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Effect of Cu Addition on the Microstructure and Magnetic Properties of the Nd-Fe-B Melt-Spun Ribbons

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Abstract

Microstructure and magnetic properties are systematically investigated to figure out what effect does the Cu content have on (Pr0.25Nd0.75)2Fe13.85-xCo0.1Ti0.05CuxB alloys in this work. The experimental result shows the optimal magnetic properties that the remanent magnetization Jr = 1.13 T, the coercivity Hcj = 588.56 kA/m, and the maximum magnetic energy product (BH)max = 260.66 kJ/m3 at the Cu content x = 0.6. However, it shows that Cu addition can promote the formation of the amorphous phase, which is an important reason for the coercivity decrease. Microstructure observation indicates that the reason for the magnetic property decrease is that the hard 2:14:1 magnetic phases and soft α-Fe phases display a state of irregular distribution with Cu content increasing.

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References

  1. Kaneko, Y., Kuniyoshi, F., Ishigaki, N.: Proven technologies on high-performance Nd-Fe-B sintered magnets. J. Alloy. Compd. 408–412, 1344–1349 (2006). https://doi.org/10.1016/j.jallcom.2005.04.169

    Article  Google Scholar 

  2. Peng, H., Luo, Y., Dou, Y., Yang, Y., Wang, Z., Yan, W., Xie, J., Yu, D., Diao, S.: Significant coercivity enhancement of Ti doping in Nd-Ce-Fe-B melt spun alloys. J. Magn. Magn. Mater. 477, 323–328 (2019). https://doi.org/10.1016/j.jmmm.2019.01.054

    Article  ADS  Google Scholar 

  3. Zhang, P., Ma, T., Liang, L., Liu, X., Wang, X., Jin, J., Zhang, Y., Yan, M.: Improved corrosion resistance of low rare-earth Nd-Fe-B sintered magnets by Nd6Co13Cu grain boundary restructuring. J. Magn. Magn. Mater. 379, 186–191 (2015). https://doi.org/10.1016/j.jmmm.2014.12.044

    Article  ADS  Google Scholar 

  4. Wang, J., Meng, Y., Zhang, H., Tang, H., Lin, R., Sun, C., Wu, C., Xie, F.: The characteristic of crystal growth of Nd-Fe-B cast strips during the rapid solidification process. J. Magn. Magn. Mater. 396, 283–287 (2015). https://doi.org/10.1016/j.jmmm.2015.08.004

    Article  ADS  Google Scholar 

  5. Wan, F., Zhang, Y., Han, J., Liu, S., Liu, T., Zhou, L., Fu, J., Zhou, D., Zhang, X., Yang, J., Yang, Y., Chen, J., Deng, Z.: Coercivity enhancement in Dy-free Nd-Fe-B sintered magnets by using Pr-Cu alloy. J. Appl. Phys. 115, 203910 (2014). https://doi.org/10.1063/1.4879898

    Article  ADS  Google Scholar 

  6. Xu, X.D., Dong, Z.J., Sasaki, T.T., Tang, X., Sepehri-Amin, H., Ohkubo, T., Hono, K.: Influence of Ti addition on microstructure and magnetic properties of a heavy-rare-earth-free Nd-Fe-B sintered magnet. J. Alloy. Compd. 806, 1267–1275 (2019). https://doi.org/10.1016/j.jallcom.2019.07.289

    Article  Google Scholar 

  7. Matsuura, M., Sugimoto, S., Fukada, T., Goto, R., Tezuka, N.: Effect of Cu addition on coercivity and interfacial state of Nd-Fe-B/Nd-rich thin films. J. Phys: Conf. Ser. 200, 82019 (2010). https://doi.org/10.1088/1742-6596/200/8/082019

    Article  Google Scholar 

  8. X. Chi, Y. Li, X. Han, J. Sun, Y. Zhang, C. Cui, Effect of Cu addition on the structure and magnetic properties of SmCo3.1-xFe0.9CuxB ribbons. J. Magn. Magn. Mater. 465, 524–530 (2018). https://doi.org/10.1016/j.jmmm.2018.06.049

  9. L. Wang, J. Wang, M. Rong, G. Rao, H. Zhou, Effect of wheel speed on phase formation and magnetic properties of (Nd0.4La0.6)-Fe-B melt-spun ribbons. J. Rare Earths 36, 1179–1183 (2018). https://doi.org/10.1016/j.jre.2018.02.013

  10. Hussain, M., Zhao, L.Z., Zhang, C., Jiao, D.L., Zhong, X.C., Liu, Z.W.: Composition-dependent magnetic properties of melt-spun La or/and Ce substituted nanocomposite Nd-Fe-B alloys. Phys. B 483, 69–74 (2016). https://doi.org/10.1016/j.physb.2015.12.033

    Article  ADS  Google Scholar 

  11. Pandian, S., Chandrasekaran, V., Markandeyulu, G., Iyer, K., Rao, K.: Effect of Co, Dy and Ga on the magnetic properties and the microstructure of powder metallurgically processed Nd-Fe-B magnets. J. Alloy. Compd. 364, 295–303 (2004). https://doi.org/10.1016/S0925-8388(03)00541-3

    Article  Google Scholar 

  12. Gholamipour, R., Beitollahi, A., Marghusian, V.K., Ohkubo, T.: Cu effects on coercivity and microstructural features in nanocrystalline Nd-Fe-Co-B annealed melt-spun ribbons. Phys. B 398, 51–54 (2007). https://doi.org/10.1016/j.physb.2007.04.087

    Article  ADS  Google Scholar 

  13. Ma, Q., Hu, Z., Zhang, Z., Liu, Y., Zhang, X., Liu, F., Ju, X., Li, Z., Wang, G., Li, Y.: The effect of Nd8Cu2 alloy on the microstructure and magnetic properties of (Nd, MM)-Fe-B sintered magnets. J. Magn. Magn. Mater. 484, 345–349 (2019). https://doi.org/10.1016/j.jmmm.2019.04.028

    Article  ADS  Google Scholar 

  14. Zhang, J.S., Zhong, M.L., Zhao, L.Z., Liao, X.F., Zeng, H.X., Zhong, X.C., Yu, H.Y., Zhong, Z.C., Liu, Z.W.: Reducing Dy content by Ce substitution in nanocomposite Nd-Dy-Fe-B/α-Fe alloys. J. Alloy. Compd. 766, 1061–1066 (2018). https://doi.org/10.1016/j.jallcom.2018.07.057

    Article  Google Scholar 

  15. Mc. Zhang, Sc. Zhou, Zc. Wang, Beneficial effects of Cu substitution on the microstructures and magnetic properties of Pr (Fe, Co) B/α-(Fe, Co) nanocomposites. J.  Alloys. Compd. 309, 212–218 (2018). https://doi.org/10.1016/S0925-8388(00)01050-1

  16. Peng, H., Luo, Y., Dou, Y., Bai, X., Yan, W., Yu, D., Yang, Y., Diao, S.: Effects of cerium substitution on phase components, microstructures and magnetic properties of Nd-Fe-Ti-B alloy. J. Rare Earths 37, 861–864 (2019). https://doi.org/10.1016/j.jre.2018.10.008

    Article  Google Scholar 

  17. Pan, M., Li, Z., Wu, Q., Ge, H., Xu, H.: Study of the role of Ti doping on magnetic properties of some nanocomposite alloys of α-Fe/Nd2Fe14B type. J. Magn. Magn. Mater. 471, 457–463 (2019). https://doi.org/10.1016/j.jmmm.2018.09.097

    Article  ADS  Google Scholar 

  18. G.S. Tan, H. Xu, L.Y. Yu, X.H. Tan, Q. Zhang, Y. Gu, X.L. Hou, Study on magnetic properties of (Nd0.8Ce0.2)2-xFe12Co2B (x=0–0.6) alloys. J. Magn. Magn. Mater 437, 7–22 (2017). https://doi.org/10.1016/j.jmmm.2017.04.032

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Funding

This work was supported by the Natural Science Foundation of China (Grant No. 51761007) and the Natural Science Foundation of Guangxi (Grant No. 2021GXNSFDA075009).

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The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

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Correspondence to Qingrong Yao or Huaiying Zhou.

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Wang, K., Huang, W., Xie, J. et al. Effect of Cu Addition on the Microstructure and Magnetic Properties of the Nd-Fe-B Melt-Spun Ribbons. J Supercond Nov Magn 34, 3369–3376 (2021). https://doi.org/10.1007/s10948-021-05993-w

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