Abstract
Densities of sodium nitrobenzoate (o-, m-, p-) have been measured in dimethylformamide (DMF)–water mixtures at 298.15 K with an oscillating-tube densimeter. From these densities, apparent molar volumes of sodium nitrobenzoate in DMF–H2O-mixtures have been calculated and partial molar volumes at infinite dilution have been evaluated. Substituent and solvent effects on the transfer volumes of each isomer from water to DMF–H2O-mixed solvents have also been obtained. The results are explained in terms of solvent–solvent and solute–solvent interactions.
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Li, SQ., Yu, JM. & Lin, RS. Volumetric Properties of Sodium Nitrobenzoate in N, N-Dimethylformamide–Water Mixtures at 298.15 K. J Solution Chem 33, 1367–1377 (2004). https://doi.org/10.1007/s10953-004-1048-x
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DOI: https://doi.org/10.1007/s10953-004-1048-x