Skip to main content
SpringerLink
Log in

Synthesis, Structural Studies, and Magnetic Properties of a New Mixed-Valence Diphosphate: Zn2+5Fe3+2(P2O7)4

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

A new mixed-valence diphosphate, Zn2+5Fe3+2(P2O7)4, was synthesized from FeII5FeIII2(P2O7)4 via the “solid way” route, by substitution of FeII by ZnII. The obtained X-ray data confirmed the crystallization of the compound in the C2221 symmetry space group (orthorhombic). Magnetic measurements were performed showing that, at room temperature, the compound is paramagnetic and that the Néel temperature is 15.44(20) K. The compound was also investigated by infrared and Raman spectroscopies, in particular to characterize the (P2O7)4− and M–O vibrations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Mayr, W.: Biochem. J. 2, 585–591 (1988)

    Article  Google Scholar 

  2. Bonnet, P., Millet, J.M.M., Leclercq, C., Védrine, J.C.: J. Catal. 158, 128–141 (1996)

    Article  Google Scholar 

  3. Bonnet, P., Millet, J.M.M.: J. Catal. 161, 198–205 (1996)

    Article  Google Scholar 

  4. Health Risks of Heavy Metals from Long-range Transboundary Air Pollution, Annual Report of the World Health Organization (2007)

  5. Biney, C., Amuzu, A.T., Calamari, D., Kaba, N., Mbome, I.L., Naeve, H., Ochumba, O., Osibanjo, O., Radegonde, V., Saad, M.A.H.: FAO Fish. Rep. (1992)

  6. 1ères Assises Nationales de R&D Autour des Phosphates: Skhirat. (2013)

  7. Terebilenko, K.V., Kirichok, A.A., Baumer, V.N., Sereduk, M., Slobodyanik, N.S., Gütlich, P.: J. Solid State Chem. 183(6), 1473–1476 (2010)

    Article  ADS  Google Scholar 

  8. Barpanda, P., Liu, G., Mohamed, Z., Ling, C.D., Yamada, A.: Solid State Ionics. 268, 305–311 (2014)

    Article  Google Scholar 

  9. Abadi, S., Aride, J., Benkhouja, K., Haddad, M., Taibi, M.: Arab. J. Chem. (2017)

  10. Malaman, B., Ijjaali, M., Gerardin, R., Venturini, G., Gleitzer, C.: Eur. J. Solid State Inorg. Chem. 29, 1269–1284 (1992)

    Google Scholar 

  11. Boudin, S., Grandin, A., Labbe, P.H., Grebille, D., Nguyen, N., Ducourelle, A., Raveau, B.: J. Solid State Chem. 121, 291–300 (1996)

    Article  ADS  Google Scholar 

  12. Elbelghitti, A., Boukhari, A.: Acta Crystallogr. Sect. C. 50, 1648–1650 (1994)

    Article  Google Scholar 

  13. Lamsaf, H., Fausto, R., Costa, B.F.O., Toyir, J., Elghadraoui, E.H., Ijjaali, M., Oulmekki, A.: Mater. Chem. Phys. 216, 22–27 (2018)

    Article  Google Scholar 

  14. Lamsaf, H., Oulmekki, A., Elghadraoui, E.H., Fausto, R., Costa, B.F.O.: J. Phys. Chem. Solids. 119, 122–125 (2018)

    Article  ADS  Google Scholar 

  15. Lamsaf, H., Oulmekki, A., Elghadraoui, E.H., Fausto, R., Wagner, F.E., Costa, B.F.O.: J. Supercond. Nov. Magn. 32, 1377 (2018). https://doi.org/10.1007/s10948-018-4848-8

    Article  Google Scholar 

  16. Ijjaadi M., PhD Thesis, University of Fes, Morocco, 1994

  17. X’PertHighScore Plus: PANalytical. Almelo B.V, Netherlands (2006)

    Google Scholar 

  18. Momma, K., Izumi, F.: VESTA 3. J.Appl. Crystallogr. 44, 1272–1276 (2011)

    Article  Google Scholar 

  19. Jain, A., Hautier, G., Moore, C., Ong, S.P., Fischer, C.C., Mueller, T., Persson, K.A., Ceder, G.: Comput. Mater. Sci. 50, 2295–2310 (2011)

    Article  Google Scholar 

  20. Guinier A., Dunod X. (Ed.), Theorie et Technique de la Radiocristallographie, third ed., 1964, p. 462

  21. Genkina, E.A., Maksimov, B.A., Zvereva, O.V., Mininze, Yu, M., Lyubutin, I.S., Luchko, S.V., Yakovlev, V.V.: Sov. Phys. Crystallogr. 37, 627–632 (1992)

    Google Scholar 

  22. Shannon, R.D.: Acta Crystallogr. A. 32, 751–767 (1976)

    Article  ADS  Google Scholar 

  23. Cullity, B.D., Stuart, R.S.: Elements of X-ray diffraction. Prentice Hall, Upper Saddle River, NJ (2001)

    Google Scholar 

  24. Ruette, F., Sierralta, A., Sánchez, M., Luiggi, N.: J. Comput. Meth. Sci. Eng. 17, 55–62 (2017)

    Google Scholar 

  25. Baran, E.J., Mercader, R.C., Massaferro, A., Kremer, E.: Spectrochim. Acta A. 60, 1001–1005 (2004)

    Article  ADS  Google Scholar 

  26. Rulmont, A., Cahay, R., Liegeois-Duyckaerts, M., Tarte, P.: Eur. J. Solid State Inorg.Chem. 28, 207–219 (1981)

    Google Scholar 

  27. Farmer, V.C.: The Infrared Spectra of Minerals, Minerals Soc. Publ., London (1974)

    Book  Google Scholar 

  28. Zhang, L., Brow, R.K., Schlesinger, M.E., Ghussn, L., Zanotto, E.D.: J. Non-Cryst. Sol. 356, 1252–1257 (2010)

    Article  ADS  Google Scholar 

  29. Scholza, R., Frost, R.L., Xi, Y., Graça, L.M., Lagoeiro, L., López, A.: J. Mol. Struct. 1039, 22–27 (2013)

    Article  ADS  Google Scholar 

Download references

Funding

This work was partially supported by funds from FEDER (Programa Operacional Factores de Competitividade COMPETE) and from FCT-Fundação para a Ciência e a Tecnologia under the Project No. UID/FIS/04564/2016. Access to TAIL-UC (VSM measurements) was funded under QREN-Mais Centro Project ICT-2009-02-012-1890. The Coimbra Chemistry Center (CQC) is also supported by FCT (Project UI0313/QUI/2013) and COMPETE. R.F. also acknowledges the Portugal 2020 Project MATIS.

Author information

Authors and Affiliations

  1. Chemistry Laboratory of Condensed Matter (LCMC), Faculty of Science and Technology Fez, University of Sidi Mohammed Ben Abdellah, BP. 2202, Fes, Morocco

    H. Lamsaf, E. H. Elghadraoui & A. Oulmekki

  2. CQC, Department of Chemistry, University of Coimbra, P-3004-535, Coimbra, Portugal

    R. Fausto

  3. CFisUC, Department of Physics, University of Coimbra, P-3004-516, Coimbra, Portugal

    B. F. O. Costa

Authors
  1. H. Lamsaf
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. H. Elghadraoui
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Fausto
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Oulmekki
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. F. O. Costa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. F. O. Costa.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lamsaf, H., Elghadraoui, E.H., Fausto, R. et al. Synthesis, Structural Studies, and Magnetic Properties of a New Mixed-Valence Diphosphate: Zn2+5Fe3+2(P2O7)4. J Supercond Nov Magn 33, 1007–1012 (2020). https://doi.org/10.1007/s10948-019-05263-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-019-05263-w

Keywords

Search

Navigation