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Journal of Structural Chemistry

, Volume 50, Issue 1, pp 97–101 | Cite as

Nature of percolation phase transition in hydration water films around immersed bodies

  • L. I. Men’shikovEmail author
  • P. O. Fedichev
Article

Abstract

The phenomenological vector model of water is used to clarify the nature of the percolation phase transition in hydration water films around the surface of immersed bodies, which is found in molecular dynamic calculations. The transition is explained by the emergence of ordering in the directions of projections of water dipole moments on the body surface at the lower critical temperature, i.e. by the formation of ferroelectric water film. The evaluation of this temperature is given, which is consistent with numerical calculations.

Keywords

polar liquid hydrophobic surface ferroelectric long-range order 

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References

  1. 1.
    G. N. Zatsepina, Physical Properties and the Structure of Water [in Russian], MGU, Moscow (1998).Google Scholar
  2. 2.
    C. Y. Lee, J. A. McCammon, and P. J. Rossky, J. Chem. Phys., 80, 4448 (1984).CrossRefGoogle Scholar
  3. 3.
    M. A. Wilson, A. Pohorille, and L. R. Pratt, ibid., 91, 4873 (1987).CrossRefGoogle Scholar
  4. 4.
    A. Kohlmeyer, C. Hartnig, and E. Spohr, J. Mol. Liq., 78, 233 (1998).CrossRefGoogle Scholar
  5. 5.
    A. Oleinikova, N. Smolin, I. Brovchenko, et al., J. Phys. Chem., B109, 1988 (2005).Google Scholar
  6. 6.
    A. Oleinikova, I. Brovchenko, N. Smolin, et al., Cond-mat/0505564 (2005).Google Scholar
  7. 7.
    A. Oleinikova, I. Brovchenko, and A. Geiger, arXiv:cond-mat/0507718 (2005).Google Scholar
  8. 8.
    A. P. Mel’nikov, Private Message.Google Scholar
  9. 9.
    P. O. Fedichev and L. I. Men’shikov, arXiv:cond-mat/0601129v3 [cond-mat.soft] 21 Apr 2006.Google Scholar
  10. 10.
    P. O. Fedichev, L. I. Men’shikov, and A. A. Vinnik, Novel Ab Initio Molecular Modelling Tools for Drug Discovery (2006); http://www.q-pharm.com/home/contents/sci_and_tech/science.
  11. 11.
    A. K. Ibrahim and G. O. Zimmerman, Phys. Rev., B35, 1860 (1987).Google Scholar
  12. 12.
    G. O. Zimmerman, A. K. Ibrahim, and F. Y. Wu, ibid., B37, 2059 (1988).Google Scholar
  13. 13.
    J. Seelig, P. M. Macdonald, and P. G. Scherer, Biochem., 26, 7535 (1987).CrossRefGoogle Scholar
  14. 14.
    J. C. Ruiz-Suarez, M. L. Klein, M. A. Moller, et al., Phys. Rev. Lett., 61, 710 (1988).CrossRefGoogle Scholar
  15. 15.
    P. I. Belobrov, V. A. Voevodin, and V. A. Ignatchenko, Zh. Éxp. Teor. Fiz., 88, 889 (1985).Google Scholar
  16. 16.
    J. G. Brankov and D. M. Danchev, Physica, A144, 128 (1987).Google Scholar
  17. 17.
    V. M. Bedanov, J. Phys.: Condens. Matter., 4, 75 (1992).CrossRefGoogle Scholar
  18. 18.
    S. Glasstone, Introduction to Electrochemistry, in: , D. Van Nostrand Co., Inc., New York, NY (1942).Google Scholar
  19. 19.
    A. Stogrin, IEEE Transactions of Microwave Theory Tech., Vol. MTT-19, 733 (1971).CrossRefGoogle Scholar
  20. 20.
    D. A. Boyarskii, V. V. Tikhonov, and N. Yu. Komarova, Progress in Electromagnetic Research, 35, 251 (2002).CrossRefGoogle Scholar
  21. 21.
    L. D. Landau, E. M. Lifshits, and L. P. Pitaevskii, Electrodynamics of Continua [in Russian], Nauka, Moscow (1982).Google Scholar
  22. 22.
    R. E. Peierls, Ann. Inst. Henry Poincare, 5, 122 (1935).Google Scholar
  23. 23.
    N. D. Mermin, Phys. Rev., 176, 250 (1968).CrossRefGoogle Scholar
  24. 24.
    J. A. Stratton, Electromagnetic Theory, McGraw-Hill, New York (1941).Google Scholar
  25. 25.
    D. V. Sivukhin, General Course of Physics [in Russian], V. 3., Electricity, Nauka-Fizmatlit, Moscow (1996).Google Scholar
  26. 26.
    P. G. Maier and F. Schwabl, Phys. Rev. B, 70, 134430 (2004).CrossRefGoogle Scholar
  27. 27.
    V. L. Berezinskii, Zh. Éxp. Teor. Fiz., 32, 493 (1971).Google Scholar
  28. 28.
    J. M. Kosterlitz and D. J. Thouless, J. Phys. C, 6, 1181 (1973).CrossRefGoogle Scholar
  29. 29.
    V. Ballenegger and J. P. Hansen, arXiv:cond-mat/0311654 v1 28 Nov 2003.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  1. 1.Russian Research Center “Kurchatov Institute”MoscowRussia

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