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Synthesis and structure of the 1,2-isopropylidene-α-D-glucofuranose 3,5,6-bis-cyclophosphite complex with tungsten(0) pentacarbonyl

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Abstract

Metallocomplexes with optically active ligands are of considerable interest as catalysts of stereoselective processes. A complex of 1,2-isopropylidene-α-D-glucofuranose 3,5,6-bis-cyclophosphite with tungsten(0) pentacarbonyl has been synthesized for the first time and studied by X-ray crystallography.

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References

  1. I. Ojima, K. Yamamoto, and M. Kumada, Aspects of Homogeneous Catalysis, Vol. 3, Reidel, Dordrecht (1977), pp. 186–228.

    Google Scholar 

  2. A. Pfaltz, Modern Synth. Meth., Vol. 5, 199–248 (1989).

    CAS  Google Scholar 

  3. M. P. Koroteev and E. E. Nifantiev, Zh. Obshch. Khim., 63, No. 3, 481–521 (1993).

    CAS  Google Scholar 

  4. E. E. Nifantiev, M. P. Koroteev, A. M. Koroteev, et al., Dokl. Ross. Akad. Nauk, 353, No. 4, 508–512 (1997).

    Google Scholar 

  5. E. E. Nifantiev, M. P. Koroteev, A. M. Koroteev, et al., J. Organometal. Chem., 587, 18–27 (1999).

    Article  Google Scholar 

  6. A. I. Gorbunov et al., Theoretical Principles of General Chemistry [in Russian], Moscow (2001).

  7. G. M. Sheldrick, SADABS, Version 2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, WI, USA (1998).

    Google Scholar 

  8. G. M. Sheldrick, SHELXTL, Version 5.10, Bruker AXS, Madison, WI, USA (1997).

    Google Scholar 

  9. N. K. Kochetkov, E. E. Nifantiev, M. P. Koroteev, et al., Carbohydr. Res., 47, No. 2, 221–231 (1976).

    Article  CAS  Google Scholar 

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Original Russian Text Copyright © 2005 by T. S. Ulbaev, Yu. S. Mardashev, M. P. Koroteev, V. N. Khrustalev, and M. Yu. Antipin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 5, pp. 924–927, September–October, 2005.

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Ulbaev, T.S., Mardashev, Y.S., Koroteev, M.P. et al. Synthesis and structure of the 1,2-isopropylidene-α-D-glucofuranose 3,5,6-bis-cyclophosphite complex with tungsten(0) pentacarbonyl. J Struct Chem 46, 891–894 (2005). https://doi.org/10.1007/s10947-006-0215-x

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  • DOI: https://doi.org/10.1007/s10947-006-0215-x

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