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Viscosity behavior of benzoic acid and benzoate ion in aqueous solution

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Abstract

Relative viscosities of aqueous solutions of benzoic acid and benzoates of lithium, sodium, potassium, and ammonium are measured. In the temperature range 25–35°C, the Jones-Dole viscosityB coefficients of the benzoate ion decrease with increasing temperature, indicating a net structure-making effect. The somewhat larger value of theB coefficient for the benzoate ion than that for the benzoic acid molecule confirms similar behavior for the acetate ion and acetic acid in aqueous solutions although the effect is much smaller.

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References

  1. W. M. Cox and J. H. Wolfenden,Proc. Roy. Soc. London, Ser. A 145, 475 (1934).

    Google Scholar 

  2. V. D. Laurence and J. H. Wolfenden,J. Chem. Soc. 1144 (1934).

  3. R. W. Gurney,Ionic Processes in Solution (Dover, New York, 1962), pp. 4, 149.

    Google Scholar 

  4. P. K. Mandal, B. K. Seal, and A. S. Basu,Z. Physi. Chem. (N.F.) 82, 236 (1972).

    Google Scholar 

  5. G. Jones and M. Dole,J. Am. Chem. Soc. 51, 2950 (1929).

    Google Scholar 

  6. H. Falkenhagen and E. L. Vernon,Phys. Z. 33, 140 (1932).

    Google Scholar 

  7. R. L. Kay, T. Vituccio, C. Zawoyski, and D. F. Evans,J. Phys. Chem. 70, 2336 (1966).

    Google Scholar 

  8. N. P. Yao and D. N. Benion,J. Phys. Chem. 75, 1727 (1971).

    Google Scholar 

  9. M. Kaminsky,Disc. Faraday Soc. 24, 171 (1957).

    Google Scholar 

  10. R. H. Stokes and R. Mills,Viscosity of Electrolytes and Related Properties (Pergamon Press, 1965), p. 37.

  11. E. R. Nightingale, Jr., and R. F. Benck,J. Phys. Chem. 63, 1777 (1959).

    Google Scholar 

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Mandal, P.K., Chatterjee, D.K., Seal, B.K. et al. Viscosity behavior of benzoic acid and benzoate ion in aqueous solution. J Solution Chem 7, 57–62 (1978). https://doi.org/10.1007/BF00654218

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  • DOI: https://doi.org/10.1007/BF00654218

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