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Selective sulfoxidation reactions with H2O2 catalyzed by Ti-containing SBA-15 materials

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Abstract

This contribution relates the behavior of Ti-SBA-15 catalysts in the sulfoxidation reaction with hydrogen peroxide under mild conditions (40–70 °C). Ti-SBA-15 samples with 1, 3 and 5 wt% of TiO2 have been prepared by grafting SBA-15 silica with Ti(OiPr)4 in ethanol followed by calcination. Due to their mesopores, the Ti-containing catalysts accommodated large molecules like methyl-phenyl-sulfide, diphenylsulfide and dibenzothiophene, which were selectively oxidized into their corresponding sulfoxides and sulfones. The turnover frequency was correlated with the amount of the tetrahedral Ti atoms in the catalyst. During the oxidation process performed in batch mode, with acetonitrile or ethanol as solvent, the catalyst topology and texture were preserved, but the nature of the Ti species suffered some changes.

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Acknowledgements

The authors would like to thank the adsorption platform of IS2M where the gas physisorption measurements have been performed.

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Authors and Affiliations

  1. Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM-ENSCM, Matériaux Avancés pour la Catalyse et la Santé, 240 avenue du Professeur Emile JEANBRAU, CS 60297, 34296, Montpellier, Cedex 05, France

    Radu Dorin Andrei & Vasile Hulea

  2. Université de Haute Alsace, CNRS, IS2M UMR 7361, 68100, Mulhouse, France

    Nathan Cambruzzi, Magali Bonne & Bénédicte Lebeau

  3. Université de Strasbourg, Strasbourg, France

    Nathan Cambruzzi, Magali Bonne & Bénédicte Lebeau

Authors
  1. Radu Dorin Andrei
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  2. Nathan Cambruzzi
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  3. Magali Bonne
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  4. Bénédicte Lebeau
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  5. Vasile Hulea
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Corresponding author

Correspondence to Vasile Hulea.

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Andrei, R.D., Cambruzzi, N., Bonne, M. et al. Selective sulfoxidation reactions with H2O2 catalyzed by Ti-containing SBA-15 materials. J Porous Mater 26, 533–539 (2019). https://doi.org/10.1007/s10934-018-0640-1

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