Abstract
A novel magnetic composite bioadsorbents composed of chitosan wrapping various content of nanoscale Fe3O4 and MIL-101 ([Cr3F(H2O)2O(bdc)3], bdc = 1,4 benzenedicarboxylate, m-CS/Fe3O4/MIL-101) were prepared for the adsorptive removal of a harmful anionicdye methyl orange (MO), from aqueous solutions. The introduction of chitosan could obviously increase the adsorption capacity of MO onto the metal–organic frameworks by about 40 % in comparison with pure MIL-101. The adsorption kinetics was investigated, and the experimental data and adsorption isotherms were better fitted by pseudo-second order kinetic model and Langmuir isotherm, respectively. Furthermore, the m-CS/Fe3O4/MIL-101 composites are reusable after adsorption in water and could be effectively separated by applying a magnetic field after adsorption.
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Acknowledgments
This work was supported by the National Natural Science Foundation of China (NSFC, 21371002), the NSFC-CAS Joint Fund for Research Based on Large-Scale Scientific Facilities (10979014), the NSF of Anhui Province, the Program for New Century Excellent Talent in University, Ministry of Education, China (NCET-08-0617), and the “211 Project” of Anhui University. Lingli Liu is grateful for Key projects of Anhui Provincial Department of Education (KJ2016A309) and Natural Science Foundation of Anhui Xinhua University (2014zr008).
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Liu, L., Ge, J., Yang, LT. et al. Facile preparation of chitosan enwrapping Fe3O4 nanoparticles and MIL-101(Cr) magnetic composites for enhanced methyl orange adsorption. J Porous Mater 23, 1363–1372 (2016). https://doi.org/10.1007/s10934-016-0195-y
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DOI: https://doi.org/10.1007/s10934-016-0195-y