Abstract
This work is devoted to experimental (X-ray photoelectron) and theoretical investigations of electron density distribution in Pd(II) β-diketonate complexes. Data about the electronic structure (effective charges, core level energies) of the compounds are compared with their thermodynamic parameters (thermal stability, vaporization enthalpy). In molecular crystals of Pd(II) β-diketonates, the volatility of the complexes and vaporization enthalpy ΔH 0T depend not only on van der Waals interactions, but also on electrostatic interactions of molecules in crystal.
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Original Russian Text Copyright © 2007 by L. N. Mazalov, S. V. Trubina, N. A. Kryuchkova, O. A. Tarasenko, S. V. Trubin, and G. I. Zharkova
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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 2, pp. 259–268, March–April, 2007.
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Mazalov, L.N., Trubina, S.V., Kryuchkova, N.A. et al. X-ray photoelectron study of electron density distribution in palladium(II) β-diketonate complexes. J Struct Chem 48, 253–261 (2007). https://doi.org/10.1007/s10947-007-0040-x
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DOI: https://doi.org/10.1007/s10947-007-0040-x