Abstract
Synthesis of a mixed complex compound Pb2[Fe(CN)6]NO3·5.5H2O is described. The results of its X-ray structural investigation are presented. Crystal data: C6H11FeN7O8.50Pb2: a = 7.2582(6) Å, b = 21.838(3) Å, c = 11.612(1) Å; β = 107.91(1)°, V = 1751.4(3) Å3, Z = 4, d calc = 2.986 g/cm3, space group P21/m, R = 0.038. The compound has a framework polymer structure.
Similar content being viewed by others
References
I. V. Tananaev, G. B. Seifer, Yu. Yu. Kharitonov, et al., Chemistry of Ferrocyanides [in Russian], Moscow, Nauka (1971).
A. G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals, Academic Press, London (1976).
Yu. Ya. Kharitonov, V. I. Goldansky, G. B. Seifer, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 271 (1970).
Mohsin Qureshi, K. G. Varshey, and Fahmida Khan, J. Chromatograph., 65, 547–555 (1972).
Yu. A. Kharitonov (ed.), Vibrational Spectra in Inorganic Chemistry [in Russian], Nauka, Moscow (1971).
E. V. Polyakov, T. A. Denisova, L. G. Maksimova, et al., Zh. Neorg. Khim., 42, No. 3, 365 (1997).
E. V. Polyakov, T. A. Denisova, L. G. Maksimova, et al., ibid., 45, No. 2, 334–340 (2000).
V. G. Zubkov, A. P. Tyutyunnik, I. F. Berger, et. al., J. Solid State Sci., 3, No. 3, 361–367 (2001).
V. M. Zainullina, V. P. Zhukov, V. G. Zubkov, et al., International Symposium “Phase transformations in solid solutions and alloys”, Proceedings, part I, 2002, pp. 96/97.
G. M. Sheldrick, SHELX-97. Release 97-1, Univ. Göttingen, Germany (1997).
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by S. A. Gromilov, I. A. Baidina, T. A. Denisova, and L. G. Maksimova
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 118–123, January–February, 2005.
Rights and permissions
About this article
Cite this article
Gromilov, S.A., Baidina, I.A., Denisova, T.A. et al. Crystal structure of Pb2[Fe(CN)6]NO3·5.5H2O. J Struct Chem 46, 116–121 (2005). https://doi.org/10.1007/s10947-006-0017-1
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-006-0017-1