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Crystal structure refinement for trans-[Pd(NO3)2(H2O)2]

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Abstract

Single crystals of trans-[Pd(NO3)2(H2O)2] were obtained, and the crystal structure of this complex, previously obtained for polycrystals, was refined. Crystal data (BRUKER X8APEX diffractometer): a = 4.9973(7) Å, b = 10.5982(14) Å, c = 11.7008(17) Å, V = 619.70(15) Å3, space group Pbca, Z = 4, d calc = 2.856 g/cm3. The structure is composed of neutral complexes with a trans configuration. The square plane environment of the Pd atom is formed by four oxygen atoms (Pd-O(NO3) 1.999(5) Å, Pd-O(H2O) 2.030(5) Å) and completed to a distorted bipyramid by two intramolecular contacts (Pd…O(NO3) 2.926 Å). The shortest hydrogen bonds are O…H 2.72 Å.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    S. P. Khranenko, I. A. Baidina & S. A. Gromilov

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  1. S. P. Khranenko
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  2. I. A. Baidina
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  3. S. A. Gromilov
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Correspondence to I. A. Baidina.

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Original Russian Text Copyright © 2007 by S. P. Khranenko, I. A. Baidina, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 6, pp. 1218–1221, November–December, 2007.

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Khranenko, S.P., Baidina, I.A. & Gromilov, S.A. Crystal structure refinement for trans-[Pd(NO3)2(H2O)2]. J Struct Chem 48, 1152–1155 (2007). https://doi.org/10.1007/s10947-007-0185-7

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  • DOI: https://doi.org/10.1007/s10947-007-0185-7

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