Abstract
Complexes of Pd(II) with aminobutyric acid AmH = NH2CH(CH2CH3)COOH, namely, trans-[Pd(AmH)2Cl2] with monodentate (via the NH2 group) AmH ligands and cis-, trans-Pd(Am)2 with bidentate (via NH2 and COO groups) ligands have been synthesized for the first time. Elemental analysis and IR and NMR spectroscopy were used to identify the synthesized compounds. The NMR spectra of the Pd(II) complexes were interpreted by comparing them with the NMR spectra of the analogous complexes of Pt(II). For Pt(II) and Pd(II) complexes with aminobutyric acid used as examples, an approach to identification of diastereomer bis-aminoacid complexes in specimens with racemic aminoacids by NMR spectroscopy is demonstrated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Efimenko, N. A. Ivanova, and O. S. Erofeeva, Abstracts of Papers from the 21st International Chugaev Conf. on Coordination Chemistry, Kiev, June, 2003, p. 72.
B. Lippert, Coord. Chem. Rev., 182, 263–295 (1999).
L. M. Volstein, Koordinats. Khim., 1, No. 5, 595–621 (1975).
A. Jakovidis and N. Hadjiliadis, Coord. Chem. Rev., 135/136, 17–63 (1994).
L. D. Pettit and M. Bezer, ibid., 61, 97–114 (1985).
L. F. Krylova, L. D. Dikanskaya, A. P. Chupakhin, et al., Zh. Neorg. Khim., 40, No. 3, 433–439 (1995).
L. F. Krylova and A. V. Golovin, Zh. Strukt. Khim., 41, No. 2, 300–311 (2000).
L. F. Krylova and A. V. Golovin, ibid., 41, No. 2, 312–323 (2000).
L. M. Volstein and N. S. Velikanova, Zh. Neorg. Khim., 2, No. 10, 2383–2389 (1957).
A. J. Gordon and R. A. Ford, The Chemist’s Companion, Wiley, New York (1972).
G. C. Levy and G. L. Nelson, Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, Wiley-Interscience, New York (1972).
M. A. Fedotov, Nuclear Magnetic Resonance in Inorganic Solutions [in Russian], Nauka, Novosibirsk (1986), p. 147.
L. F. Krylova and T. A. Pavlushko, Zh. Neorg. Khim., 46, No. 6, 930–941 (2001).
L. M. Volstein, L. F. Krylova, and A. V. Belyaev, ibid., 18, No. 4, 1066–1070 (1973).
L. F. Krylova, L. D. Dikanskaya, and M. A. Fedotov, Koordinats. Khim., 20, No. 1, 57–59 (1994).
L. F. Krylova and I. S. Kuprov, Zh. Neorg. Khim., 48, No. 8, 1288–1298 (2003).
H. Gunther, NMR Spectroscopy, Wiley, Chichester (1995).
J. A. Pople, W. G. Schneider, and H. J. Bernstein, High-Resolution Nuclear Magnetic Resonance, McGraw-Hill, New York (1959).
E. Baks, Two-Dimensional Nuclear Magnetic Resonance in Liquids [in Russian], Nauka, Novosibirsk (1989), p. 69.
Yu. N. Kukushkin, Coordination Chemistry [in Russian], Vysshaya Shkola, Moscow (1985), p. 455.
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York (1970).
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by L. F. Krylova and L. M. Matveeva
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 77–89, January–February, 2005.
Rights and permissions
About this article
Cite this article
Krylova, L.F., Matveeva, L.M. Identification of Pt(II) and Pd(II) stereoisomeric complexes with aminobutyric acid by NMR and IR spectroscopy. J Struct Chem 46, 75–86 (2005). https://doi.org/10.1007/s10947-006-0011-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-006-0011-7