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Synthesis of dual herbicides-intercalated hydrotalcite-like nanohybrid compound with simultaneous controlled release property

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Abstract

A new monophasic nanohybrid containing two herbicides anions, 3,4-dichlorophenoxyacetate (3,4D) and 2-methyldichlorophenoxyacetate (MCPA), was successfully synthesized. The two anions were simultaneously intercalated into the inorganic interlayers of zinc-aluminium-layered double hydroxide (ZAL) for the formation of a nanohybrid, ZAL—MCPA—3,4D (ZAMDX) by anion exchange method. The properties of ZAL intercalated with single guest MCPA and 3,4D, as well as dual-guest nanocomposite were monitored using powder X-ray diffractometer (PXRD), and showed a basal spacing of 19.7, 19.0 and 19.2 Å, respectively. Direct-injection mass spectroscopy (DIMS) and Fourier transform infrared (FTIR) confirmed the dual intercalation of both anions into the interlayer regions of dual-guest nanocomposite. The release of MCPA and 3,4D from ZAMDX fitted a pseudo-second order model and possessed good controlled release properties. This release property exhibits the potential application of layered materials as a delivery system, as well as reservoirs, especially when multiple active agents are used simultaneously in the formation of an organic–inorganic host–guest nanohybrid.

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References

  1. J. Miao, M. Xue, H. Itoh, Q. Feng, J. Mater. Chem. 16, 474 (2006)

    Article  CAS  Google Scholar 

  2. D.G. Evans, R.C. Slade, Struct. Bonding 119, 1–87 (2006)

    CAS  Google Scholar 

  3. J. Yang, Y. Han, M. Park, T. Park, S. Hwang, J. Choy, Chem. Mater. 19, 2679 (2007)

    Article  CAS  Google Scholar 

  4. B. Li, J. He, D.G. Evans, X. Duan, Appl. Clay Sci. 27, 199 (2004)

    Article  Google Scholar 

  5. S.H. Sarijo, M.Z. Hussein, A.H. Yahaya, Z. Zainal, Appl. Clay. Sci 58, 60–68 (2012)

    Article  Google Scholar 

  6. R. Wahab, S.G. Ansari, Y.S. Kim, M.A. Dar, H.S. Shin, J. Alloy Compd. 461, 66–71 (2008)

    Article  CAS  Google Scholar 

  7. M.Z. Hussein, S. Halima, A.H. Yahya, Z. Zainal, J. Nanosci. Technol. 7, 1–11 (2007)

    Google Scholar 

  8. M.Z. Hussein, A.H. Yahya, Z. Zainal, L.H. Kian, J. Sci. Techol. Adv. Mater. 6(8), 956–962 (2005)

    Article  Google Scholar 

  9. Z. Wang, E. Wang, L. Ga, L. X, J. Mater. Chem. A. 2(36), 15102–15110 (2014)

    Article  Google Scholar 

  10. X. Fu, H. Zhang, S. Niu, Q. Xin, J. Solid State Chem. 178(3), 736–741 (2005)

    Article  Google Scholar 

  11. L. Qin, S. Wang, R. Zhang, R. Zhu, X. Sun, S. Yao, J. Phys. Chem. Solids 69(11), 2779–2784 (2008)

    Article  CAS  Google Scholar 

  12. S. Miyata, Clays Clay Miner 28, 50–56 (1980)

    Article  CAS  Google Scholar 

  13. A.I. Khan, D. O’Hare, J. Mater. Chem. 12, 3191–3198 (2002)

    Article  CAS  Google Scholar 

  14. M.Z. Hussein, M.Y. Ghotbi, A.H. Yahaya, M.Z. Abd Rahman, Mater. Chem. Phys. 113, 491–496 (2009)

    Article  Google Scholar 

  15. D. Guo, C. Wu, H. Jiang, Q. Li, X. Wang, B. Chen, J. Photochem. Photobio. B Biolog. 93, 119–126 (2008)

    Article  CAS  Google Scholar 

  16. R.Y. Hong, S.Z. Zhang, G.Q. Di, H.Z. Li, Y. Zheng, J. Ding, D.G. Wei, J. Environ. Health Sci. Eng. 12, 140–144 (2014)

  17. M.Z. Hussein, S.H. Sarijo, A. Yahya, Z. Zainal, J. Nanosci. Nanotechnol. 7(8), 2852–2862 (2007)

    Article  Google Scholar 

  18. M.S. Gasser, Colloids Surf. B Biointerfaces 73, 103–109 (2009)

    Article  CAS  Google Scholar 

  19. M. Belmouden, A. Assabbane, Y.A. Ichou, J. Environ. Monit. 2(3), 257–260 (2000)

    Article  CAS  Google Scholar 

  20. P.S. Braterman, Z.P. Xu, F. Yarberry, in Handbook of Layered Materials, eds. by S.M. Auerbach, K.A. Carrado, P.K. Dutta (Marcel Dekker, New York, 2004) pp. 373–474

  21. K.A. Dutta, P.K. (eds.), Handbook of Layered Materials (Marcel Dekker, New York)

  22. M.J. Dos Reis, F. Silve´Rio, J. Tronto, J.B. Valim, J. Phys. Chem. Solids 65(2–3), 487–492 (2004)

    Article  Google Scholar 

  23. M.C. Hermosin, J. Cornejo, Chemosphere 24(10), 1493–1503 (1992)

    Article  CAS  Google Scholar 

  24. M.C. Hermosin, J. Cornejo, J. Environ. Qual. 22(2), 325–331 (1993)

    Article  CAS  Google Scholar 

  25. B. Houri, A. Legrouri, A. Barroug, C. Forano, J.P. Besse, J. Chim. Phys. 96(3), 455–463 (1999)

    Article  CAS  Google Scholar 

  26. D. Kolousek, Collect. Czech. Chem. Commun. 64(9), 1517–1528 (1999)

    Article  Google Scholar 

  27. G. Lagaly, Appl. Clay Sci. 18(5–6), 205–209 (2001)

    Article  CAS  Google Scholar 

  28. A.I. Khan, D. O’Hare, J. Mater. Chem. 12(11), 3191–3198 (2002)

    Article  CAS  Google Scholar 

  29. Z. Liu, R. Ma, M. Osada, N. Iyi, Y. Ebina, K. Takada, T. Sasaki, J. Am. Chem. Soc. 128(14), 4872–4880 (2006)

    Article  CAS  Google Scholar 

  30. Z. Liu, R. Ma, M. Osada, K. Takada, T. Sasaki, J. Am. Chem. Soc. 127, 13869 (2005)

    Article  CAS  Google Scholar 

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Acknowledgments

This research was funded by the Ministry of Higher Education Malaysia (MOHE) under the Fundamental Research Grant Scheme (FRGS) No. 600RMI/ST/FRGS/FST(194/2010).

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Authors and Affiliations

  1. Faculty of Applied Science, Universiti Teknologi MARA (UiTM), 40450, Shah Alam, Selangor, Malaysia

    Siti Halimah Sarijo & Sheikh Ahmad Izaddin Sheikh Mohd Ghazali

  2. Material Synthesis and Characterization Laboratory (MSCL), Institute of Advanced Technology (ITMA), Universiti Putra Malaysia (UPM), 43400, Serdang, Selangor, Malaysia

    Mohd Zobir Hussein

Authors
  1. Siti Halimah Sarijo
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  2. Sheikh Ahmad Izaddin Sheikh Mohd Ghazali
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  3. Mohd Zobir Hussein
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Correspondence to Siti Halimah Sarijo.

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Sarijo, S.H., Ghazali, S.A.I.S.M. & Hussein, M.Z. Synthesis of dual herbicides-intercalated hydrotalcite-like nanohybrid compound with simultaneous controlled release property. J Porous Mater 22, 473–480 (2015). https://doi.org/10.1007/s10934-015-9916-x

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  • DOI: https://doi.org/10.1007/s10934-015-9916-x

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