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Synthesis and Characterization of High Catalytic Activity Magnetic Fe3O4 Supported Pd Nanocatalyst

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Abstract

This study reports the fabrication and characterization of magnetically recyclable catalysts of Fe3O4–Pd nanocomposite as highly effective catalysts for reduction reactions in liquid phase. The characterization of Fe3O4–Pd MRCs were done by X-ray powder diffraction, ınfrared spectroscopy, thermal analyzer, transmission electron spectroscopy, ınductively coupled plasma, UV-Vis spectroscopy, vibrating sample magnetometer, respectively. The reduction of Pd2+ was accomplished with polyethylene glycol 400 (PEG-400) and Fe3O4 nanoparticles were prepared by co-precipitation of FeCI3⋅6H2O and FeCl2⋅4H2O. Thus formed Fe3O4–Pd MRCs showed a very high activity in reduction reactions of 4-nitro-aniline and 1,3-di-nitrobenzene in liquid phase. Magnetic character of this system allowed recovery and multiple use without significant loss of its catalytic activity.

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Acknowledgements

This work is supported by Fatih University under BAP grant no P50021104-B.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500, B. Cekmece, Istanbul, Turkey

    Abdulhadi Baykal & Ebubekir Karaoglu

  2. TUBITAK-UME, National Metrology Institute, PO Box 54, 41470, Gebze, Kocaeli, Turkey

    Hüseyin Sözeri & Emre Uysal

  3. Division of Functional Materials, KTH-Royal Institute of Technology, 16440, Kista, Stockholm, Sweden

    Muhammet S. Toprak

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  1. Abdulhadi Baykal
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Correspondence to Abdulhadi Baykal.

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Baykal, A., Karaoglu, E., Sözeri, H. et al. Synthesis and Characterization of High Catalytic Activity Magnetic Fe3O4 Supported Pd Nanocatalyst. J Supercond Nov Magn 26, 165–171 (2013). https://doi.org/10.1007/s10948-012-1702-2

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