Abstract
In this work, the phase transitions, for a molecular-based magnet, are examined using mean field method (MFM). The longitudinal magnetizations can be achieved by minimizing the free energy is an interesting function for locating and induction of spin compensation temperatures as well. By applying Blume-Capel (BC) configuration to a system consisting of two sublattices for a mixed spin-3/2 and spin-7/2on a square lattice in the anisotropies plane, the ground-state phase diagram of this system has been built. On principles of Bogoliubov inequality (BI) of the free energy, it has been investigated the spin compensation phenomena. In particular, characteristic ferrimagnetic features have been shown depending on an unequal crystal field parameters (DA, DB<-1.0) applied on the A−sites and B−sites, respectively.
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Mohamad, H.K., Zuhair, A. Ground-State Phase Diagram of a Mixed Spin-3/2 and Spin-7/2 Ising Model: A Study of Complex [Cr(CN)4(μ-CN)2Gd(H2O)4-(bpy)]n.4nH2O.1.5nbpy. J Supercond Nov Magn 33, 1481–1487 (2020). https://doi.org/10.1007/s10948-019-05352-w
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DOI: https://doi.org/10.1007/s10948-019-05352-w