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Pd@silicate-1 synthesized by steam-assisted-crystallization strategy for high-efficient catalytic hydrogenation of furfural

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Abstract

Here, we demonstrate a simple in situ synthesis of Pd@silicate-1 (S-1), using [Pd(NH2CH2CH2NH2)2]Cl2 as a metal precursor and steam-assisted crystallization (SAC) method. The ultra-small Pd nanoparticles (NPs) (~ 1 nm) can be successfully in situ encapsulated into the silicate-1 matrix with well dispersion. The obtained Pd@S-1 catalyst possesses high crystallinity, a large specific surface area and pore volume. More importantly, Pd NPs encapsulated into silicate-1 matrix can avoid the aggregation and sintering during catalytic reaction. Meanwhile, micropores of silicate-1 can improve the selectivity of the products in the hydrogenation of biomass furfural. Consequently, Pd@S-1 catalyst shows excellent catalytic activity in the selective hydrogenation of biomass furfural with selectivity of 95.7% and activity of 83.7% in the condition of relatively low temperature (458 K). Therefore, this strategy provides a new idea for the synthesis of molecular sieve supported metal catalysts.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21971132, 51772162 and 52072197), Outstanding Youth Foundation of Shandong Province, China (ZR2019JQ14), Youth Innovation and Technology Foundation of Shandong Higher Education Institutions, China (2019KJC004), Major Scientific and Technological Innovation Project (2019JZZY020405), Major Basic Research Program of Natural Science Foundation of Shandong Province (ZR2020ZD09), and Taishan Scholar Young Talent Program (tsqn201909114), Natural Science Foundation of Shandong Province, China (ZR2019MB042), the Key Laboratory of Resource Chemistry, Ministry of Education (KLRC_ME2101).

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  1. Key Laboratory of Eco-Chemical Engineering, Taishan Scholar Advantage and Characteristic Discipline Team of Eco-Chemical Process and Technology, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Tiantian Ye, Hanfang Liu, Fupeng Wang, Huijie Xie, Saisai Ran, Wei Xu, Jia Liu, Bin Li, Haifeng Lin & Lei Wang

  2. College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, Shandong, China

    Tiantian Ye, Hanfang Liu, Fupeng Wang, Huijie Xie, Saisai Ran, Haifeng Lin & Lei Wang

  3. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Wei Xu & Bin Li

  4. State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580, Shandong, China

    Yongming Chai

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  1. Tiantian Ye
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  2. Hanfang Liu
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Contributions

TY: Writing—original draft, Methodology, Investigation. HL: Investigation, Formal analysis. FW: Formal analysis. HX: Formal analysis. SR: Formal analysis. WX: Formal analysis. JL: Formal analysis, Validation. BL: Conceptualization, Writing—review and editing, Funding acquisition, Methodology, Supervision. HL: Formal analysis, Validation. YC: Validation, Supervision. LW: Conceptualization, Writing—review and editing, Funding acquisition, Methodology, Supervision.

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Correspondence to Bin Li, Yongming Chai or Lei Wang.

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Ye, T., Liu, H., Wang, F. et al. Pd@silicate-1 synthesized by steam-assisted-crystallization strategy for high-efficient catalytic hydrogenation of furfural. J Porous Mater 29, 1479–1487 (2022). https://doi.org/10.1007/s10934-022-01269-3

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