Abstract
Fullerite films covered with d-metal layers were obtained. The metal deposited over fullerite was shown to diffuse substantially into the films. The prepared heterophase film structures M/C60 were studied by X-ray diffraction and vibrational spectroscopy. It is established that the interaction between metal and fullerite phases gives rise to chemical bonds M—C60. It results in a partial polymerization of fullerite. Samples of metal-impregnated fullerite films exhibit semiconducting properties.
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Original Russian Text Copyright © 2004 by Yu. V. Shevtsov, S. V. Trubin, Yu. V. Shubin, A. S. Berdinsky, B. M. Ayupov, D. Fink, Kh. G. Chan, and V. S. Kravchenko
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Translated from Zhurnal Strukturnoi Khimii, Vol. 45, Supplement, pp.77–84, 2004.
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Shevtsov, Y.V., Trubin, S.V., Shubin, Y.V. et al. Investigation of phase interactions in C60 fullerite films during gas phase metal deposition. J Struct Chem 45 (Suppl 1), S76–S83 (2004). https://doi.org/10.1007/s10947-006-0098-x
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DOI: https://doi.org/10.1007/s10947-006-0098-x