Skip to main content
SpringerLink
Log in

Vapor Pressures, Osmotic and Activity Coefficients of Electrolytes in Protic Solvents at Different Temperatures. 2. Lithium Bromide in Ethanol

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Precise vapor pressure data for LiBr solutions in ethanol are given for temperatures ranging from 298.15 to 348.15 K. The molality range investigated is from 0.0705 to 3.4451 mol-kg−1. Osmotic coefficients are calculated by taking into account the second virial coefficient of ethanol. The parameters of the extended Pitzer ion-interaction model of Archer, the MSA-NRTL model, and the chemical model of Barthel are evaluated and discussed. The parameters of the extended Pitzer ion-interaction model of Archer are used to calculate the mean molal activity coefficients. Osmotic and activity coefficients both decrease with increasing temperature in this temperature range.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Nasirzadeh, N. Papaiconomou, R. Neueder, and W. Kunz, (2004)J. Solution Chem. 33, 227 .

    Article  Google Scholar 

  2. F. Mato and M. J. Cocero, (1988)J. Chem. Eng. Data 33, 38 .

    Google Scholar 

  3. M. T. Zafarani-Moattar and J. Jahanbin, (1999)Fluid Phase Equilib. 166, 207 .

    Article  Google Scholar 

  4. A. Nasehzadeh, E. Noroozian, and H. Omrani, (2004)J. Chem. Thermodyn. 36, 245 .

    Article  Google Scholar 

  5. D. G. Archer, (1991)J. Phys. Chem. Ref. Data 20, 509 .

    Google Scholar 

  6. D. G. Archer, (1992)J. Phys. Chem. Ref. Data 21, 793 .

    Google Scholar 

  7. N. Papaiconomou, J.-P. Simonin, O. Bernard, and W. Kunz, (2002)Phys. Chem. Chem. Phys. 4, 4435 .

    Article  Google Scholar 

  8. J. Barthel, R. Neueder, H. Poepke, and H. Wittmann, (1998)J. Solution Chem. 27, 1055 .

    Article  Google Scholar 

  9. J. Barthel, H. Krienke, and W. Kunz, Physical Chemistry of Electrolyte Solutions (Springer, Darmstadt, Germany, 1998).

    Google Scholar 

  10. P. Walden, H. Ulich, and F. Laun, (1925)Z. Phys. Chem. 114, 275 .

    Google Scholar 

  11. K. Nasirzadeh, D. Zimin, R. Neueder, and W. Kunz, (2004)J. Chem. Eng. Data 49, 607 .

    Article  Google Scholar 

  12. B. E. Poling, J. M. Prausnitz, and J. P. O’Connnell, The Properties of Gases and Liquids (McGraw-Hill, Boston, 2002).

    Google Scholar 

  13. J. Barthel and R. Neueder, Electrolyte Data Collection, Vol. XII, Part 1a (DECHEMA, Frankfurt, Germany, 1992).

    Google Scholar 

  14. D. G. Archer and J. A. Rard, (1998)J. Chem. Eng. Data 43, 791 .

    Article  Google Scholar 

  15. L. Blum, (1975)Mol. Phys. 30, 1529 .

    Google Scholar 

  16. H. Renon and J. M. Prausnitz, (1968)AIChE J. 14, 135 .

    Article  Google Scholar 

  17. C. C. Chen and L. B. Evans, (1982)AIChE J. 28, 4 .

    Google Scholar 

  18. H. Krienke, J. Barthel, M. Holovko, I. Protsykevich, and Yu. Kalyushnyi, (2000)J. Mol. Liq. 87, 191 .

    Article  Google Scholar 

  19. J. A. Rard, S. L. Clegg, and D. A. Palmer, (2000)J. Solution Chem. 29, 1 .

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Physikalische and Theoretische Chemie, Universität Regensburg, D-93040, Regensburg, Germany

    Karamat Nasirzadeh, Roland Neueder & Werner Kunz

  2. Department of Chemistry, Azarbaijan University of Tarbiat Moallem, Tabriz, Iran

    Karamat Nasirzadeh

Authors
  1. Karamat Nasirzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Roland Neueder
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Werner Kunz
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Karamat Nasirzadeh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nasirzadeh, K., Neueder, R. & Kunz, W. Vapor Pressures, Osmotic and Activity Coefficients of Electrolytes in Protic Solvents at Different Temperatures. 2. Lithium Bromide in Ethanol. J Solution Chem 33, 1429–1446 (2004). https://doi.org/10.1007/s10953-004-1057-9

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-004-1057-9

Search

Navigation