Abstract
Relative viscosities of aqueous solutions of benzoic acid and benzoates of lithium, sodium, potassium, and ammonium are measured. In the temperature range 25–35°C, the Jones-Dole viscosityB coefficients of the benzoate ion decrease with increasing temperature, indicating a net structure-making effect. The somewhat larger value of theB coefficient for the benzoate ion than that for the benzoic acid molecule confirms similar behavior for the acetate ion and acetic acid in aqueous solutions although the effect is much smaller.
Similar content being viewed by others
References
W. M. Cox and J. H. Wolfenden,Proc. Roy. Soc. London, Ser. A 145, 475 (1934).
V. D. Laurence and J. H. Wolfenden,J. Chem. Soc. 1144 (1934).
R. W. Gurney,Ionic Processes in Solution (Dover, New York, 1962), pp. 4, 149.
P. K. Mandal, B. K. Seal, and A. S. Basu,Z. Physi. Chem. (N.F.) 82, 236 (1972).
G. Jones and M. Dole,J. Am. Chem. Soc. 51, 2950 (1929).
H. Falkenhagen and E. L. Vernon,Phys. Z. 33, 140 (1932).
R. L. Kay, T. Vituccio, C. Zawoyski, and D. F. Evans,J. Phys. Chem. 70, 2336 (1966).
N. P. Yao and D. N. Benion,J. Phys. Chem. 75, 1727 (1971).
M. Kaminsky,Disc. Faraday Soc. 24, 171 (1957).
R. H. Stokes and R. Mills,Viscosity of Electrolytes and Related Properties (Pergamon Press, 1965), p. 37.
E. R. Nightingale, Jr., and R. F. Benck,J. Phys. Chem. 63, 1777 (1959).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mandal, P.K., Chatterjee, D.K., Seal, B.K. et al. Viscosity behavior of benzoic acid and benzoate ion in aqueous solution. J Solution Chem 7, 57–62 (1978). https://doi.org/10.1007/BF00654218
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00654218