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Boron Difluoride β-Diketonates: Structure and Phosphorescence

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Abstract

Phosphorescence data on boron difluoride β-diketonates of various structure have been systematized. Nonplanar boron difluoride molecules are characterized by the inversion of the S1 and T2 levels, which promotes efficient population of triplet levels and intense phosphorescence or delayed fluorescence of crystals. Planar molecules are characterized by a classical sequence of singlet and triplet levels and a coplanar arrangement of antiparallel molecules, which contributes to excimer delayed fluorescence.

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Funding

The work was supported by the Ministry of Education and Science of the Russian Federation in the framework of State assignment no. FWFN (0205)-2022-0003.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    A. G. Mirochnik, E. V. Fedorenko & A. V. Gerasimenko

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  1. A. G. Mirochnik
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  2. E. V. Fedorenko
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  3. A. V. Gerasimenko
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Correspondence to E. V. Fedorenko.

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The authors declare no conflicts of interest.

Additional information

The article devoted to the 50th anniversary of Konstantin Yu. Zhizhin, Corresponding Member of the Russian Academy of Sciences

Translated by G. Kirakosyan

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Mirochnik, A.G., Fedorenko, E.V. & Gerasimenko, A.V. Boron Difluoride β-Diketonates: Structure and Phosphorescence. Russ. J. Inorg. Chem. 68, 722–728 (2023). https://doi.org/10.1134/S0036023623600600

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