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The catalytic reactivity of titanium dioxide supported on SBA-15 catalyst for selective oxidation of benzyl alcohol

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Abstract

Titania doped Mesoporous SBA-15 with various metal ratios was prepared by wet chemical route. Several phyisco chemical methods were applied to determine the structural and chemical property of the catalyst such as XRD, BET, FT-IR, TEM, SEM, and UV–Vis diffuse reflectance spectroscopy. The prepared SBA-15 catalyst has a hexagonal structure after the addition of zirconium doesn’t affect the structure of the SBA-15 catalyst it is also confirmed by TEM analysis. Titanium ions are tetrahedrally coordinated with silica framework which is confirmed by DRS-UV analysis. The catalytic performances of the Ti-SBA-15 catalysts were examined in the BzOH conversion under acetonitrile as a solvent and tert-butyl hydroperoxide (TBHP) as an oxidant. The reaction parameters like the molar ratio of H2O2: BzOH, catalyst amount, temperature, and reaction time were explored in detail. The ST-30 is the best catalyst composition of the prepared catalyst with a maximum conversion of 85% and selectivity of 98%. The recycling studies show that the synthesized Ti-SBA-15 catalyst is more stable up to five consecutive runs.

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Acknowledgements

The authors are grateful to the Deanship of Scientific Research, King Saud University for funding through Vice Deanship of Scientific Research Chairs and this research was funded by the Deanship of Scientific Research at Princess Nourah bint Abdulrahman University through the Fast-track Research Funding Program.

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Authors and Affiliations

  1. Department of Chemistry, Dwaraka Doss Goverdhan Doss Vaishnav College (Autonomous), (Affiliated to the University of Madras, Chennai), 833, Gokul Bagh, E.V.R. Periyar Road, Arumbakkam, Chennai, 600 106, Tamil Nadu, India

    P. Tamizhdurai

  2. Department of Chemical Engineering, SSN College of Engineering, Kalavakkam, Chennai, 603110, India

    A. Abilarasu

  3. Sriram College of Arts and Science, Perumalpattu, Veppampattu, Tiruvallur, Tamilnadu, 602 024, India

    S. Narayanan & C. Ragupathi

  4. Department of Materials and Minerals Engineering, National Taipei University of Technology, Taipei, Taiwan

    Mani Govindasamy

  5. Advanced Materials Research Chair, Chemistry Department, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia

    Ayman A. Ghfar & Mohamed Ouladsmane

  6. Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, Riyadh, 11671, Saudi Arabia

    Murefah Mana AL-Anazy

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  1. P. Tamizhdurai
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Tamizhdurai, P., Abilarasu, A., Narayanan, S. et al. The catalytic reactivity of titanium dioxide supported on SBA-15 catalyst for selective oxidation of benzyl alcohol. J Porous Mater 28, 1787–1796 (2021). https://doi.org/10.1007/s10934-021-01124-x

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