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Structural contribution to the effect of hydrophobic hydration of noble gases

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Abstract

Within the concepts of structurally-thermodynamic characteristics of solvation and pseudo-chemical potential, the sample collection of the most authentic experimental data on solubility of gaseous He, Ne, Ar, Kr, Xe, and Rn in H2O and D2O is analysed at ≈0.1 MPa and T = 278–318 K. The conclusion is drawn that at deuteration of water molecules and also with increasing molar mass of noble gas, the relative contribution of effect of its hydrophobic hydration decreases. However in case of pass from lightweight noble gases (He, Ne, Ar) to heavy ones (Kr, Xe, Rn), structural transformations in their aqueous solutions become more expressed as a whole due to strengthening interaction between dissolved substance and solvent.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo

    E. V. Ivanov, E. J. Lebedeva, V. K. Abrosimov & N. G. Ivanova

  2. Ivanovo State University of Power Engineering, Ivanovo

    V. K. Abrosimov & N. G. Ivanova

Authors
  1. E. V. Ivanov
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  2. E. J. Lebedeva
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  3. V. K. Abrosimov
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  4. N. G. Ivanova
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Original Russian Text Copyright © 2005 by E. V. Ivanov, E. J. Lebedeva, V. K. Abrosimov, and N. G. Ivanova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp. 262–272, March–April, 2005.

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Ivanov, E.V., Lebedeva, E.J., Abrosimov, V.K. et al. Structural contribution to the effect of hydrophobic hydration of noble gases. J Struct Chem 46, 253–263 (2005). https://doi.org/10.1007/s10947-006-0039-8

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  • DOI: https://doi.org/10.1007/s10947-006-0039-8

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