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Magnetochemistry of boron hydride structures. Empirical aspects

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Abstract

The reviews and monographs on magnetochemistry of boron compounds are discussed. The structural peculiarities of borane derivatives relevant to magnetochemical calculations of diamagnetic contributions are are considered. Experimental measurements of diamagnetic susceptibility for deltahedral B10H 2−10 and B12H 2−12 cluster closo-anions were used to derive the diamagnetic atomic increments of the B atoms (χB) with coordination numbers 5 and 6. The atomic increments χB thus obtained were used to calculate molecular diamagnetic susceptibility χM of borane derivatives. Diamagnetic susceptibility χM was measured and calculated for the series of borane derivatives BnH 2−n and B10H12L2 (L is a Lewis base)and cobalt(III) derivatives of ortho-carborane(12) [(B9C2H11)2Con(B8C2H10) n−1]n−. Diamagnetic increments were obtained for |B10H12| fragments and (B9C2H11)2− and (B8C2H10)4− ligands. The increments can be employed for calculating χM for novel compounds. The calculated values of χM coincide with the experimental values within 2%–6%.

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  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    V. V. Volkov & V. N. Ikorskii

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  1. V. V. Volkov
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Original Russian Text Copyright © 2004 by V. V. Volkov and V. N. Ikorskii

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 729–740, July–August 2004.

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Volkov, V.V., Ikorskii, V.N. Magnetochemistry of boron hydride structures. Empirical aspects. J Struct Chem 45, 694–705 (2004). https://doi.org/10.1007/s10947-005-0046-1

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  • DOI: https://doi.org/10.1007/s10947-005-0046-1

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