements of these binary mixtures at 303.15 K. The deviations have been fitted by a Redlich–Kister equation and the results are discussed in terms of molecular interactions and structural effects. The excess properties are found to be either negative or positive depending on the molecular interactions and the nature of the liquid mixtures. The systems studied exhibit very strong cross association through hydrogen bonding.
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M. N. Roy, A. Choudhury, and A. Sinha, J. Teach. Res. Chem. 11, 12 (2004).
D. K. Hazra, M. N. Roy, and B. Das, Indian J. Chem. Techno. 1, 93 (1994).
M. N. Roy and A. Choudhury, J. Teach. Res. Chem. 1, 17 (2000).
M. N. Roy, B. B. Gurung, and A. Choudhury, J. Indian Chem. Soc. 81, 1 (2004).
S. L. Oswal and H. S. Desai, Fluid Phase Equilib. 161, 191 (1999).
S. L. Oswal and H. S. Desai, Fluid Phase Equilib. 186, 81 (2001).
C. Lafuente, B. Giner, A. Villares, I. Gascon, and P. Cea, Int. J. Thermophys. 25, 1735 (2004).
P. S. Nikam, L. N. Shirsat, and M. Hasan, J. Indian Chem. Soc. 77, 244 (2000).
E. Perez, M. Cardoso, A. M. Mainar, J. I. Pardo, and J. S. Urieta, J. Chem. Eng. Data 48, 1306 (2003).
J. N. Nayak, T. M. Aminabhavi, and M. I. Aralaguppi, J. Chem. Eng. Data 48, 1152 (2003).
G. Douheret, A. Pal, and M. I. Davis, J. Chem. Thermodyn. 22, 1 (1990).
S. L. Oswal and K. D. Prajapati, J. Chem. Eng. Data. 43, 367 (1998).
J. R. Suindells and T. B. Godfray, J. Res. Natd. Bur. Stand. 48, 1 (1952).
M. N. Roy, A. Jha, and R. Dey, J. Chem. Eng. Data 46, 1247 (2001).
M. N. Roy, A. Jha, and A. Choudhury, J. Chem. Eng. Data 49, 291 (2004).
S. L. Oswal and H. S. Desai, Fluid Phase Equilib. 149, 359(1998).
D. D. Perrin and W. L. F. Armarego, Purification of Laboratory Chemicals, 3rd ed. (Pergamon, Great Britain, 1988).
J. Riddick, W. B. Bunger, and T. K Sakano, Organic Solvents: Physical Properties and Methods of Purification (Wiley, New York, 1986).
J. N. Gurtu and R. Kapoor, Adv. Exp. Chem. 1, 338, 346 (1987).
J. Timmermans, Physico Chemical Constants of Pure Organic Compounds (Elsevier, Amsterdam, 1950, 1; 1965, 2).
A. K. Covington and T. Dickinson, Physical Chemistry of Organic Solvent Systems (Plenum, New York, 1973).
A. W. Quin, D. F. Hoffmann, and P. Munk, J. Chem. Eng. Data 37, 55 (1992).
S. Glasstone, K. J. Laidler, and H. Eyring, The Theory of Rate Process (McGraw-Hill, New York, 1941, p. 514).
D. S. Gill, T. S. Kaur, H. Kaur, I. M. Joshi, and J. Singh, J. Chem. Soc., Faraday Trans. 89, 1737 (1993).
H. Artigas, C. Lafuente, M. C. Lopez, F. M. Royo, and J. S. Urieta, Zeit. Phys. Chem. 215, 933 (2001).
I. Gascon, S. Martin, P. Cea, M. C. Lopez, and F. M. Royo, J. Solution Chem. 31, 905 (2002).
F. Kimura, A. Treszczanowicz, C. Halpin, and G. Benson, J. Chem. Thermodyn. 15, 503 (1983).
L. Grunberg and A. H. Nissan, Nature 164, 799(1949).
O. Redlich and A. J. Kister, Ind. Eng. Chem. 40, 345 (1948).
D. W. Marquardt, J. Soc. Ind. Appl. Math. 11, 431 (1963).
M. C. S. Subha and K. C. Rao, J. Phys. Chem. Liq. 18, 185 (1988).
A. Assarsson and F. R. Eirich, J. Phys. Chem. 72, 2710 (1968).
E. A. Muller, J. Chem. Eng. Data 36, 214 (1991).
P. Brocos, E. Calvo, A. Pineiro, R. Bravo, and A. Amigo, J. Chem. Eng. Data 44, 1341 (1999).
A. Amigo, R. Bravo, and M. Pintos, J. Chem. Eng. Data 38, 141 (1993).
D. Papaioannou, M. Bridakis, and C. Panayiotou, J. Chem. Eng. Data 38, 616 (1993).
A. Krishnaiah and P. R. Naidu, Acta Chem. Acad. Sci. Hung. 104, 295 (1986).
D. S. Gill and T. S. Cheema, Z. Phys. Chem (N.F). 134, 205 (1983).
Y. Marcus, Ion Solvation (Wiley, New York, 1985).
M. G. Prolongo, R. M. Masegosa, H. I. Fuentes, and A. Horta, J. Phys. Chem. 88, 2163 (1984).
T. M. Reed and T. E. Taylor, J. Phys. Chem. 63, 58 (1959).
R. Meyer, M. Meyer, and J. Metzer, A. Peneloux. Chem. Phys. 62, 406 (1971).
A. J. Treszczanowicz, T. Treszczanowicz, T. Pawlowski, and T. K. Guttman, J. Solution Chem. 33, 1049 (2004).
R. J. Fort and W. R. Moore, Trans. Faraday Soc. 62, 1112 (1966).
K. Ramamoorthy, J. Pure. Appl. Phys. 11, 554 (1973).
P. S. Nikam and M. Hasan, J. Chem. Eng. Data 33, 165 (1988).
B. V. K. Naidu, K. C. Rao, and M. C. S. Subha, J. Indian Chem. Soc. 78, 259 (2001).
R. J. Fort and W. R. Moore, Trans. Faraday Soc. 61, 2102 (1965).
T. Takizawa and K. Tamura, J. Therm. Anal. Calorim. 69, 1075 (2002).
L. Pikkarainen, J. Chem. Eng. Data 33, 299 (1988).
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Roy, M.N., Sinha, A. & Sinha, B. Excess Molar Volumes, Viscosity Deviations and Isentropic Compressibility of Binary Mixtures Containing 1,3-Dioxolane and Monoalcohols at 303.15 K. J Solution Chem 34, 1311–1325 (2005). https://doi.org/10.1007/s10953-005-8022-0
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DOI: https://doi.org/10.1007/s10953-005-8022-0