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The effects of different dimensional organic amines on synthetic zinc phosphites/phosphates

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Abstract

Three different dimensional zinc phosphites and zinc phosphates, [C7H18N]2[Zn(HPO3)2] (1), [C6H9N2][Zn2(PO4)(HPO3)] (2), and [C6H14N2][Zn2(PO4)2] (3) were hydro(solvo)thermally synthesized from organic amines with the same number of nonhydrogen atoms and different dimensionalities and sizes. Structural analysis indicates that compound 1 shows a one-dimensional (1D) chain structure; compound 2 is an inorganic–organic hybrid two-dimensional (2D) material; compound 3 is a three-dimensional (3D) open-framework zinc phosphate EDI zeolite. The mechanisms of 1D chain-like n-heptamine, 2D planar 3-aminomethylpyridine, and 3D triethylenediamine on the synthetic process were analyzed. The n-heptamine has only one function: a protonated template in compound 1, while 3-aminomethylpyridine has two functions: a protonated template and binding ligand in the synthesis of compound 2. The triethylenediamine has three functions in compound 3: a protonated template, space-filling agent, and structure-directing agent. Thus, the three organic amines play different roles in the three compounds. They were analyzed by XRD, SEM, TGA, FT-IR, ICP, and CHN analyses.

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References

  1. J.Y. Li, A. Corma, J.H. Yu, Chem Soc Rev. 44, 7112 (2015)

    CAS  PubMed  Google Scholar 

  2. D.F. Weng, Z.M. Wang, S. Gao, Chem. Soc. Rev. 40, 3157 (2011)

    CAS  PubMed  Google Scholar 

  3. C.N.R. Rao, S. Natarajan, A. Choudhury, S. Neeraj, A.A. Ayi, Acc. Chem. Res. 34, 80 (2001)

    CAS  PubMed  Google Scholar 

  4. T. Rojo, J.L. Mesa, J. Lago, B. Bazán, J.L. Pizarro, M.I. Arriortua, J. Mater. Chem. 19, 3793 (2009)

    CAS  Google Scholar 

  5. S.T. Wilson, B.M. Lok, C.A. Messian, T.R. Cannan, E.M. Flanigen, J. Am. Chem. Soc. 104, 1146 (1982)

    CAS  Google Scholar 

  6. R. Murugavel, A. Choudhury, M.G. Walawalkar, R. Pothiraja, C.N.R. Rao, Chem. Rev. 108, 3549 (2008)

    CAS  PubMed  Google Scholar 

  7. J.B. Wu, Y. Yan, B.K. Liu, X.L. Wang, J.Y. Li, J.H. Yu, Chem. Commun. 49, 4995 (2013)

    CAS  Google Scholar 

  8. M. Yang, P.F. Yan, F.F. Xu, J.H. Ma, U. Welz-Biermann, Micropor Mesoporo Mater 147, 73 (2012)

    Google Scholar 

  9. Y.T. Chang, S.H. Lo, C.H. Lin, L.I. Hung, S.L. Wang, Chem.-Eur. J. 24, 12474 (2018)

    CAS  PubMed  Google Scholar 

  10. H.Z. Xing, W.T. Yang, T. Su, Y. Li, J. Xu, T. Nakano, J.H. Yu, R.R. Xu, Angew. Chem. Int. Ed. 49, 2328 (2010)

    CAS  Google Scholar 

  11. G.M Wang, J.H Li, L Wei, S.D. Han, X.M. Zhao, Z.Z. Bao, CrystEngComm. 17, 8414 (2015)

    CAS  Google Scholar 

  12. X.J. Wang, J.H. Zhang, J.L. Song, F. Kong, J.G. Mao, CrystEngComm 15, 2519 (2013)

    CAS  Google Scholar 

  13. P. Ramaswamy, N.N. Hegde, R. Prabhu, V.M. Vidya, A. Datta, S. Natarajan, Inorg. Chem. 48, 11697 (2009)

    CAS  PubMed  Google Scholar 

  14. H.Y. Lin, C.Y. Chin, H.L. Huang, W.Y. Huang, M.J. Sie, L.H. Huang, Y.H. Lee, C.H. Lin, K.H. Lii, X.H. Bu, S.L. Wang, Science 339, 811 (2013)

    CAS  PubMed  Google Scholar 

  15. C. Lin, F.J. Pan, J. Li, Y.P. Chen, D.E. Shi, T.Q. Ma, Y.Q. Yang, X. Du, W. Wang, F.H. Liao, J.H. Lin, T. Yang, J.L. Sun, Cryst. Growth Des. 18, 1267 (2018)

    CAS  Google Scholar 

  16. X.L. Wang, Y. Yan, J.B. Wu, C.Q. Zhang, J.Y. Li, CrystEngComm 16, 2266 (2014)

    Google Scholar 

  17. X.C. Liu, Y. Xing, X.L. Wang, H.B. Xu, X.Z. Liu, K.Z. Shao, Z.M. Su, Chem. Commun. 46, 2614 (2010)

    CAS  Google Scholar 

  18. L.M. Li, K. Cheng, J. Zhang, Inorg. Chem. Commun. 30, 136 (2013)

    CAS  Google Scholar 

  19. J.A. Rodgers, W.T.A. Harrison, Chem. Commun. 2000, 2385 (2000)

    Google Scholar 

  20. J.M. Tian, B. Li, X.Y. Zhang, J.P. Zhang, CrystEngComm 16, 1071 (2014)

    CAS  Google Scholar 

  21. H.D. Li, L.R. Zhang, Q.S. Huo, Y.L. Liu, J. Solid State Chem. 197, 75 (2013)

    CAS  Google Scholar 

  22. A. Sutrisno, L. Liu, J. Xu, Y.N. Huang, Phys. Chem. Chem. Phys. 13, 16606 (2011)

    CAS  PubMed  Google Scholar 

  23. X. Zhang, G.M. Wang, Z.H. Wang, Y.X. Wang, J.H. Lin, J Mol Struct. 1056–1057, 25 (2014)

    Google Scholar 

  24. Y.L. Lai, K.H. Lii, S.L. Wang, J. Am. Chem. Soc. 129, 5350 (2007)

    CAS  PubMed  Google Scholar 

  25. Z.J. Dong, L. Zhao, Z.Q. Liang, P. Chen, Y. Yan, J.Y. Li, J.H. Yu, R.R. Xu, Dalton Trans. 39, 5439 (2010)

    CAS  PubMed  Google Scholar 

  26. Y.L. Yang, N. Li, H.B. Song, H.G. Wang, W.B. Chen, S.H. Xiang, Chem. Mater. 19, 1889 (2007)

    CAS  Google Scholar 

  27. J. Přech, P. Pizarro, D.P. Serrano, J. Čejka, Chem Soc Rev 47, 8263 (2018)

    PubMed  Google Scholar 

  28. M.Y. Emran, M.A. Shenashen, H. Morita, S.A. El-Safty, Advanced healthcare materials 7, 1701459 (2018)

    Google Scholar 

  29. M.Y. Emran, M.A. Shenashen, H. Morita, S.A. El-Saftya, Biosens Bioelectron 109, 237 (2018)

    CAS  PubMed  Google Scholar 

  30. N. Akhtar, M.Y. Emran, M.A. Shenashen, H. Khalifa, T. Osaka, A. Faheem, T. Homma, H. Kawarada, S.A. El-Safty, J Mater Chem B5, 7985 (2017)

    Google Scholar 

  31. M.Y. Emran, M.A. Shenashen, A.A. Abdelwahab, M. Abdelmottaleb, S.A. El-Safty, New J. Chem 42, 5037 (2018)

    CAS  Google Scholar 

  32. D. Hassen, M.A. Shenashen, A.R. El-Safty, A. Elmarakbi, S.A. El-Safty, Scientific reports. 8, 3740 (2018)

    CAS  PubMed  PubMed Central  Google Scholar 

  33. D. Hassen, S.A. El-Safty, K. Tsuchiya, A. Chatterjee, A. Elmarakbi, M.A. Shenashen, M. Sakai, Scientific reports. 6, 24330 (2016)

    CAS  PubMed  PubMed Central  Google Scholar 

  34. M.A. Shenashen, D. Hassen, S.A. El-Safty, M.M. Selim, N. Akhtar, A. Chatterjee, A. Elmarakbi, Advanced Materials Interfaces 3, 1600743 (2016)

    Google Scholar 

  35. M.A. Shenashen, D. Hassen, S.A. El-Safty, H. Isago, A. Elmarakbi, H. Yamaguchi, Chem Eng J 313, 83 (2017)

    CAS  Google Scholar 

  36. I. Halime, A. Bezgour, M. Fahim, M. Dusek, K. Fejfarova, M. Lachkar, B.E. Bali, J. Chem. Crystallogr. 41, 223 (2011)

    CAS  Google Scholar 

  37. C.M. Wang, C.W. Chiu, H.M. Lin, K.H. Lii, J. Solid State Chem. 204, 16 (2013)

    CAS  Google Scholar 

  38. SAINT, Bruker AXS Inc. 5465 East Cheryl Parkway, Madison, WI 53711–5373, USA, 2000.

  39. G.M. Sheldrick, Acta Crystallogr. A. 64, 112 (2008)

    CAS  PubMed  Google Scholar 

  40. Z.G. Zhang, S.J. Yao, J.C. Liao, Z.Y. Dai, J. Fu, Mater. Chem. A. 1, 4945 (2013)

    CAS  Google Scholar 

  41. C. Fan, D. Slebodnick, R. Troya, B.E. Angel, Hanson. Inorg. Chem. 44, 2719 (2005)

    CAS  PubMed  Google Scholar 

  42. J.H. Li, L. Wei, Z.Z. Bao, G.M. Wang, Z.H. Wang, Solid State Sci 51, 13 (2016)

    CAS  Google Scholar 

  43. A.L.J. Spek, J. Appl. Crystallogr. 36, 7 (2003)

    CAS  Google Scholar 

  44. W.T.A. Harrison, Acta Crystallogr. E. 57, 248 (2001)

    Google Scholar 

  45. J. Liang, J.Y. Li, J.H. Yu, Q.H. Pan, Q.R. Fang, R.R. Xu, J. Solid State Chem. 178, 2673 (2005)

    CAS  Google Scholar 

Download references

Acknowledgement

This work is supported by the National Natural Science Foundation of China (51774175 and 51805235), the Department of Education of Liaoning Province (LJ2017QL005) and College Students' innovation training program (201810147077).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Liaoning Technical University, Fuxin, 123000, Liaoning, People’s Republic of China

    Xuelei Wang, Yihui Zhou, Chao Meng, Xiang Li, Xiaodong Hong & Shaobin Yang

  2. College of New Energy and Environment, Jilin University, Changchun, 130012, Jilin, People’s Republic of China

    Zhaojun Dong

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  1. Xuelei Wang
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  2. Yihui Zhou
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Wang, X., Zhou, Y., Dong, Z. et al. The effects of different dimensional organic amines on synthetic zinc phosphites/phosphates. J Porous Mater 27, 21–28 (2020). https://doi.org/10.1007/s10934-019-00790-2

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