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Synthesis and structure of isomeric (μ-H)Os3(μ,η2-(O,N)-6,6-clusters of dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-one oxime)(CO)10. Crystal structure of one of the isomers

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Abstract

(μ-H)2Os3(μ,η2-(O,N)-6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-one oxime)(CO)10 isomeric clusters have been synthesized, separated chromatographically, and investigated by IR and NMR spectroscopy. The crystal structure of one of the isomers has been determined (Enraf-Nonius CAD-4 automatic diffractometer, graphite monochromator, λMoK α, θ/2θ scan mode at a variable rate). The crystals are monoclinic with unit cell parameters: a = 9.125(2) Å, b = 13.629(3) Å, c = 10.098(2) Å, β = 90.16(3)°, V = 1255.8(4) Å3, space group P21, Z = 2, composition (μ-H)2Os3(μ,η2-ONC10H14)(CO)10, d calc = 2.647 g/cm3. The structure is molecular; the planes of the Os3 triangle and the OsONOs bridging ligand are linked according to the “butterfly” pattern with an angle of 102.0° between the planes. The Os-Os bonds vary within the range 2.840 Å–2.882 Å.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    V. A. Maksakov, N. V. Pervukhina, S. V. Korenev, N. V. Podberezskaya & V. P. Kirin

  2. N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    A. V. Tkachev

Authors
  1. V. A. Maksakov
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  2. N. V. Pervukhina
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  3. S. V. Korenev
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  4. N. V. Podberezskaya
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  5. V. P. Kirin
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  6. A. V. Tkachev
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Original Russian Text Copyright © 2004 by V. A. Maksakov, N. V. Pervukhina, S. V. Korenev, N. V. Podberezskaya, V. P. Kirin, and A. V. Tkachev

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 698–705, July–August, 2004.

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Maksakov, V.A., Pervukhina, N.V., Korenev, S.V. et al. Synthesis and structure of isomeric (μ-H)Os3(μ,η2-(O,N)-6,6-clusters of dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-one oxime)(CO)10. Crystal structure of one of the isomers. J Struct Chem 45, 663–670 (2004). https://doi.org/10.1007/s10947-005-0042-5

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  • DOI: https://doi.org/10.1007/s10947-005-0042-5

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