Abstract
Zinc di-(4-chlorphenylthioacetate) dihydrate (4-ClC6H4SCH2COO)2Zn·2H2O (ZTD) is obtained in the reaction of protatrane 4-chlorphenylthioacetate 4-ClC6H4SCH2COO 2s- ·N+H(CH2CH2OH)3 with zinc dichloride (ZnCl2) in aqueous alcohol. X-ray diffraction is used to study the crystal structure of ZTD and compare it with related compounds. All intermolecular O…O contacts of the neighboring zinc polyhedra are short in ZTD molecules. Apparently, the short intermolecular O…O contacts cause distortions of the octahedral environment of the zinc atom.
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Original Russian Text Copyright © 2010 by M. G. Voronkov, V. S. Fundamenskii, É. A. Zelbst, A. A. Kashaev, A. N. Mirskova, and S. N. Adamovich
Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 4, pp. 816–818, July–August, 2010
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Voronkov, M.G., Fundamenskii, V.S., Zelbst, É.A. et al. Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate. J Struct Chem 51, 790–792 (2010). https://doi.org/10.1007/s10947-010-0119-7
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DOI: https://doi.org/10.1007/s10947-010-0119-7