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Synthesis and crystal structure of the octahedral cluster complex [Th(DMSO)8Cl][Re6Se7Cl7]

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Abstract

A cluster complex of the composition [Th(DMSO)8Cl][Re6Se7Cl7] has been obtained by interaction of ThCl4 solution in DMSO with a water solution of K3[Re6Se7Cl7] and KCl. The compound crystallizes in the rhombic space group Pbcm with unit cell parameters a = 12.262(2) Å, b = 19.653(6) Å, c = 23.603(6) Å, V = 5688(2) Å3, Z = 4, d calc = 3.282 g/cm3. The structure is built from centrosymmetric cluster anions [Re6Se7Cl7]3− and complex cations [Th(DMSO)8Cl]3+ possessing mirror-plane symmetry, half of the DMSO ligands being doubly disordered.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    S. S. Yarovoi, S. F. Solodovnikov, Z. A. Solodovnikova, Yu. V. Mironov & V. E. Fedorov

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  1. S. S. Yarovoi
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  2. S. F. Solodovnikov
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  3. Z. A. Solodovnikova
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  4. Yu. V. Mironov
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  5. V. E. Fedorov
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__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 1, pp. 100–103, January–February, 2006.

Original Russian Text Copyright © 2006 by S. S. Yarovoi, S. F. Solodovnikov, Z. A. Solodovnikova, Yu. V. Mironov, and V. E. Fedorov

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Yarovoi, S.S., Solodovnikov, S.F., Solodovnikova, Z.A. et al. Synthesis and crystal structure of the octahedral cluster complex [Th(DMSO)8Cl][Re6Se7Cl7]. J Struct Chem 47, 97–101 (2006). https://doi.org/10.1007/s10947-006-0272-1

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  • DOI: https://doi.org/10.1007/s10947-006-0272-1

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