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Triangular telluride complexes containing a cluster fragment [M3(µ3-Te)(µ2-Te2)3]4+ (M = Mo, W): Study of specific non-valence interactions

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Abstract

Various synthetic approaches are used to obtain new triangular complexes with rare cluster nuclei M3Te7 4+ (M = Mo, W), as well as with partial substitution for chalcogen W3Te3.8Se 4+3.2 . The crystalline structure has been identified for K5{[Mo3Te7(CN)6]2I}·2.5H2O (I), K3{[Mo3Te7(CN)6]SeCN}·3.25H2O (II), Cs2K{ [W3Te7(CN)6]Br0.8Cl0.2}·2.5H2O (III), Cs3{ [W3Te7(CN)6]Br}·2H2O (IV), Cs1.59K1.41{[W3Te3.8Se3.2× ×(CN)6]Br}·1,5H2O (V), [W3Te7((EtO)2PS2)3]Br (VI). The compounds are characterized by IR methods and electronic spectroscopy, electrospray-mass-spectrometry. The crystalline structure of this class of compounds is analyzed. Specific non-valence interactions in these systems are considered in detail.

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Authors and Affiliations

  1. A. V. Nikolayev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    A. V. Virovets, A. L. Gushchin, P. A. Abramov, N. I. Alferova, M. N. Sokolov & V. P. Fedin

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  1. A. V. Virovets
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  2. A. L. Gushchin
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  3. P. A. Abramov
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  4. N. I. Alferova
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  5. M. N. Sokolov
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  6. V. P. Fedin
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Original Russian Text Copyright © 2006 by A. V. Virovets, A. L. Gushchin, P. A. Abramov, N. I. Alferova, M. N. Sokolov, and V. P. Fedin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 2, pp. 332–345, March–April, 2006.

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Virovets, A.V., Gushchin, A.L., Abramov, P.A. et al. Triangular telluride complexes containing a cluster fragment [M3(µ3-Te)(µ2-Te2)3]4+ (M = Mo, W): Study of specific non-valence interactions. J Struct Chem 47, 326–338 (2006). https://doi.org/10.1007/s10947-006-0303-y

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  • DOI: https://doi.org/10.1007/s10947-006-0303-y

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