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Synthesis, characterization and controlled release properties of zinc–aluminium-beta-naphthoxyacetate nanocomposite

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Abstract

An organic–inorganic nanohybrid nanocomposite was synthesized by co-precipitation method using beta-naphthoxyacetate (BNOA) as guest anion and zinc–aluminium layered double hydroxide (Zn–Al-LDH) as the inorganic host. A well-ordered nanohybrid nanocomposite was formed when the concentration of BNOA was 0.08 M and the molar ratio of Zn to Al, R = 2. Basal spacing of layered double hydroxide containing nitrate ions expanded from 8.9 to 19.5 Å in resulting of Zn–Al-BNOA nanocomposite was obtained indicates that beta-naphthoxyacetate was successfully intercalated into interlayer spaces of layered double hydroxide. It was also found out the BET surface area increased from 1.13 to 42.79 m2 g−1 for Zn–Al-LDH and Zn–Al-BNOA nanocomposite, respectively. The BJH average pore diameter of the synthesized nanocomposite is 199 Å which shows mesoporous-type of material. CHNS analysis shows the Zn–Al-BNOA nanocomposite material contains 36.2 % (w/w) of BNOA calculated based on the percentage of carbon in the sample. Release of BNOA from the lamella of Zn–Al-BNOA was controlled by the zeroth and first order kinetics at the beginning of the deintercalation process up to 200 min and controlled by pseudo-second order kinetics for the whole process. This study suggests that layered double hydroxide can be used as a carrier for organic acid herbicide controlled release formulation of BNOA.

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Acknowledgments

The work was supported by Ministry of Science, Technology and Environment, Malaysia for the Grant under e-Science Fund No: 03-02-03-SF0126.

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Authors and Affiliations

  1. College of Engineering, Universiti Tenaga Nasional, 43009, Kajang, Selangor, Malaysia

    Zaemah binti Jubri, Nor Zalina Anua binti Mohd Yusoff & Elya Sufliza binti Marsom

  2. Faculty of Applied Science, Universiti Teknologi Mara, 40450, Shah Alam, Selangor, Malaysia

    Siti Halimah binti Sarijo

  3. Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia

    Mohd Zobir bin Hussein

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  1. Zaemah binti Jubri
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  2. Nor Zalina Anua binti Mohd Yusoff
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  3. Siti Halimah binti Sarijo
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Correspondence to Zaemah binti Jubri.

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Jubri, Z.b., Yusoff, N.Z.A.b.M., Sarijo, S.H.b. et al. Synthesis, characterization and controlled release properties of zinc–aluminium-beta-naphthoxyacetate nanocomposite. J Porous Mater 24, 573–582 (2017). https://doi.org/10.1007/s10934-016-0293-x

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  • DOI: https://doi.org/10.1007/s10934-016-0293-x

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