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Crystal structure of benzoic acid 4-nitrobenzylidenhydrazide

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Abstract

The crystal structure of benzoic acid 4-nitrobenzylidenhydrazide has been determined. Crystal data: crystal system — monoclinic, a = 7.101(9) Å, b = 25.48(3) Å, c = 7.730(11) Å; β = 112.43(9)°, space group P21/n, Z = 4, R = 0.038. The compound under investigation has a non-planar structure in general, and the substituents at azomethine N-C bond are in E-position. Root-mean-square planes of the six-memebered heterocycles make angles of 29.9° and 37.7° to fairly planar hydrazine fragment. In crystalline state the compound forms layers, the molecules within the layers being linked by C-H...O bonds. Neighboring layers are connected by hydrogen bonds between carbonyl oxygen atoms and amide hydrogens.

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References

  1. Yu. P. Kitaev and B. I. Buzykin, Hydrazones [in Russian], Nauka, Moscow (1974).

    Google Scholar 

  2. G. A. Melent’eva, Pharmaceutical Chemistry [in Russian], Meditzina, Moscow (1987).

    Google Scholar 

  3. M. D. Mashkovskii, Pharmaceuticals [in Russian], V. 2, Belorussia, Minsk (1987).

    Google Scholar 

  4. G. I. Zhungietu and V. G. Granik, Basic Principles of Drug Design [in Russian], Izd-vo MoldGU, Chisinau (2000).

    Google Scholar 

  5. G. M. Sheldrick, SHELX-86, Program for Crystal Structure Determination, Univ. Göttingen, Germany.

  6. G. M. Sheldrick, SHELX-93, Program for Crystal Structure Refinement, Univ. Göttingen, Germany.

  7. F. N. Allen and O. Kennard, Chem. Design Automat. News, 8, 131 (1993).

    CAS  Google Scholar 

  8. L. A. Litvinov, O. N. Kataeva, L. V. Ermolaeva, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 75–81 (1991).

  9. A. Lyubchova, A. Cosse-Barbi, J. P. Doucet, et al., Acta Crystallogr. Sect. C, 51, 1893–1985 (1995).

    Article  Google Scholar 

  10. Hoong-Kun Fun, Zhong-Lin Lu, Chun-Ying Duan, et al., ibid., 53, 1454/1455 (1997).

    Google Scholar 

  11. S. Shanmuga Sundara Raj, Hoong-Kun Fun, and Zhong-Lin Lu, ibid., 56, 1013/1014 (2000).

    Google Scholar 

  12. G. R. Desiraju, J. Chem. Soc., Chem. Commun., 18, 1239 (1991).

    Article  Google Scholar 

  13. R. K. Castelano, F. Diederich, and E. A. Meyer, Angew. Chem. Int. Ed., 42, No. 11, 1210–1250 (2003).

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Applied Physics, Moldova Academy of Sciences, Chisinau

    Yu. M. Chumakov & B. Ya. Antosyak

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow

    Z. A. Starikova

  3. Moldova State University, Chisinau

    V. I. Tzapkov, N. M. Samus & A. P. Gulya

Authors
  1. Yu. M. Chumakov
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  2. Z. A. Starikova
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  3. B. Ya. Antosyak
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  4. V. I. Tzapkov
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  5. N. M. Samus
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  6. A. P. Gulya
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Original Russian Text Copyright © 2005 Yu. M. Chumakov, Z. A. Starikova, B. Ya. Antosyak, V. I. Tzapkov, N. M. Samus, and A. P. Gulya

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp.378–382, March–April, 2005.

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Chumakov, Y.M., Starikova, Z.A., Antosyak, B.Y. et al. Crystal structure of benzoic acid 4-nitrobenzylidenhydrazide. J Struct Chem 46, 371–375 (2005). https://doi.org/10.1007/s10947-006-0056-7

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  • DOI: https://doi.org/10.1007/s10947-006-0056-7

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