Skip to main content
SpringerLink
Log in

Crystal structure of boron difluoride 3-phenylthiopentane-2,4-dionate. π stacking interactions and luminescence of boron difluoride acetyl acetonates

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of boron difluoride 3-phenylthiopentane-2,4-dionate was determined. The relationship between the structure and luminescent properties is traced in the series of boron difluoride acetyl acetonates (acetyl acetonate, phenylacetyl acetonate, and phenylthioacetyl acetonate). The presence of the π stacking interactions in boron difluoride phenylthioacetyl acetonate crystals leads to increased intensity and bathochromic shift of the fluorescence band.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. A. Reynolds, J. A. Van Allan, and A. K. Seidel, J. Heterocyclic Chem., 16, 369/370 (1979).

    Article  Google Scholar 

  2. G. S. Spicer and I. D. Strickland, J. Chem. Soc., 4644–4650 (1952).

  3. A. G. Mirochnik, E. V. Gukhman, V. E. Karasev, and P. A. Zhikhareva, Izv. Akad. Nauk, Ser. Khim., No. 6, 1030–1033 (2000).

  4. A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, et al., ibid., No. 9, 1535–1538 (2001).

  5. A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, et al., Zh. Obshch. Khim., 72, No. 5, 790–793 (2002).

    Google Scholar 

  6. Bruker, SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System, Bruker AXS, Madison, WI (1998).

  7. G. M. Sheldrick, (1998), SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Bruker AXS, Madison, WI (1998).

    Google Scholar 

  8. A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, and V. E. Karasev, J. Fluor., 13, 157–162 (2003).

    Article  CAS  Google Scholar 

  9. Y. Dromzee, J. Kossanyi, V. Wintgens, et al., Z. Krist., 212, 372–376 (1997).

    CAS  Google Scholar 

  10. M. B. Hursthouse, J. Emsley, and L. M. Harman, Private Communication, The Cambridge Structural Database, ConQuest 1.6 (2003).

  11. N. N. Barashkov, T. V. Sakhno, R. N. Nurmukhametov, and O. A. Khakhel, Usp. Khim., 62, No. 6, 579–593 (1993).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok

    B. V. Bukvetskii, E. V. Fedorenko, A. G. Mirochnik & V. E. Karasev

Authors
  1. B. V. Bukvetskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Fedorenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Mirochnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. E. Karasev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. G. Mirochnik.

Additional information

Original Russian Text Copyright © 2007 by B. V. Bukvetskii, E. V. Fedorenko, A. G. Mirochnik, and V. E. Karasev

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 6, pp. 1214–1217, November–December, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bukvetskii, B.V., Fedorenko, E.V., Mirochnik, A.G. et al. Crystal structure of boron difluoride 3-phenylthiopentane-2,4-dionate. π stacking interactions and luminescence of boron difluoride acetyl acetonates. J Struct Chem 48, 1148–1151 (2007). https://doi.org/10.1007/s10947-007-0184-8

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-007-0184-8

Keywords

Search

Navigation